Nous avons développé un récepteur hétérodyne terahertz (THz) compact et ultra-sensible à base de laser à cascade quantique (QCL) comme oscillateur local et de bolomètre à électron chaud (HEB) comme mélangeur. Le récepteur est basé sur un nouveau concept pour le couplage quasi-optique entre l'oscillateur local et le mélangeur ce qui a permis de ne pas utiliser de lame semi-réfléchissante pour la superposition du signal provenant du QCL et du signal à détecter. Le mélangeur utilisé est un HEB en nitrure de niobium avec une antenne planaire formée d’une double hélice log-spiral. Le HEB est monté sur la partie plane d’une lentille convexe en silicium. L’oscillateur local est un QCL que nous avons développé avec un système de contre-réaction répartie du troisième ordre avec une faible dissipation thermique, un faisceau peu divergent et un fonctionnement mono-mode à la fréquence cible de 2.7 THz. Le couplage entre l’oscillateur local et le mélangeur HEB a également été amélioré en couplant le QCL avec une fibre creuse en diélectrique ce qui a permis d’améliorer la directivité du faisceau laser à 55 dBi. Grâce aux précédents résultats, nous avons obtenu un récepteur THz hétérodyne compact qui présente une sensibilité proche de l’état de l’art à 2.7 THz. / We demonstrate an ultra-compact Terahertz (THz) heterodyne detec- tion system based on a quantum cas- cade laser (QCL) as local oscillator and a hot electron bolometer (HEB) for the mixing. It relies on a new opti- cal coupling scheme where the local oscillator signal is coupled through the air side of the planar HEB an- tenna, while the signal to be de- tected is coupled to the HEB through the lens. This technique allows us to suppress the beam splitter usu- ally employed for heterodyne mea- surements. The mixer is a Niobium Nitride HEB with a log-spiral planar antenna on silicon and mounted on the back of a plano-convex silicon lens. We have developed a low power consumption and low beam di- vergence 3rd-order distributed feed- back laser with single mode emis- sion at the target frequency of 2.7 THz to be used as local oscillator for the heterodyne receiver. The cou- pling between the QC laser and the the HEB has been further optimized, using a dielectric hollow waveguide that reliably increases the laser beam directivity up to 55 dBi. Upon the high beam quality, sufficient output power in a single mode at the tar- geted frequency and low power dissi- pation of our local oscillator, we have build an ultra compact THz hetero- dyne receiver with sensitivity close to the state of the art at 2.7 THz.

Some interesting electronic and dynamic properties of semiconductor nanocrystal heterostructures have been investigated using various spectroscopic methods. Semiconductor nanocrystal heterostructures were prepared using colloidal synthesis techniques. Ultrafast transient absorption spectroscopy was used to monitor the relaxation of hot electrons in CdS/HgS/CdS quantum dot quantum wells. Careful analysis of the hot electron relaxation in CdS/HgS/CdS quantum dot quantum wells reveals an energy dependent relaxation mechanism involving electronic states of varying CdS and HgS composition. The composition of the electronic states, combined with the layered structure of the nanocrystal permits the assignment of CdS localized and HgS localized excited states. The dynamic effect of surface passivation is then shown to have the strongest influence on excited states that are localized in the HgS layer. New quantum dot quantum well heterostructures of different sizes and compositions were also prepared and studied. The dynamic properties of CdS/CdSe/CdS colloidal quantum wells suggest simultaneous relaxation of excited electrons within the CdS core and CdSe shell on the sub-picosecond time scale. Despite the very different electronic structure of CdS/CdSe/CdS compared to CdS/HgS/CdS, the time scales of the relaxation and electron localization were very similar. Enhancement of trap luminescence was observed when CdS quantum dots were coated with silver. The mechanism of the enhancement was investigated using time-resolved spectroscopic techniques.

CMOS RF circuit design has been an ever-lasting research field. It gained so much attention since RF circuits have high mobility and wide band efficiency, while CMOS technology has the advantage of low cost and better capability of integration. At the same time, IC circuits never stopped scaling down for the recent many decades. Reliability issues with RF circuits have become more and more severe with device scaling down: reliability effects such as gate oxide break down, hot carrier injection, negative bias temperature instability, have been amplified as the device size shrinks. Process variability issues also become more predominant as the feature size decreases. With these insights provided, reliability and variability evaluations on typical RF circuits and possible compensation techniques are highly desirable. In this work, a class E power amplifier is designed and laid out using TSMC 0.18 µm RF technology and the chip was fabricated. Oxide stress and hot electron tests were carried out at elevated supply voltage, fresh measurement results were compared with different stress conditions after 10 hours. Test results matched very well with mixed mode circuit simulations, proved that hot carrier effects degrades PA performances like output power, power efficiency, etc. Self- heating effects were examined on a class AB power amplifier since PA has high power operations. Device temperature simulation was done both in DC and mixed mode level. Different gate biasing techniques were analyzed and their abilities to compensate output power were compared. A simple gate biasing circuit turned out to be efficient to compensate selfheating effects under different localized heating situations. iv Process variation was studied on a classic Colpitts oscillator using Monte-Carlo simulation. Phase noise was examined since it is a key parameter in oscillator. Phase noise was modeled using analytical equations and supported by good match between MATLAB results and ADS simulation. An adaptive body biasing circuit was proposed to eliminate process variation. Results from probability density function simulation demonstrated its capability to relieve process variation on phase noise. Standard deviation of phase noise with adaptive body bias is much less than the one without compensation. Finally, a robust, adaptive design technique using PLL as on-chip sensor to reduce Process, Voltage, Temperature (P.V.T.) variations and other aging effects on RF PA was evaluated. The frequency and phase of ring oscillator need to be adjusted to follow the frequency and phase of input in PLL no matter how the working condition varies. As a result, the control signal of ring oscillator has to fluctuate according to the working condition, reflecting the P.V.T changes. RF circuits suffer from similar P.V.T. variations. The control signal of PLL is introduced to RF circuits and converted to the adaptive tuning voltage for substrate bias. Simulation results illustrate that the PA output power under different variations is more flat than the one with no compensation. Analytical equations show good support to what has been observed.

The role played by power converting circuits is extremely important to almost any electronic system built today. Circuits that use converters of any type depend on power that is consistent in form and reliable in order to properly function. In addition, today's demands require more efficient use of energy, from large stationary systems such as power plants all the way down to small mobile devices such as laptops and cell phones. This places a need to reduce any losses to a minimum. The power conversion circuitry in a system is a very good place to reduce a large amount of unnecessary loss. This can be done using circuit topologies that are low loss in nature. For low loss and high performance, soft switching topologies have offered solutions in some cases. Also, limited study has been performed on device aging effects on switching mode power converting circuits. The impact of this effect on a converter's overall efficiency is theoretically known but with little experimental evidence in support. In this thesis, non-isolated buck type switching converters will be the main focus. This type of power conversion is widely used in many systems for DC to DC voltage step down. Newer methods and topologies to raise converter power efficiency are discussed, including a new synchronous ZVT topology . Also, a study has been performed on device aging effects on converter efficiency. Various scenarios of voltage conversion, switching frequency, and circuit components as well as other conditions have been considered. Experimental testing has been performed in both cases, ZVT's benefits and device aging effects, the results of which are discussed as well.

No description available.

Graphene base transistors (GBTs) have been, recently, proposed to overcome the intrinsic limitations of the graphene field effect transistors (GFETs) and exploit the graphene unique properties in high frequency (HF) applications. These devices utilize single layer graphene as the base material in the vertical hot-electron transistors. In an optimized GBT, the ultimate thinness of the graphene-base and its high conductivity, potentially, enable HF performance up to the THz region.  This thesis presents an experimental investigation on the GBTs as well as integration process developments for the fabrication of graphene-based devices. In this work, a full device fabrication and graphene integration process were designed with high CMOS compatibility considerations. To this aim, basic process modules, such as graphene transfer, deposition of materials on graphene, and formation of tunnel barriers, were developed and optimized. A PDMS-supporting graphene transfer process were introduced to facilitate the wet/dry wafer-scale transfer from metal substrate onto an arbitrarily substrate. In addition, dielectric deposition on graphene using atomic layer deposition (ALD) was investigated. These dielectric layers, mainly, served as the base-collector insulators in the fabricated GBTs. Moreover, the integration of silicon (Si) on the graphene surface was studied. Using the developed fabrication process, the first proof of concept devices were demonstrated. These devices utilized 5 nm-thick silicon oxide (SiO2) and about 20 nm-thick aluminum oxide (Al2O3) as the emitter-base insulator (EBI) and base-collector insulator (BCI). The direct current (DC) functionality of these devices exhibited &gt;104 on/off current ratios and a current transfer ratio of about 6%. The performance of these devices was limited by the non-optimized barrier parameters and device manufacturing technology. The possibility to improve and optimize the GBT performance was demonstrated by applying different barrier optimization approaches. Comparing to the proof of concept devices, several orders of magnitude higher injection current density was achieved using a bilayer dielectric tunnel barrier. Utilizing the novel TmSiO/TiO2 (1 nm/6 nm) dielectric stack, this tunnel barrier prevents defect mediated tunneling and, simultaneously, promotes the Fowler-Nordheim tunneling (FNT) and step tunneling (ST). Furthermore, it was shown that Si/graphene Schottky junction can significantly improve the current gain by reducing the electron backscattering at the base-collector barrier. In this thesis, a maximum current transfer ratio of about 35% has been achieved. / <p>QC 20160503</p>

<p>The concept of energy production through the fusion of two light nuclei has been studied since the 1950’s. One of the major problems that fusion scientists have encountered is the confinement of the hot ionised gas, i.e. the plasma, in which the fusion process takes place. The most common way to contain the plasma is by using at magnetic field configuration, in which the plasma takes a doughnut-like shape. Experimental devices of this kind are referred to as tokamaks. For the fusion process to proceed at an adequate rate, the temperature of the plasma must exceed 100,000,000C. Such a high temperature forces the plasma out of thermodynamical equilibrium which plasma tries to regain by exciting a number of turbulent processes. After successfully quenching the lager scale magnetohydrodynamic turbulence that may instantly disrupt the plasma, a smaller scale turbulence revealed itself. As this smaller scale turbulence behaved contrary to the common theory at the time, it was referred to as anomalous. This kind of turbulence does not directly threaten existents of the plasma, but it allows for a leakage of heat and particles which inhibits the fusion reactions. It is thus essential to understand the origin of anomalous turbulence, the transport it generates and most importantly, how to reduce it. Today it is believed that anomalous transport is due to drift-type waves driven by temperature and density inhomogeneities and the theoretical treatment of these waves is the topic of this thesis.</p><p>The first part of the thesis contains a rigorous analytical two-fluid treatment of drift waves driven solely by density inhomogeneities. Effects of the toroidal magnetic field configuration, the Landau resonance, a peaked diamagnetic frequency and a sheared rotation of the plasma have been taken into account. These effects either stabilise or destabilise the drift waves and to determine the net result on the drift waves requires careful analysis. To this end, dispersion relations have been obtained in various limits to determine when to expect the different effects to be dominant. The main result of this part is that with a large enough rotational shear, the drift waves will be quenched.</p><p>In the second part we focus on temperature effects and thus treat reactive drift waves, specifically ion temperature gradient and trapped electron modes. In fusion plasmas the α-particles, created as a by-product of the fusion process, transfer the better part of their energy to the electrons and hence the electron temperature is expected to exceed the ion temperature. In most experiments until today, the ion temperature is greater than the electron temperature and this have been proven to improve the plasma confinement. To predict the performance of future fusion plasmas, where the fusion process is ongoing, a comprehensive study of hot-electron plasmas and external heating effects have been carried out. Especially the stiffness (heat flux vs. inverse temperature length scale) of the plasma has been examined. This work was performed by simulations done with the JETTO code utilising the Weiland model. The outcome of these simulations shows that the plasma response to strong heating is very stiff and that the plasma energy confinement time seems to vary little in the hot-electron mode.</p>

The concept of energy production through the fusion of two light nuclei has been studied since the 1950’s. One of the major problems that fusion scientists have encountered is the confinement of the hot ionised gas, i.e. the plasma, in which the fusion process takes place. The most common way to contain the plasma is by using at magnetic field configuration, in which the plasma takes a doughnut-like shape. Experimental devices of this kind are referred to as tokamaks. For the fusion process to proceed at an adequate rate, the temperature of the plasma must exceed 100,000,000C. Such a high temperature forces the plasma out of thermodynamical equilibrium which plasma tries to regain by exciting a number of turbulent processes. After successfully quenching the lager scale magnetohydrodynamic turbulence that may instantly disrupt the plasma, a smaller scale turbulence revealed itself. As this smaller scale turbulence behaved contrary to the common theory at the time, it was referred to as anomalous. This kind of turbulence does not directly threaten existents of the plasma, but it allows for a leakage of heat and particles which inhibits the fusion reactions. It is thus essential to understand the origin of anomalous turbulence, the transport it generates and most importantly, how to reduce it. Today it is believed that anomalous transport is due to drift-type waves driven by temperature and density inhomogeneities and the theoretical treatment of these waves is the topic of this thesis. The first part of the thesis contains a rigorous analytical two-fluid treatment of drift waves driven solely by density inhomogeneities. Effects of the toroidal magnetic field configuration, the Landau resonance, a peaked diamagnetic frequency and a sheared rotation of the plasma have been taken into account. These effects either stabilise or destabilise the drift waves and to determine the net result on the drift waves requires careful analysis. To this end, dispersion relations have been obtained in various limits to determine when to expect the different effects to be dominant. The main result of this part is that with a large enough rotational shear, the drift waves will be quenched. In the second part we focus on temperature effects and thus treat reactive drift waves, specifically ion temperature gradient and trapped electron modes. In fusion plasmas the α-particles, created as a by-product of the fusion process, transfer the better part of their energy to the electrons and hence the electron temperature is expected to exceed the ion temperature. In most experiments until today, the ion temperature is greater than the electron temperature and this have been proven to improve the plasma confinement. To predict the performance of future fusion plasmas, where the fusion process is ongoing, a comprehensive study of hot-electron plasmas and external heating effects have been carried out. Especially the stiffness (heat flux vs. inverse temperature length scale) of the plasma has been examined. This work was performed by simulations done with the JETTO code utilising the Weiland model. The outcome of these simulations shows that the plasma response to strong heating is very stiff and that the plasma energy confinement time seems to vary little in the hot-electron mode.

Cette thèse expérimentale traite de l'électroluminescence de contacts atomiques en or. Les contacts métalliques ponctuels sont formés et pilotés à l'aide d'un dispositif de jonction brisée contrôlée mécaniquement. Les contacts sont formés à partir d'un fil d'or et sont étudiés à la température ambiante.L'électroluminescence est observée dans le visible au travers d'un microscope optique. Le détecteur est une caméra sensible en silicium. Pour l'analyse du spectre émis, un dispositif dispersif en ligne a été spécifiquement développé. Pour l'infrarouge, le détecteur photovoltaïque monocanal est en InAsSb.Nos mesures électriques et optiques simultanées permettent de sonder la physique des interactions entre électrons et photons à l'échelle nanométrique. L'électroluminescence est attribuée à l'émission spontanée d'un nanogaz à haute température d'électrons chauds, conséquence des fortes densités de courant. Cette haute température électronique est fonction des conditions opératoires. Pour ces nanojonctions d'or, nos expériences nous permettent d’en proposer une expression analytique simple.Ces travaux complètent des expériences similaires menées depuis le début des années 2000. Ils sont discutés dans le cadre d'un modèle développé pour expliquer l'émission d'électrons chauds à partir de films métalliques granulaires. Nous discutons de la physique d’échauffement du gaz d’électron en rapprochant nos résultats d'expériences pompe/sonde femtoseconde interrogeant la dynamique des électrons hors équilibre dans des nanobilles d'or ainsi que d'expériences de transport en physique mésoscopique menées à très basse température. / This experimental thesis deals with electroluminescence from gold atomic point contacts. Metallic point contacts are formed and driven with a home-made mechanically controlled break junction device. The nanojunctions are made from gold wires. Experiments are performed at room temperature and in air.Electroluminescence is observed in the visible range with an infinity corrected inverted optical microscope. The detector is a high sensitivity silicon camera. To perform spectral analysis, a dispersive on-line device has been developed to be inserted directly within the microscope. A reflective objective collects infrared photons and focuses them onto an InAsSb photovoltaic cooled detector.Our simultaneous electrical and optical measurements allow us to investigate the physics of electrons and photons interactions at the nanometric scale. Electroluminescence is explained by the spontaneous emission of a hot electron nano-gas favoured by huge current densities. This high electron temperature depends on operating conditions. For gold ballistic nanojunctions, our results lead us to propose a simple expression of this temperature. This work extends similar electroluminescence studies performed since the early 2000’s. The results are discussed in this context and in the framework of a model first introduced to account for hot electron emission from thin granular metallic films. Moreover, we discuss the physics leading to the hot electron gaz with the support of pump/probe femtosecond experiments probing the nonequilibrium electron dynamics in gold nanosphere and with the support of low temperature mesoscopic transport experiments.

Abstract: When noble metals particles are synthesized with progressively smaller dimensions, strikingly novel optical properties arise. For nanoscale particles, collective disturbances of the electron density known as localized surface plasmons resonances can arise, and these resonances are utilized in a variety of applications ranging from surface-enhanced molecular spectroscopy and sensing to photothermal cancer therapy to plasmon-driven photochemistry. Central to all of these studies is the plasmon’s remarkable ability to process light, capturing and converting it into intense near fields, heat, and even energetic carriers at the nanoscale. In the past decade, we have witnessed major advances in plasmonics which is directly linked with the much broader field of (colloidal) nanotechnology. These breakthroughs span from plasmon lasing and waveguides, plasmonic photochemistry and solar cells to active plasmonics, plasmonics nanocomposites and semiconductor plasmons. All the above-mentioned phenomena rely on precise spatial placement and distinct control over the dimensions and orientation of the individual plasmonic building blocks within complex one-, two- or three-dimensional complex arrangements. For the nanofabrication of metal nanostructures at surfaces, most often lithographic approaches, e.g. e-beam lithography or ion-beam milling are generally applied, due to their versatility and precision. However, these techniques come along with several drawbacks such as limited scalability, limited resolution, limited compatibility with silicon manufacturing techniques, damping effects due to the polycrystalline nature of the metal nanostructures and low sample throughput. Thus, there is a great demand for alternative approaches for the fabrication of metal nanostructures to overcome the above-mentioned limitations. But why colloids? True three-dimensionality, lower damping, high quality modes due to mono-dispersity, and the absence of grain boundaries make the colloidal assembly an especially competitive method for high quality large-scale fabrication. On top of that, colloids provide a versatile platform in terms of size, shape, composition and surface modification and dispersion media. 540The combination of directed self-assembly and laser interference lithography is a versatile admixture of bottom-up and top-down approaches that represents a compelling alternative to commonly used nanofabrication methods. The objective of this thesis is to focus on large area fabrication of emergent spectroscopic properties with high structural and optical quality via colloidal self-assembly. We focus on synergy between optical and plasmonic effects such as: (i) coupling between localized surface plasmon resonance and Bragg diffraction leading to surface lattice resonance; (ii) strong light matter interaction between guided mode resonance and collective plasmonic chain modes leading to hybrid guided plasmon modes, which can further be used to boost the hot-electron efficiency in a semiconducting material; (iii) similarly, bilayer nanoparticle chains leading to chiro-optical effects. Following this scope, this thesis introduces a real-time tuning of such exclusive plasmonic-photonic (hybrid) modes via flexible template fabrication. Mechanical stimuli such as tensile strain facilitate the dynamic tuning of surface lattice resonance and chiro-optical effects respectively. This expands the scope to curb the rigidity in optical systems and ease the integration of such systems with flexible electronics or circuits.:Contents Abstract Kurzfassung Abbreviations 1. Introduction and scope of the thesis 1.1. Introduction 1.1.1. Classical optics concepts 1.1.2. Top down fabrication methods and their challenges 1.1.3. Template-assisted self-assembly 1.1.4. Functional colloidal surface assemblies 1.2. Scope of the thesis 2. Results and Discussion 2.1. Mechanotunable Surface Lattice Resonances in the Visible Optical Range by Soft Lithography Templates and Directed Self-Assembly 2.1.1. Fabrication of flexible 2D plasmonic lattice 2.1.2. Investigation of the influence of particle size distribution on SLR quality 2.1.3. Band diagram analysis of 2D plasmonic lattice 2.1.4. Strain induced tuning of SLR 2.1.5. SEM and force transfer analysis in 2D plasmonic lattice under various strain 2.2. Hybridized Guided-Mode Resonances via Colloidal Plasmonic Self-Assembled Grating 2.2.1. Fabrication of hybrid opto-plasmonic structure via template assisted self-assembly 2.2.2. Comparison of optical band diagram of three (plasmonic, photonic and hybrid) different structures in TE and TM modes 2.2.3. Simulative comparison of optical properties of hybrid opto-plasmonic NP chains with a grating of metallic gold bars 2.2.4. Effect of cover index variation with water as a cover medium 2.3. Hot electron generation via guided hybrid modes 2.3.1. Fabrication of the hybrid GMR structure via LIL and lift-off process 2.3.2. Spectroscopic and simulative analysis of hybrid opto-plasmonic structures of different periodicities 2.3.3. Comparative study of photocurrent generation in different plasmonic structures 2.3.4. Polarization dependent response at higher wavelength 2.3.5. Directed self-assembly of gold nanoparticles within grating channels of a dielectric GMR structure supported by titanium dioxide film 2.4. Active Chiral Plasmonics Based on Geometrical Reconfiguration 2.4.1. Chiral 3D assemblies by macroscopic stacking of achiral chain substrates 3. Conclusion 4. Zusammenfassung 5. Bibliography 6. Appendix 6.1. laser interference lithography 6.2. Soft molding 6.3. Determine fill factor of plasmonic lattice 6.4. 2D plasmonic lattice of Au_BSA under strain 6.5. Characterizing order inside a 2D lattice 6.6. Template-assisted colloidal self-assembly 6.7. Out of plane lattice resonance in 1D and 2D lattices 6.8. E-Field distribution at out of plane SLR mode for 1D lattices of various periodicity with AOI 20° 6.9. Refractive index of PDMS and UV-PDMS 6.10. Refractive index measurement for sensing 6.11. Optical constants of TiO2, ma-N 405 photoresist and glass substrate measured from spectroscopic ellipsometry Acknowledgement/ Danksagung Erklärung & Versicherung List of Publications