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Developing critical loads for nitrogen (N) in the Athabasca Oil Sands Region (AOSR) requires an understanding of the hydrological connectivity and potential for N transport among uplands, fens and bogs typical in the wetland-rich Boreal region of northern Alberta. The Cumulative Environmental Management Association’s (CEMA) overarching mandate is to determine a nitrogen critical load specific to the Boreal region of northern Alberta. To this end, nitrogen amendment experiments were initiated at two Boreal wetland sites: an upland – rich fen gradient at Jack Pine High (JPH) and an upland – fen – bog mosaic at Mariana Lakes (ML), 45 km north and 100 km south of Fort McMurray respectively. The objectives of this study are to use geochemical and isotopic tracers to describe baseline hydrogeochemical variability and connectivity between bog, fens and upland areas in the AOSR. Sites were instrumented with piezometer nests and water table wells along transects that cover the targeted landscape units (n = 108 sampling locations). Fieldwork related to this thesis was conducted during the open-water season: in June and August 2011, and in May, July, and September 2012. Field campaigns also included a snow survey (March 2012), and spring melt/freshet sampling (April 2012). The analysis of spatiotemporal variability of water isotopes and geochemistry in the years 2011-2012 yielded: i) a characterization of baseline conditions from which perturbations can be assessed, and ii) evidence of connectivity among landscape units. No evidence for elevated concentrations of nitrogen related to the amendment experiments was found in 2011 or 2012. The baseline characterization and annual monitoring did show increasing concentrations of inorganic ammonium with increasing depth associated with increasing solute concentrations: average concentrations of inorganic ammonium were 23 mg/L at deepest sampling locations (7 m) at ML bog and ML fen landscape units. These ammonium concentrations in porewaters, given a porosity of 0.90 for peatlands, constitute a store of ammonium that may be a significant source of nitrogen if the hydrology is altered due to co-occurring changes in vegetation (due to, for example, elevated nitrogen inputs), climate and/or landuse. Hydrologic connectivity at JPH is likely driven by topography. Hydraulic head in 2011 and 2012 field seasons showed that flow persisted from the upland to the fen. The consistent and distinct geochemical signatures and isotopic labelling of mid-depth and deep groundwater samples of fen and upland landscape units is consistent with such a stable groundwater continuum. Near-surface water samples at JPH fen however varied hydrogeochemically in response to seasonal changes in precipitation inputs, water levels, and biogeochemical productivity. At ML, hydrological connectivity is a function of antecedent moisture conditions (which determines run-off) and low and variable (10-6 to 10-9 m/s) hydrological conductivity of the peatland substrate (which may result in lateral flow where hydraulic head shows potential for vertical re- or discharge). Near-surface samples showed greater temporal than spatial variability as snowmelt inputs, variations in antecedent moisture conditions and seasonal changes in biogeochemical process rates affected nutrient and solute concentrations. In contrast, shallow, mid-depth and deep samples showed greater spatial than temporal variability. The spatial distributions of parameters could be associated to some degree with vegetation, distance along a surficial flowpath, or depth to mineral substrate or distance from the upland/edge transition. / Graduate / 0996 / 0388 / 0425 / cbkusel@yahoo.ca

The objective of this research was to determine the impact of climate change on the Churchill River basin and perform analysis on uncertainty related to this impact. Three hydrological models were used to determine this impact and were calibrated to approximately equivalent levels of efficiency. These include WATFLOODTM, a semi-physically based, distributed model; HBV-EC, a semidistributed, conceptual model; and HMETS, a lumped, conceptual model. These models achieved Nash-Sutcliffe calibration values ranging from 0.51 to 0.71. Climate change simulations indicated that the average of simulations predict a small increase in flow for the 2050s and a slight decrease for the 2080s. Each hydrological model predicted earlier freshets and a shift in timing of low flow events. Uncertainty analysis indicated that the chief contributor of uncertainty was the selection of GCM followed by hydrological model with less significant sources of uncertainty being parameterization of the hydrological model and selection of emissions scenario.

Developing critical loads for nitrogen (N) in the Athabasca Oil Sands Region (AOSR) requires an understanding of the hydrological connectivity and potential for N transport among uplands, fens and bogs typical in the wetland-rich Boreal region of northern Alberta. The Cumulative Environmental Management Association’s (CEMA) overarching mandate is to determine a nitrogen critical load specific to the Boreal region of northern Alberta. To this end, nitrogen amendment experiments were initiated at two Boreal wetland sites: an upland – rich fen gradient at Jack Pine High (JPH) and an upland – fen – bog mosaic at Mariana Lakes (ML), 45 km north and 100 km south of Fort McMurray respectively. The objectives of this study are to use geochemical and isotopic tracers to describe baseline hydrogeochemical variability and connectivity between bog, fens and upland areas in the AOSR. Sites were instrumented with piezometer nests and water table wells along transects that cover the targeted landscape units (n = 108 sampling locations). Fieldwork related to this thesis was conducted during the open-water season: in June and August 2011, and in May, July, and September 2012. Field campaigns also included a snow survey (March 2012), and spring melt/freshet sampling (April 2012). The analysis of spatiotemporal variability of water isotopes and geochemistry in the years 2011-2012 yielded: i) a characterization of baseline conditions from which perturbations can be assessed, and ii) evidence of connectivity among landscape units. No evidence for elevated concentrations of nitrogen related to the amendment experiments was found in 2011 or 2012. The baseline characterization and annual monitoring did show increasing concentrations of inorganic ammonium with increasing depth associated with increasing solute concentrations: average concentrations of inorganic ammonium were 23 mg/L at deepest sampling locations (7 m) at ML bog and ML fen landscape units. These ammonium concentrations in porewaters, given a porosity of 0.90 for peatlands, constitute a store of ammonium that may be a significant source of nitrogen if the hydrology is altered due to co-occurring changes in vegetation (due to, for example, elevated nitrogen inputs), climate and/or landuse. Hydrologic connectivity at JPH is likely driven by topography. Hydraulic head in 2011 and 2012 field seasons showed that flow persisted from the upland to the fen. The consistent and distinct geochemical signatures and isotopic labelling of mid-depth and deep groundwater samples of fen and upland landscape units is consistent with such a stable groundwater continuum. Near-surface water samples at JPH fen however varied hydrogeochemically in response to seasonal changes in precipitation inputs, water levels, and biogeochemical productivity. At ML, hydrological connectivity is a function of antecedent moisture conditions (which determines run-off) and low and variable (10-6 to 10-9 m/s) hydrological conductivity of the peatland substrate (which may result in lateral flow where hydraulic head shows potential for vertical re- or discharge). Near-surface samples showed greater temporal than spatial variability as snowmelt inputs, variations in antecedent moisture conditions and seasonal changes in biogeochemical process rates affected nutrient and solute concentrations. In contrast, shallow, mid-depth and deep samples showed greater spatial than temporal variability. The spatial distributions of parameters could be associated to some degree with vegetation, distance along a surficial flowpath, or depth to mineral substrate or distance from the upland/edge transition. / Graduate / 0996 / 0388 / 0425 / cbkusel@yahoo.ca

Thesis (Ph. D. - Renewable Natural Resources)--University of Arizona, 1989. / Includes bibliographical references (leaves 188-193).

Thesis (M. S.)--Texas A&M University, 2007. / "Major Subject: Water Management & Hydrological Science" Title from author supplied metadata (automated record created on Oct. 13, 2008.) Vita. Abstract. Includes bibliographical references.

Thesis (M.S.)--Ohio University, August, 1996. / Title from PDF t.p.

Thesis (Ph. D.)--Auburn University, 2009. / Abstract. Vita. Includes bibliographical references (p. 107-120).

Thesis (Ph. D.)--University of California, Los Angeles, 1997. / Vita. Includes bibliographical references (leaves 200-208).

Thesis (MScIng)--University of Stellenbosch, 2006. / Bibliography. Also available via the Internet.