Thesis (Ph. D.)--Columbia University, 1941. / Vita. eContent provider-neutral record in process. Description based on print version record. Bibliography: p. 29.

Thesis (Ph. D.)--Columbia University, 1941. / Vita. eContent provider-neutral record in process. Description based on print version record. Bibliography: p. 29.

Because of As toxicity, the complexity of its chemistry, and the recent lowering of the maximum contaminant level of As in municipal drinking water, there has been considerable interest for improved methods to remove As from water. Although Al and Fe hydroxides have been extensively studied as adsorbents for As removal during water treatment, coprecipitated Al:Fe hydroxides have received only minimal attention. The theoretical and experimental feasibility of coprecipitated Al:Fe hydroxide systems were evaluated by studying their mineralogy, stability, and As adsorption and desorption behavior. The broad XRD peaks revealed that Al was substituted into the ferrihydrite structure and that this was the only major product up to about a 2:8 Al:Fe molar ratio. Gibbsite and bayerite were identified when Al content was higher. The rate of recrystallization of ferrihydrite into goethite and hematite was significantly reduced as Al substitution was increased. In general, adsorption capacity of both AsV and AsIII decreased with increase in Al:Fe molar ratio; however, similar AsV adsorption capacities were observed with Fe and Al:Fe hydroxides with Al:(Al+Fe) molar ratios < 0.20. Both AsIII and AsV adsorption isotherms were effectively described by Langmuir and Freundlich equations. Adsorption maxima of AsV on Fe and Al:Fe hydroxides were observed at pH 3 to 7, and that of AsV on Al hydroxide was observed at pH 5.2, with significant decreases in adsorption with increase and decrease in pH. Adsorption maxima of AsIII decreased by approximately 4 % for each 10 % increase in Al substitution up to 5:5 Al:Fe molar ratio. Adsorption maxima of AsIII on Fe and Al:Fe hydroxides were observed at pH 8 to 9. AsIII adsorption on Al hydroxide was negligible. Counterion Ca2+, compared to Na+, enhanced the retention of AsV, especially at pH > 7. Counterion concentration did not significantly affect AsV adsorption. Though phosphate desorbed both AsV and AsIII from all Al:Fe hydroxides, quantitative desorption was never observed. The results of this study indicate the possible utility of coprecipitated Al:Fe hydroxide in wastewater treatment. Based on adsorption/desorption behavior and stability of the Al:Fe hydroxide product, the preferred Al:Fe molar ratio was 2:8.

Thesis (Ph. D.)--University of Wisconsin--Madison, 1950. / Typescript. Includes abstract and vita. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references.

No description available.

No description available.

In this study, an electrolytic micro-machining tester is employed to investigate the effects of supply voltage and initial machining position on the geometry of the tungsten needle using the single-point and the reciprocating methods. The tungsten needle to be electrolyzed is dipped in an aqueous electrolyte of 2wt % sodium hydroxide as the anode, and the stainless steel needle with a diameter of 100 £gm as the cathode, and the electrode gap is set to be 10 £gm. Experimental results show that it is difficult to control the diameter of the tungsten needle because the reduction rate of its diameter is quite fast and the bubbles are generated violently to cause the breakage of the tungsten needle at the higher supply voltage. At the lower supply voltage, the tungsten needle can be machined to a finer scale, but it takes a long machining time. Under the single-point machining condition, it can be used to manufacture a short, uniform, and smooth tungsten needle with the diameter of 9 £gm at the supply voltage of 12V and the initial machining position of 75 £gm. Under the reciprocating machining condition, a long uniform micro-cylinder tungsten needle can be manufactured, but its surface becomes rough slightly at the supply voltage of 4V and the initial machining position in the range between -50 and 0 £gm. A tungsten needle with the aspect ratio of 30 and the diameter of 9 £gm can be manufactured using the following process: the machining time of 24 min at the supply voltage of 4V, and then the machining time of 28 min at the supply voltage of 2V. Key words¡Gtungsten needle, sodium hydroxide

Thesis (M.S.)--University of Michigan, Ann Arbor, 1974. / Typescript (photocopy). Includes bibliographical references (leaves 30-33). Also issued in print.

Thesis (Ph. D.)--University of Nebraska, 1934. / Bibliography: p. 19.

Abstract of Thesis (Ph. D.)--Ohio state University, 1925.