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Where a galaxy is located has a strong effect on its properties. The dense cluster environment is home to a large population of red, quiescent elliptical galaxies, whereas blue, star-forming, spiral galaxies are common in lower-density environments. This difference is intricately linked to the ability of the galaxy to form new stars and therefore ultimately to the fuel for star formation, the atomic and molecular gas. In this thesis, I use two large JCMT surveys to explore the effects of environment on the atomic gas, molecular gas, and star formation properties of a large sample of nearby gas-rich galaxies. From the NGLS and follow-up studies, I select a sub-sample of 98 HI-flux selected spiral galaxies. I measure their total molecular gas mass using the CO J=3-2 line and combine this data with measurements of their total atomic gas mass using the 21-cm line and star formation rate using attenuation-corrected H-alpha luminosity. I find an enhancement in the mean H2 mass and a higher H2-to-HI ratio for the Virgo Cluster sample. Virgo Cluster galaxies also have longer molecular gas depletion times (H2/SFR), which suggests that they are forming stars at a lower rate relative to their molecular gas reservoirs than non-Virgo galaxies. Next, I collect VLA 21 cm line maps from the VIVA survey and follow-up VLA studies of selected galaxies in the NGLS. I measure the surface density maps of the atomic gas, molecular gas, and star formation rate in order to determine radial trends. I find that the H2 distribution is enhanced near the centre for Virgo Cluster galaxies, along with a steeper total gas (HI + H2) radial profile. I suggest that this is due to the effects of moderate ram pressure stripping, which would strip away low-density gas in the outskirts while enhancing high-density gas near the centre. There are no trends with radius for the molecular gas depletion times, but the longer depletion times for the Virgo Cluster sample is still present. Finally, I use 850 micron continuum observations for 105 star-forming galaxies and CO J=2-1 line observations for 35 galaxies in the initial data release (DR1) of the JINGLE survey. I match the JINGLE galaxies to a SDSS group catalogue and measure environmental parameters such as the host halo mass, environment density, and location in phase space. I find that the molecular gas masses estimated from the 850 μm and CO J=2-1 line observations are well-correlated. The H2-to-HI ratio and the molecular gas depletion times do not appear to vary with stellar mass. I did not find any significant variation with environment in the DR1 sample, but I will apply this framework to the full JINGLE sample once the complete dataset is available. / Thesis / Doctor of Philosophy (PhD)

Most small asteroids are defined as "rubble-piles," or bodies with zero tensile strength and large bulk porosity that are tenuously held together by cohesive forces. Improving the accuracy of predictions of asteroid strengths requires suitable laboratory measurements of relevant materials, as well as increasing the availability of materials from sample return. In this work, we use Atomic Force Microscopy (AFM) force measurements and particle characterization to characterize, evaluate, and decouple variables that affect cohesive forces that act between micron-sized grains. In our first investigation we explored interactions of JSC-1 lunar simulant grains using three sample sizes, three spherical AFM tip diameters, and varying relative humidity, observing that the results are very dependent on the RH and, by proxy, adsorbed water. We observed weaker adhesion with larger grain/tip size, which can be attributed to the changing contact area between the samples and the tips. We next performed experiments in vacuum conditions and characterized the cohesive values of a high-fidelity CI simulant (Exolith) based on the CI1 meteorite Orgueil. Our results show no significant trend in adhesion, but we do observe that some correlating characteristics of the grains, such as roughness, can dominate the work of adhesion. The chemical nature of the grains, including their affinity for water, also played a role in if they became more adhesive in vacuum conditions or less adhesive in vacuum conditions. Our studies decouple several factors that contribute to the complex physics of adhesion and even more complex idea of understanding adhesion in a space environment with irregularly shaped grains. This approach will pave the way to a better understanding of regolith surface properties, improve contact models for irregularly shaped particles, and provide suitable inputs for models of asteroid cohesion. This analysis technique can be used on future materials provided by sample return missions.

We present a range of steady-state photoionization simulations, corresponding to different assumed shell geometries and compositions, of the unseen postulated rapidly expanding outer shell to the Crab Nebula. The properties of the shell are constrained by the mass that must lie within it, and by limits to the intensities of hydrogen recombination lines. In all cases the photoionization models predict very strong emission from high ionization lines that will not be emitted by the Crab’s filaments, alleviating problems with detecting these lines in the presence of light scattered from brighter parts of the Crab. The NIR [Ne VI] λ 7.652 mm line is a particularly good case; it should be dramatically brighter than the optical lines commonly used in searches. The C IV λ1549Å doublet is predicted to be the strongest absorption line from the shell, which is in agreement with HST observations. We show that the cooling timescale for the outer shell is much longer than the age of the Crab, due to the low density. This means that the temperature of the shell will actually “remember” its initial conditions. However, the recombination time is much shorter than the age of the Crab, so the predicted level of ionization should approximate the real ionization. In any case, it is clear that IR observations present the best opportunity to detect the outer shell and so guide future models that will constrain early events in the original explosion. Infrared observations have discovered a variety of objects, including filaments in the Crab Nebula and cool-core clusters of galaxies, where the H2 1-0 S(1) line is stronger than the infrared H I lines. A variety of processes could be responsible for this emission. Although many complete shock or PDR calculations of H2 emission have been published, we know of no previous simple calculation that shows the emission spectrum and level populations of thermally excited low-density H2. We present a range of purely thermal collisional simulations, corresponding to constant gas kinetic temperature at different densities. We consider the cases where the collisions affecting H2 are predominantly with atomic or molecular hydrogen. The resulting level population (often called “excitation”) diagrams show that excitation temperatures are sometimes lower than the gas kinetic temperature when the density is too low for the level populations to go to LTE. The atomic case goes to LTE at much lower densities than the molecular case due to larger collision rates. At low densities for the v=1 and 2 vibrational manifolds level populations are quasi-thermal, which could be misinterpreted as showing the gas is in LTE at high density. At low densities for the molecular case the level population diagrams are discontinuous between v=0 and 1 vibrational manifolds and between v=2, J=0, 1 and other higher J levels within the same vibrational manifold. These jumps could be used as density diagnostics. We show how much the H2 mass would be underestimated using the H2 1-0 S(1) line strength if the density is below that required for LTE. We give diagnostic diagrams showing level populations over a range of density and temperature. The density where the level populations are given by a Boltzmann distribution relative to the total molecular abundance (required to get the correct H2 mass), is shown for various cases. We discuss the implications of these results for the interpretation of H2 observations of the Crab Nebula and filaments in cool-core clusters of galaxies.

The interstellar medium (ISM) of our Galaxy, and of others, is pervaded by ultra low-density gas and dust, as well as magnetic fields. Embedded magnetic fields have been known to play an important role in the structure and dynamics of the ISM. However, the ability to accurately quantify these fields has plagued astronomers for many decades. Unfortunately, the experimental techniques for measuring the strength and direction of magnetic fields are few, and they are observationally challenging. The only direct method of measuring the magnetic field is through the Zeeman effect. The goal of this dissertation is to expand upon the current observational studies and understanding of the effects of interstellar magnetic fields across various regions of the Galaxy. Zeeman effect observations of magnetic fields in two dynamically diverse environments in the Milky Way are presented: (1) An OH and HI absorption line study of envelopes of molecular clouds distributed throughout the Galaxy, and (2) A study of OH absorption lines toward the Galactic center region in the vicinity of the supermassive black hole Sgr A*. We have executed the first systematic observational survey designed to determine the role of magnetic fields in the inter-core regions of molecular clouds. Observations of extragalactic continuum sources that lie along the line-of-sight passing through Galactic molecular clouds were studied using the Arecibo telescope. OH Zeeman effect observations were combined with estimates of column density to allow for computation of the mass-to-flux ratio, a measurement of the gravitational to magnetic energies within a cloud. We find that molecular clouds are slightly subcritical overall. However, individual measurements yield the first evidence for magnetically subcritical molecular gas. Jansky VLA observations of 18 cm OH absorption lines were used to determine the strength of the line-of-sight magnetic field in the Galactic center region. This study yields no clear detections of the magnetic field and results that differ from a similar study by Killeen, Lo, & Crutcher (1992). Our results suggest magnetic fields no more than a few microgauss in strength.

Os eletrocatalisadores de PtSn/C-ITO foram preparados pelo método de redução via borohidreto de sódio com uma carga metálica de 20% em massa suportados em carbono Vulcan XC72 e óxidos de estanho e índio (ITO) nas seguintes composições; 50:50, 70:30 e 90:10. Os eletrocatalisadores foram submetidos a análises de caracterização por difração de raios-x (DRX), microscopia de transmissão eletrônica (MET), espectroscopia de energia dispersiva de raios x (EDX) e análises eletroquímicas pelas técnicas de voltametria cíclica e de amperometria para os estudos da oxidação eletroquímica em etanol. Nas técnicas eletroquímicas foi utilizado o eletrodo de camada fina porosa onde os eletrocatalisadores foram testados tanto no meio ácido quanto no meio alcalino. Experimentos em célula unitária alimentadas diretamente por etanol foram testados simulando condições reais de operação. As análises eletroquímicas e de caracterização física em meio ácido permitiram comparar o desempenho e estabilidades dos eletrocatalisadores em estudo e também demonstraram os benefícios da adição do estanho e do ITO, tendo como destaque o eletrocatalisador de PtSn/C-ITO 70:30. Em meio alcalino o eletrocatalisador PtSn/C-ITO 50:50 demonstrou ter o melhor desempenho nas análises de voltametria cíclica e amperometria, entretanto, a mesma eficácia não ocorreu nos experimentos em célula unitária o que leva a crer que em meio alcalino o mecanismo de oxidação do etanol sob temperatura e outros parâmetros reais pertinentes à operação da célula precisam ser mudados e/ou estudados. / PtSn /C-ITO electrocatalysts were prepared by the sodium borohydride reduction method with 20% mass metallic load supported on Vulcan XC72 carbon and tin and indium oxides (ITO) in the following compositions; 50:50, 70:30 and 90:10. The electrocatalysts were subjected to x-ray diffraction characterization (XRD), transmission electron microscope (TEM), energy dispersive x-ray spectroscopy (EDX) and electrochemical analyzes using cyclic voltammetry and amperometric techniques for studies of ethanol electrochemical oxidation. In the electrochemical techniques the thin porous coating was used where the electrocatalysts were tested in both the acidic and alkaline media. Experiments in unit cell fed directly by ethanol were tested simulating real operating conditions. The electrochemical and physical characterization analyzes in acid medium allowed to compare the performance and stabilities of the electrocatalysts under study and also demonstrated the benefits of the addition of tin and ITO, with emphasis at PtSn/C-ITO 70:30 electrocatalyst. In alkaline media the PtSn/C-ITO 50:50 electrocatalyst demonstrated the best performance in the tests of cyclic voltammetry and amperometry, however, the same efficiency did not happen in the unit cell tests which leads to believe that in alkaline medium the oxidation mechanism of ethanol under temperature and other actual pertinent parameters to cell operation need to be changed and/or studied.

The intergalactic medium is kept highly photoionised by the intergalactic UV background radiation field generated by the overall population of quasars and galaxies. In the vicinity of sources of UV photons, such as luminous high-redshift quasars, the UV radiation field is enhanced due to the local source contribution. The higher degree of ionisation is visible as a reduced line density or generally as a decreased level of absorption in the Lyman alpha forest of neutral hydrogen. This so-called proximity effect has been detected with high statistical significance towards luminous quasars. If quasars radiate rather isotropically, background quasar sightlines located near foreground quasars should show a region of decreased Lyman alpha absorption close to the foreground quasar. Despite considerable effort, such a transverse proximity effect has only been detected in a few cases. So far, studies of the transverse proximity effect were mostly limited by the small number of suitable projected pairs or groups of high-redshift quasars. With the aim to substantially increase the number of quasar groups in the vicinity of bright quasars we conduct a targeted survey for faint quasars around 18 well-studied quasars at employing slitless spectroscopy. Among the reduced and calibrated slitless spectra of 29000 objects on a total area of 4.39 square degrees we discover in total 169 previously unknown quasar candidates based on their prominent emission lines. 81 potential z>1.7 quasars are selected for confirmation by slit spectroscopy at the Very Large Telescope (VLT). We are able to confirm 80 of these. 64 of the newly discovered quasars reside at z>1.7. The high success rate of the follow-up observations implies that the majority of the remaining candidates are quasars as well. In 16 of these groups we search for a transverse proximity effect as a systematic underdensity in the HI Lyman alpha absorption. We employ a novel technique to characterise the random absorption fluctuations in the forest in order to estimate the significance of the transverse proximity effect. Neither low-resolution spectra nor high-resolution spectra of background quasars of our groups present evidence for a transverse proximity effect. However, via Monte Carlo simulations the effect should be detectable only at the 1-2sigma level near three of the foreground quasars. Thus, we cannot distinguish between the presence or absence of a weak signature of the transverse proximity effect. The systematic effects of quasar variability, quasar anisotopy and intrinsic overdensities near quasars likely explain the apparent lack of the transverse proximity effect. Even in absence of the systematic effects, we show that a statistically significant detection of the transverse proximity effect requires at least 5 medium-resolution quasar spectra of background quasars near foreground quasars whose UV flux exceeds the UV background by a factor 3. Therefore, statistical studies of the transverse proximity effect require large numbers of suitable pairs. Two sightlines towards the central quasars of our survey fields show intergalactic HeII Lyman alpha absorption. A comparison of the HeII absorption to the corresponding HI absorption yields an estimate of the spectral shape of the intergalactic UV radiation field, typically parameterised by the HeII/HI column density ratio eta. We analyse the fluctuating UV spectral shape on both lines of sight and correlate it with seven foreground quasars. On the line of sight towards Q0302-003 we find a harder radiation field near 4 foreground quasars. In the direct vicinity of the quasars eta is consistent with values of 25-100, whereas at large distances from the quasars eta>200 is required. The second line of sight towards HE2347-4342 probes lower redshifts where eta is directly measurable in the resolved HeII forest. Again we find that the radiation field near the 3 foreground quasars is significantly harder than in general. While eta still shows large fluctuations near the quasars, probably due to radiative transfer, the radiation field is on average harder near the quasars than far away from them. We interpret these discoveries as the first detections of the transverse proximity effect as a local hardness fluctuation in the UV spectral shape. No significant HI proximity effect is predicted for the 7 foreground quasars. In fact, the HI absorption near the quasars is close to or slightly above the average, suggesting that the weak signature of the transverse proximity effect is masked by intrinsic overdensities. However, we show that the UV spectral shape traces the transverse proximity effect even in overdense regions or at large distances. Therefore, the spectral hardness is a sensitive physical measure of the transverse proximity effect that is able to break the density degeneracy affecting the traditional searches. / Das intergalaktische Medium wird durch das intergalaktische UV-Hintergrundsstrahlungsfeld in einem hochgradig photoionisierten Zustand gehalten. Der UV-Hintergrund stammt von der gesamten Population von Quasaren und Galaxien. In der Nähe von leuchtkräftigen Quasaren, ist das UV-Strahlungsfeld lokal erhöht durch den Anteil der Quelle. Der höhere Ionisationsgrad ist beobachtbar als eine reduzierte Liniendichte oder allgemein als ein vermindertes Maß an Absorption im Lyman-alpha Wald des neutralen Wasserstoffs. Dieser sogenannte Proximity-Effekt ist bei leuchtkräftigen Quasaren mit hoher statistischer Signifikanz nachgewiesen worden. Falls Quasare fast isotrop strahlen, dann sollten Sichtlinien zu Hintergrundquasaren in der Nähe von Vordergrundquasaren eine Region mit verminderter Absorption zeigen. Trotz beträchtlichen Aufwands wurde solch ein transversaler Proximity-Effekt nur in wenigen Fällen entdeckt. Bisher waren Studien des transversalen Proximity-Effekts meist begrenzt durch die kleine Anzahl von geeigneten projizierten Paaren oder Gruppen von hochrotverschobenen Quasaren. Mit dem Ziel die Zahl der Quasargruppen in der Nähe von hellen Quasaren beträchtlich zu erhöhen, führen wir eine gezielte Suche nach schwachen Quasaren um 18 oft studierte Quasare durch. Unter den reduzierten und kalibrierten spaltlosen Spektren von 29000 Objekten auf einer Gesamtfläche von 4.39 Quadratgrad entdecken wir insgesamt 169 vorher unbekannte Quasarkandidaten anhand ihrer Emissionslinien. 81 potentielle z>1.7 Quasare werden ausgesucht zur Bestätigung mittels Spaltspektroskopie am Very Large Telescope (VLT). Wir können 80 von diesen als Quasare bestätigen. 64 der neu entdeckten Quasare liegen bei z>1.7. Die hohe Erfolgsrate der Nachfolgebeobachtungen deutet an, dass die Mehrzahl der verbleibenden Kandidaten ebenfalls Quasare sind. In 16 dieser Gruppen suchen wir nach dem transversalen Proximity-Effekt als eine systematische Unterdichte in der HI Lyman-alpha-Absorption. Wir nutzen eine neuartige Methode die zufälligen Absorptionsfluktuationen zu charakterisieren, um die Signifikanz des transversalen Proximity-Effekts abschätzen zu können. Weder schwach aufgelöste noch hoch aufgelöste Spektren von Hintergrundquasaren unserer Gruppen zeigen Anzeichen für einen transversalen Proximity-Effekt. Aufgrund von Monte Carlo Simulationen sollte der Effekt jedoch nur schwach in der Nähe von 3 Vordergrundquasaren detektierbar sein. Deshalb können wir nicht zwischen An- oder Abwesenheit des Effekts unterscheiden. Selbst in Abwesenheit von systematischen Effekten zeigen wir, dass eine statistisch signifikante Detektion des transversalen Proximity-Effekts mindestens 5 Hintergrundquasarspektren bei mittlerer Auflösung nahe Vordergrundquasaren erfordert, deren UV-Fluss den UV-Hintergrund um einen Faktor 3 übersteigt. Deshalb erfordern statistische Studien des transversalen Proximity-Effekts große Zahlen von geeigneten Quasaren. Zwei Sichtlinien zeigen HeII-Absorption. Ein Vergleich der HeII-Absorption mit der entsprechenden HI-Absorption liefert eine Abschätzung der Spektralform des UV-Strahlungsfelds, das typischerweise durch das HeII/HI Säulendichteverhältnis eta parameterisiert wird. Wir analysieren die fluktuierende spektrale Form des UV-Strahlungsfelds auf beiden Sichtlinien und korrelieren sie mit 7 Vordergrundquasaren. Auf der Sichtlinie zu Q0302-003 finden wir ein härteres Strahlungsfeld nahe 4 Vordergrundquasaren. In der direkten Umgebung der Quasare ist eta konsistent mit Werten von 25-100, wogegen bei großen Entfernungen zu den Quasaren eta>200 erforderlich ist. Die zweite Sichtlinie zu HE2347-4342 sondiert kleinere Rotverschiebungen. Wieder finden wir, dass das Strahlungsfeld nahe der 3 Vordergrundquasaren signifikant härter ist als im allgemeinen. Während eta trotzdem große Fluktuationen nahe den Quasaren aufweist, die wahrscheinlich von Strahlungstransport herrühren, ist das Strahlungsfeld in der Nähe der Quasare im Mittel härter als in großer Entfernung. Wir interpretieren diese Entdeckungen als die ersten Detektionen des transversalen Proximity-Effekts als eine lokale Fluktuation im spektralen Härtegrad. Kein signifikanter HI Proximity-Effekt ist für die 7 Vordergrundquasare vorhergesagt. Tatsächlich ist die HI-Absorption nahe den Quasaren nahe am oder etwas über dem Mittelwert, was darauf hindeutet, dass die schwache Signatur des transversalen Proximity-Effekts maskiert wird durch intrinsische Überdichten. Jedoch zeigen wir, dass der Härtegrad den transversalen Proximity-Effekt selbst in überdichten Regionen oder auf großen Distanzen sichtbar werden läßt. Deshalb ist der spektrale Härtegrad ein empfindliches physikalisches Maß für den transversalen Proximity-Effekt, der in der Lage ist, die Dichteentartung zu brechen, die die traditionelle Suche behindert.

After the epoch of reionisation the intergalactic medium (IGM) is kept at a high photoionisation level by the cosmic UV background radiation field. Primarily composed of the integrated contribution of quasars and young star forming galaxies, its intensity is subject to spatial and temporal fluctuations. In particular in the vicinity of luminous quasars, the UV radiation intensity grows by several orders of magnitude. Due to an enhanced UV radiation up to a few Mpc from the quasar, the ionised hydrogen fraction significantly increases and becomes visible as a reduced level of absorption in the HI Lyman alpha (Ly-alpha) forest. This phenomenon is known as the proximity effect and it is the main focus of this thesis. Modelling the influence on the IGM of the quasar radiation, one is able to determine the UV background intensity at a specific frequency (J_nu_0), or equivalently, its photoionisation rate (Gamma_b). This is of crucial importance for both theoretical and observational cosmology. Thus far, the proximity effect has been investigated primarily by combining the signal of large samples of quasars, as it has been regarded as a statistical phenomenon. Only a handful of studies tried to measure its signature on individual lines of sight, albeit focusing on one sight line only. Our aim is to perform a systematic investigation of large samples of quasars searching for the signature of the proximity effect, with a particular emphasis on its detection on individual lines of sight. We begin this survey with a sample of 40 high resolution (R~45000), high signal to noise ratio (S/N~70) quasar spectra at redshift 2.1<z<4.7, publicly available in the European Southern Observatory (ESO) archive. The extraordinary quality of this data set enables us to detect the proximity effect signature not only in the combined quasar sample, but also along each individual sight line. This allows us to determine not only the UV background intensity at the mean redshift of this sample, but also to estimate its intensity in small (Delta z~0.2) redshift intervals in the range 2<z<4. Our estimates (J_nu_0~ 3x10^{-22} erg s^{-1} cm^{-2} Hz^{-1} sr^{-1}) are for the first time in very good agreement with different constraints of its evolution obtained from theoretical predictions and numerical simulations. We continue this systematic analysis of the proximity effect with the largest search to date invoking the Sloan Digital Sky Survey (SDSS) data set. The sample consists of 1733 quasars at redshifts z>2.3. In spite of the low resolution and limited S/N we detect the proximity effect on about 98% of the quasars at a high significance level. Thereby we are able to determine the evolution of the UV background photoionisation rate within the redshift range 2<z<5 finding Gamma_b~ 1.6x10^{-12} s^{-1}. With these new measurements we explore literature estimates of the quasar luminosity function and predict the stellar luminosity density up to redshift of about z~5. Our results are globally in good agreement with recent determinations inferred from deep surveys of high redshift galaxies. We then compare our measurements on the UV background photoionisation rate inferred from the two samples at high and low resolution. While these data sets show extreme differences, our determinations are in considerable agreement at z<3.3, even though they show less agreement at higher redshifts. We suspect that this may be caused by either the small number of high resolution quasar spectra at the highest redshifts considered or by some systematic effect due to the limited data quality of SDSS. Complementary to the observational investigation of the proximity effect on high redshift quasars, we exploit some theoretical aspects linked to and based on the results on this phenomenon. We employ complex numerical simulations of structure formation to achieve a better representation of the Ly-alpha forest. Modelling the signature of the proximity effect on randomly selected sight lines, we prove the advantages of dealing with individual lines of sight instead of combining their signal to investigate this phenomenon. Furthermore, we develop and test novel techniques aimed at a more precise determination of the proximity effect signal. With this investigation we demonstrate that the technique developed and employed in this thesis is the most accurate adopted thus far. Tighter determinations of the UV background are certainly based on suitable methods to detect its signature, but also on a deeper understanding of the environments in which quasars form and evolve. We initiate an investigation of complex numerical simulations including the radiative transport of energy to model in a more detailed way the proximity effect. Such a simulation may lead to the characterisation of the quasar environment based on the comparison between the observed and simulated statistical properties of the proximity effect signature. / Nach dem kosmologischen Zeitalter der Reionisation wird der hohe Photoionisationsgrad des intergalaktische Mediums (IGM) durch die kosmische UV-Hintergrundstrahlung aufrecht erhalten. Zur Intensitaet der Hintergrundstrahlung tragen hauptsaechlich Quasare und jungen Galaxien bei. Daher entstehen sowohl raeumliche als auch zeitliche Fluktuationen, wobei die Intensistaet insbesondere in der Naehe von leuchtkraeftigen Quasaren um mehrere Groessenordnungen ansteigt. Aufgrund der erhoehten UV-Strahlung in einer Entfernung von bis zu einigen Mpc von einem Quasar wird ein groesserer Anteil des intergalaktischen Wasserstoffs ionisiert, was als reduzierte Absorption im Lyman alpha (Ly-alpha) Wald sichtbar wird. Dieses Phaenomen wird proximity effect genannt und ist das Hauptthema dieser Arbeit. Durch Modellierung des Einflusses des Quasars auf das IGM kann die Intensitaet des UV-Hintergrunds bei einer bestimmten Frequenz (J_nu_0) bzw. die entsprechende Photoionisationrate (Gamma_b) bestimmt werden. Dies ist sowohl fuer die theoretische als auch fuer die beobachtende Kosmologie eine wichtige Groesse. Bisher wurde der Proximity-Effekt als ein statistisches Phaenomen untersucht, wobei die Signale vieler einzelner Quasare kombiniert wurden. Nur in wenigen Analysen wurde versucht, den Effekt in einzelnen Sehlinien zu detektieren. Das Ziel dieser Arbeit ist eine systematische Untersuchung des Proximity-Effekts in einer grossen Anzahl von Quasaren, wobei der besonderen Schwerpunkt auf seiner Detektion in einzelnen Sehlinien liegt. Zunaechst werden 40 Quasare im Rotverschiebungsbereich 2.1<z<4.7 untersucht, deren Spektren mit hoher Aufloesung (R=45000) und hohem Signal-zu-Rausch-Verhaeltnis (S/N~70) im Archiv des European Southern Observatory (ESO) vorliegen. Die ausserordentlich gute Qualitaet dieser Daten ermoeglicht die Detektion des Proximity-Effekts nicht nur als kombiniertes Signal aller Quasare sondern auch in jeder einzelnen Sehlinie. Daher konnten wir nicht nur die Intensitaet des UV-Hintergrunds bei der mittleren Rotverschiebung ermitteln sondern auch in kleineren Rotverschiebungsintervallen (Delta z~0.2) im Bereich 2<z<4. Unsere Ergebnisse (J_nu_0}~3x10^{-22} erg s^{-1} cm^{-2} Hz^{-1} sr^{-1}) stimmen zum ersten Mal gut anderen Bestimmungen ueberein, die auf theoretischen Voraussagen und auf numerischen Simulationen beruhen. Unsere systematische Analyse des Proximity-Effekts wird mit dem bisher groessten Datensatz bestehend aus 1733 Quasaren mit Rotverschiebungen z>2.3 aus dem Sloan Digital Sky Survey (SDSS) fortgefuehrt. Trotz der niedrigen Aufloesung und dem begrenzten S/N detektieren wir den Proximity-Effekt mit einer hohen Signifikanz in etwa 98% der Sehlinen. Dabei kann die Entwicklung der Photoionisationsrate Gamma_b~1.6x10^{-12} s^{-1} im Rotverschiebungsbereich 2<z<5 bestimmt werden. Mit diesen neuen Messungen diskutieren wir verschiedene Quasar-Leuchtkraftfunktionen aus der Literatur und berechnen die stellare Emissivitaet bis z~5. Unsere Ergebnisse stimmen im Allgemeinen gut mit denen von neueren Himmelsdurchmusterungen nach hochrotverschobenen Galaxien ueberein. Dann vergleichen wir die auf den hoch bzw. niedrig aufgeloesten Spektren basierenden Photoionisationsraten miteinander. Obwohl die Datensaetze sehr unterschiedlich sind, fuehren sie bei z<3.3 zu den selben Ergebnissen, waehrend die Resultate bei hoeheren Rotverschiebungen weniger gut uebereinstimmen. Wir vermuten, dass dies entweder durch die kleine Anzahl von hochaufgeloesten Quasarspektren bei den hoechsten Rotverschiebungen, oder durch systematische Effekte der geringen SDSS Datenqualitaet hervorgerufen wird. Ergaenzend zu der Auswertung der Beobachtungsdaten fuehren wir basierend auf unseren Ergebnissen einige theoretische Untersuchugen durch. Wir benutzen komplexe Strukturbildungssimulationen, um eine bessere Beschreibung des Ly-alpha-Walds zu gewinnen. Mit Hilfe der Modellierung des Proximity-Effekts in zufaellig ausgesuchten Sehlinien zeigen wir den Vorteil auf, den die Analyse einzelner Sehlinien im Vergleich zur kombinierten Auswertung mehrerer Spektren hat. Ausserdem entwickeln und testen wir neue Ansaetze zur genaueren Bestimmung des Proxmity-Effekts. Dabei zeigen wir, dass die im Rahmen dieser Arbeit entwickelte und angewendete Methode bisher zu den genauesten Ergebnissen fuehrt. Fuer eine noch bessere Bestimmung des UV-Hintergurnds brauchen wir neben der optimalen Detektionsmethode auch ein tieferes Verstaendnis der Umgebung, in der Quasare entstehen und sich entwickeln. Wir beginnen eine Analyse komplexer numerischer Simulationen, die auch Strahlungstransportrechungen beinhalten, um weitere Details des Proximity-Effekts zu verstehen. Der Vergleich der statistischen Eigenschaften des Proximity-Effekts in solchen Simulationen mit Beobachtungen koennte in Zukunft zu einer genaueren Beschreibung der Umgebung von Quasaren fuehren.