Chromatographic measurements were made for the adsorption of benzene, toluene and m-xylene on molecular sieving carbon (MSC) in a supercritical fluid CO2 mixed with organics. A supercritical chromatograph packed with MSC was used to detect pulse responses of the organics. Adsorption equilibria and adsorption dynamic parameters for organics were obtained by moment analysis of the response peaks. Dependences of adsorption equilibrium constants, K*, and micropore diffusivity, D, on the amount adsorbed were examined. The dependencies of adsorption equilibrium constants, K*, and micropore diffusivities, D, for benzene, toluene and m-xylene, on the molarity of benzene over a range of temperature and pressure were obtained. Experimental results were simulated using the “Stop & Go” method as well as by molecular simulation.

Gas diffusion in nanoporous carbon includes distinct diffusion modes: surface diffusion on the pore walls and non-surface diffusion away from pore walls. We have performed molecular dynamics (MD) simulations of Ar diffusion in disordered nanoporous carbon. The main objective of this work is to separate the surface diffusion and non-surface diffusion contributions so as to comprehend their respective dependency on the porous structure and testing conditions. The nanoporous carbon sample is obtained using the quenched molecular dynamics (QMD) method. Gas flows are generated by applying a constant external force on each Ar atom, mimicking a constant chemical potential gradient. The contributions from surface diffusion and non-surface diffusion are separated according to the distance of the gas atoms away from the pore wall. We show that the surface diffusivity is affected by the interactions between gas atoms and the pore walls, the temperature, and the loading.

Diffusion of tetrafluoromethane in aluminosilicate nanotubes was studied by means of 13C pulsed field gradient (PFG) NMR at 297 K. The measured data allow the estimation of the diffusivity of tetrafluoromethane inside the nanotubes as well as the diffusivity for these molecules undergoing fast exchange between many nanotubes. The results support the assumption about the one-dimensional nature of the tetrafluoromethane diffusion inside nanotubes.

In the modelling of translational motion, the concepts of frequency-dependent (of the angular fluctuations of the velocity field) self-diffusion and the dispersion tensor are commonly used in its characterisation. Both of these parameters are related to velocity autocorrelation. An alternative means of modelling translational motion is via the equilibrium and nonequilibrium fluctuation-dissipation theorem in classical statistical mechanics. This alternative approach provides further insight into the molecular level processes occurring in the system. Here both of these theoretical fluctuation-dissipation approaches are employed to determine expressions for energy dissipation in simple equilibrium systems exhibiting asymptotic and preasymptotic diffusion and dispersion phenomena and also in a nonequilibrium preasymptotic system involving dispersion within and beyond the upper limit of heterogeneity of an isotropic porous medium. As an example the permeability of porous media due to diffusion and dispersion are studied and it is shown how a frequency-dependent permeability can be treated as a phasor.

Ni based superalloys can be welded by diffusion bonding. Temperature, diffusion coefficient, activation energy and Boltzmann constant influence the quality of diffusion bonding, so obtaining the best condition for welding is considered. Showing the suitable condition for diffusion welding of nickel-based superalloys is the aim of this paper.

The LDD model was first applied to Arsenic concentration profiles determined in surface diffusion experiments by Yoshida and Arai [1]. The new method presented is based on a mathematical convolution with a delta-function-like concentration profile. By comparing the LDD approximation of post-surface diffusion with post-implant diffusion experiments, the same LDD model parameter r is found to hold for both experimental arrangements. This work found that post-implant diffusivity is concentration dependant and this might indicate an anomalous diffusion mechanism for Arsenic.

The solvent resistance properties of the unsaturated polyster and their montmorillonite filled nanocomposites are studied in acetic through equilibrium swelling method at different temperatures. The kinetics of sorption is studied by using the equation of transport phenomena. The values of ‘n’ in solvent transport equation are found to be below ‘0.5’, showing the non-Fickian or pseudo-Fickian transport in the polymer. The dependence of diffusion coefficient on composition and temperature has been studied for all polymeric samples. The diffusion coefficient of unsaturated polyester samples decreases with an increase in unsaturated acid content. The nanocomposite samples show low diffusion coefficient than corresponding pristine polymers. The diffusion coefficient, sorption coefficient and permeation coefficient increase with an increase in temperature for all samples. The crosslink density for neat polymer with varied unsaturated acid content ranges from 2.98 to 3.52 ×105mol/cm3. For the nanocomposite samples it ranges from 3.70 to 5.72 × 105 mol/cm3.

A number of random processes in various fields of science is described by phenomenological equations of motion containing stochastic forces, the best known example being the Langevin equation (LE) for the Brownian motion (BM) of particles. Long ago Vladimirsky (1942) in a little known paper proposed a simple method for solving such equations. The method, based on the classical Gibbs statistics, consists in converting the stochastic LE into a deterministic equation for the mean square displacement of the particle, and is applicable to linear equations with any kind of memory in the dynamics of the system. This approach can be effectively used in solving many of the problems currently considered in the literature. We apply it to the description of the BM when the noise driving the particle is exponentially correlated in time. The problem of the hydrodynamic BM of a charged particle in an external magnetic field is also solved.

A method for rapid acquisition of multiple scans of NMR sequences is presented. The method initially applies two RF-pulses in combination with two magnetic field gradient pulses of opposite polarity, different strength and different duration. The basic idea is to spoil any magnetization in any direction before by letting the system recover to some degree of restoration of the thermal equilibrium magnetization. Thereafter any pulse sequence can be applied, and the next scan may be run immediately after the end of the pulse sequence. Thus one avoids the 5 times T1 delay between each scan. A set of PFG sequences are presented that apply the spoiler recovery method for significant reduction in acquisition time, and the method has been verified at 0.5 Tesla as well as at 11.7 Tesla.

Starch is a highly disperse material with broad distributions of molecular sizes and geometries. Its dissolution in aqueous media is difficult to achieve and it tends to form aggregates through both inter- and intra-molecular interactions. Asymmetrical flow field-flow fractionation (AF4) is a suitable technique for the separation of such macromolecular and colloidal systems. A major advantage of AF4 is the direct correlation of translational diffusion coefficients with retention time and experimental parameters. In this article, the hydrodynamic and diffusive mobility of normal corn starch dissolved in 0.035 M KSCN was investigated by systematically varying the cross flow rates (applied forces); the translational diffusion coeffcients for normal corn starch in aqueous medium were found to range between 9.9 x 10-9 cm2/s and ~2.5 x 10-7 cm2/s with varying Fcr rates. Diffusion coefficient ranges shifted to higher diffusion co-efficient values at higher cross flow rates (applied forces). This behaviour, which may be attributed to the increased retention of very large starch molecules/particles at high Fcr rates, is further confirmed by the decrease in apparent molar mass and mass recovery values.