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Ediacaran iron formations and carbonates from Uruguay: palaeoceanographic, palaeoclimatic and palaeobiologic implicationsPecoits, Ernesto 11 1900 (has links)
The Ediacaran in Uruguay preserves a unique record of deposits generated during the assembly of the palaeocontinent Gondwana and concurrent with major changes in the atmosphere and oceans, and the rise of animal life.
Recent studies have suggested that the deep oceans remained anoxic and highly ferruginous throughout the Ediacaran and possibly into the Cambrian. Unfortunately, acceptance of this idea has been hindered by the virtual absence of iron formations (IF). Detailed studies of Ediacaran IF in Uruguay confirm that ferruginous conditions dominated the pre-Gaskiers (~580 Ma), and interestingly, they also extended well into the upper Ediacaran before complete ocean ventilation occurred. Significantly, a simple twolayer
stratified system that argues for an oxygenated surface layer overlying a suboxic zone is proposed.
The association of negative 13C excursions in Neoproterozoic carbonates and large-scale glaciations has become a tempting explanation for the short-term perturbation of the global carbon cycle. Not surprisingly, negative 13C shifts in Ediacaran-aged carbonates from Uruguay have been interpreted as recording post-Gaskiers glacial events. New highresolution 13C-chemostratigraphy of carbonates shows negative fractionations in deep facies with a progressive rise towards shallow-water settings, and suggests a deposition across a stratified ocean. Furthermore, 87Sr/86Sr chemostratigraphy coupled with radiometric data allowed a more precise chronostratigraphy, which supports an age of
~600-575 Ma for the unit, and suggests a deposition concurrent with the Gaskiers glaciation. Notwithstanding whether associated 13C variations in shallow water facies were produced by glacially-related conditions or by the dynamic of the basin itself remains unresolved. Although these conclusions are particularly valid for these deposits, they carry important implications for the understanding of other negative 13C excursions recorded in the Precambrian.
Finally, bilaterian burrows occur in Gaskiers age glaciomarine rocks in Uruguay implying that these are the oldest definite animal tracks yet reported. Crucially, our new discovery unites the palaeontological and molecular data pertaining to the origin of bilaterians, and brings the origin of animals firmly into the interval of the Neoproterozoic glaciations. It also implies that ancestral bilaterians likely evolved first in relatively shallow seas, and only colonized the deep-sea floor once sufficient bottom water
oxygenation had taken place.
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Ediacaran iron formations and carbonates from Uruguay: palaeoceanographic, palaeoclimatic and palaeobiologic implicationsPecoits, Ernesto Unknown Date
No description available.
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Phosphate and Arsenic Cycling under Experimental Early Proterozoic Marine ConditionsHemmingsson, Christoffer January 2017 (has links)
Nutrient dynamics in the Archean-Paleoproterozoic oceans strongly influenced primary productivity and the rise of atmospheric O2. Reconstructing the cycling of key nutrients such as dissolved inorganic phosphate (DIP) at this time is important for our understanding of the timing, rate and extent of atmospheric oxygenation at this time. Banded iron formations (BIF) can be used as proxies for global DIP content in Precambrian marine waters. Estimating Precambrian DIP requires understanding of the mechanisms by which Fe(III)(oxyhydr)oxides scavenge DIP which has come mainly from experimental studies using NaCl solutions that mimick Precambrian marine conditions with for example, elevated Si and Fe(II) concentrations. The two DIP binding modes suggested for Early Proterozoic marine waters are 1) Adsorption - surface attachment on pre-formed Fe(III) (oxyhydr)oxides, and 2) Coprecipitation - incorporation of P into actively growing Fe(III) (oxyhydr)oxides. It has been suggested that the elevated Si concentrations suggested for Precambrian seawater, strongly inhibit adsorption of DIP in Fe(III)(oxyhydr)oxides. However recent coprecipitation experiments show that DIP is strongly scavenged by Fe(III)(oxyhydr)oxides in the presence of Si, seawater cations and hydrothermal As. In this study we show that the DIP uptake onto Fe(III)(oxyhydr)oxides by adsorption is less than 5% of that by coprecipitation. The data imply that in the Early Proterozoic open oceans, the precipitation of Fe(III)(oxyhydr)oxides during mixing of deep anoxic Fe(II)-rich waters with oxygenated ocean surface waters caused DIP removal from surface waters through coprecipitation rather than adsorption. Local variations in DIP and perhaps even stratification of DIP in the oceans were likely created from the continuous removal of DIP from surface waters by Fe(III)(oxyhydr)oxides, and its partial release into the anoxic bottoms waters and in buried sediments. In addition to a DIP famine, the selectivity for DIP over As(V) may have led to As enrichment in surface waters both of which would have most likely decreased the productivity of Cyanobacteria and O2 production. / Näringscirkulationen i haven under arkeikum och paleoproterozoikum påverkade primärproduktionen och uppkomsten av atmosfärisk syrgas (O2). För att förstå när och hur fort koncentrationen av O2 i atmosfären ökade behöver vi rekonstruera hur viktiga näringsämnen, t.ex. löst oorganiskt fosfor (engelska “Dissolved Inorganic Phosphorous”, DIP) cirkulerade. Bandad järnmalm (engelska “Banded Iron Formations”, BIF) kan användas som en markör för DIP i de prekambriska haven. För att kunna använda DIP som markör måste man förstå hur prekambrisk DIP tas upp av järn(III)(oxyhydr)oxider. Hittills har detta studerats med natriumkloridlösningar som ska efterlikna förhållande i de prekambriska haven, med t.ex. förhöjda kisel- och järn(II)-koncentrationer. Ur sådana studier har två bindningsmekanismer föreslagits för paleoproterozoiskt havsvatten 1) Adsorption, d.v.s. DIP binds till ytan på redan bildade kristaller av järn(III)(oxyhydr)oxid, och 2) samutfällning, d.v.s. upptag av fosfor i kristaller av järn(III)(oxyhydr)oxid medan kristallerna bildas. Det har föreslagits att de höga kiselkoncentrationerna som tros ha funnits i de prekambriska havsvattnet hämmade adsorption av DIP på ytan av järn(III) (oxyhydr)oxidkristaller. Men de senaste samutfällningsexperimenten tyder på att järn(III) (oxyhydr)oxid effektivt tar upp DIP även i närvaro av kisel, arsenik från hydrotermala källor och de katjoner som dominerar i havsvatten. I här presenterad studie var mängden DIP som bands till järn(III)(oxyhydr)oxidkristaller genom adsorption mindre än 5 % av den DIP som togs upp av kristallerna via samutfällning. Våra data tyder på att när järn(III) (oxyhydr)oxid fälldes ut i tidiga-proterozoiska hav när järn(II)-rikt djupvatten blandades med syrerikt ytvatten, och att DIP avlägsnades från ytvattnet genom samutfällning snarare än adsorption. Lokala variationer av DIP-koncentrationer i haven, möjligen även skiktning, kan ha orsakats av kontinuerlig utfällning av järn(III)(oxyhydr)oxider ur ytvattnet följt av partiell frigörelse av DIP i syrefria djupvatten och sediment. Kristallisationsprocessen, som gynnar inbindning av DIP och misgynnar inbinding av arsenik (V) kan ha orsakat brist av DIP och anrikning av arsenik i ytvattnet, vilket troligen minskade tillväxten av cyanobakterier med lägre syrgasproduktion som följd. / CLAPO
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Petrography and Provenance of an Archean Conglomerate Manitou Lake Northwestern OntarioTeal, Suzanne E. 05 1900 (has links)
<p> The Archean "Loose Pebble Bay" conglomerate, Manitou Lake, northwestern Ontario, contains a variety of clast types, not all of which can be readily ascribed to local lithologies. This study was undertaken to determine the modal clast composition of the conglomerate, and
investigate the origin of the clasts. The conglomerate lies near the top of a stratigraphic sequence which includes mafic and felsic volcanic rocks, iron formations, conglomerates, sandstones and argillites. The conglomerate unit itself consists of interbedded conglomerate and sandstone, and probably represents a channel-fill deposit of an ancient submarine fan.</p> <p> Modal percentages of clast types were obtained using a line-intercept method. They indicate that most of the debris in the conglomerate can be reasonably attributed to uplift and erosion of the lateral equivalents of the underlying stratigraphy, except for the granitoid clasts, which have no known origin within the area.</p> <p> Petrographic examinations of the clasts indicate that field identifications must be confirmed with thin
section investigations.</p> <p> The modal composition of granitoid clasts was determined utilizing both thin sections and stained slabs. Most of the granitoid clasts are granodiorite, or lie just within the granite field, adjacent to the granodiorite field. Textural studies of the granitoid clasts suggest that gneissic and allotriomorphic-granular textured rocks may have formed by deformation or partial recrystallization along grain boundaries of previously hypidiomorphic-granular rocks. Textures generally indicate intrusive origin and slow cooling,
although two granophyric samples may have solidified at relatively shallower depths than the other granitoid rocks.</p> <p> The textures and compositions of most of the granitoid clasts suggest that they were derived from one intrusive body. Intrusion of such a body into the
volcanic-sedimentary belt, followed by uplift and erosion, would account for the presence in the "Loose Pebble Bay" conglomerate of granitic clasts and clasts similar to the underlying rocks. However, no evidence of such an intrusion has been found in the Manitou Lake area,
and two of the granitoid clasts are noticeably different in composition from the others. The possibility of a pre-existing sialic basement cannot be ruled out.</p> / Thesis / Bachelor of Science (BSc)
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Proposta metodológica sobre dados de geofísica aeroportada na prospecção de minério de Fe: indicação de ambientes geológicos propícios e geração de mapas de probabilidade na região de Curral Novo do Piauí (PI) / Methodological proposal on airborne geophysical data for iron ore exploration : favorable geological environments indication and probability maps making in Curral Novo do Piauí region (PI)Sato, Enos Nobuo 12 April 2011 (has links)
A dissertação tem por cerne dois textos complementares, ambos refletindo o histórico de um programa de exploração mineral no distrito ferrífero de Curral Novo do Piauí. Como trabalho executado por empresa, a discussão sobre os custos e a definição de prioridades foram aspectos continuamente considerados. Assim os textos referidos refletem essas preocupações e se referem à proposição de métodos voltados à definição dos ambientes geológicos propícios à ocorrência de formações ferríferas à magnetita e à definição de probabilidade de ocorrências destes ambientes na fase de reconaissance da pesquisa. Na contextualização geológica do tema apresenta-se aspectos da geologia e uma discussão dos tipos e origens das formações ferríferas bandadas. Nos trabalhos foram aplicadas diversas técnicas, incluindo estatística multivariada, processamento digital de imagens, mapeamento geológico sistemático de superfície e subsuperfície em testemunhos de sondagens, caracterização petrográfica de rochas, geofísica de exploração a partir da utilização de métodos potenciais (magnetometria e radiometria). / This dissertation presents two complementary manuscripts, both reflecting the history of an exploration program in the Ferriferous Mineral District of Curral Novo do Piauí. As a research performed by a company, the discussion about the costs and prioritization aspects were continuously considered. The manuscripts reflects these concerns, referring to the proposition of methods aimed at defining the geological environments conducive to the occurrence of magnetite iron formations and the definition of probability of occurrence of these environments during the research reconnaissance phase. In the introductory chapter are presented the geological context and also a discussion of types and genesis of banded iron formations. In these studies were applied several techniques, including multivariate statistics, digital image processing, systematic geological surface mapping, diamond drill surveys, petrographic characterization of rocks and exploration geophysics methods (magnetometric and radiometric).
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Proposta metodológica sobre dados de geofísica aeroportada na prospecção de minério de Fe: indicação de ambientes geológicos propícios e geração de mapas de probabilidade na região de Curral Novo do Piauí (PI) / Methodological proposal on airborne geophysical data for iron ore exploration : favorable geological environments indication and probability maps making in Curral Novo do Piauí region (PI)Enos Nobuo Sato 12 April 2011 (has links)
A dissertação tem por cerne dois textos complementares, ambos refletindo o histórico de um programa de exploração mineral no distrito ferrífero de Curral Novo do Piauí. Como trabalho executado por empresa, a discussão sobre os custos e a definição de prioridades foram aspectos continuamente considerados. Assim os textos referidos refletem essas preocupações e se referem à proposição de métodos voltados à definição dos ambientes geológicos propícios à ocorrência de formações ferríferas à magnetita e à definição de probabilidade de ocorrências destes ambientes na fase de reconaissance da pesquisa. Na contextualização geológica do tema apresenta-se aspectos da geologia e uma discussão dos tipos e origens das formações ferríferas bandadas. Nos trabalhos foram aplicadas diversas técnicas, incluindo estatística multivariada, processamento digital de imagens, mapeamento geológico sistemático de superfície e subsuperfície em testemunhos de sondagens, caracterização petrográfica de rochas, geofísica de exploração a partir da utilização de métodos potenciais (magnetometria e radiometria). / This dissertation presents two complementary manuscripts, both reflecting the history of an exploration program in the Ferriferous Mineral District of Curral Novo do Piauí. As a research performed by a company, the discussion about the costs and prioritization aspects were continuously considered. The manuscripts reflects these concerns, referring to the proposition of methods aimed at defining the geological environments conducive to the occurrence of magnetite iron formations and the definition of probability of occurrence of these environments during the research reconnaissance phase. In the introductory chapter are presented the geological context and also a discussion of types and genesis of banded iron formations. In these studies were applied several techniques, including multivariate statistics, digital image processing, systematic geological surface mapping, diamond drill surveys, petrographic characterization of rocks and exploration geophysics methods (magnetometric and radiometric).
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Tectônica e sedimentação do Grupo Jacadigo (Neoproterozóico, MS) / Tectonics and sedimentation of Jacadigo Group (Neoproterozoic, MS)Freitas, Bernardo Tavares 26 April 2010 (has links)
Ao sul da cidade de Corumbá, MS, ocorrem imponentes elevações topográficas constituídas por depósitos sedimentares neoproterozóicos do Grupo Jacadigo. Nessas montanhas, cujo conjunto é referido como Maciço do Urucum, assentam-se discordantemente sobre o embasamento rochas siliciclásticas da Formação Urucum com espessuras máximas da ordem de 200 a 300m. A seção continua com depósitos mistos de componentes siliciclásticos e GIFs (granular iron formations), por aproximadamente 100m, e com mais 300m de predomínio de BIFs (banded iron formations). Na periferia do Maciço do Urucum ocorrem rochas carbonáticas do Grupo Corumbá, principalmente das formações Bocaina e Tamengo. Foi esse o conjunto de rochas abordado no presente trabalho por estudos sedimentológicos e estratigráficos em escala de detalhe. A análise integrada de fácies e paleocorrentes permitiu interpretar os mecanismos tectônicos geradores de espaço de acomodação, a orientação da bacia sedimentar, a estruturação de seu preenchimento, implicações geotectônicas regionais e para modelos de deposição de formações ferríferas. Para o preenchimento da bacia, definida na presente dissertação como Bacia Jacadigo, foram interpretados 6 sistemas deposicionais: (I) sistemas de leques aluviais; (II) sistema lacustre; (III) sistema fluvial entrelaçado; (IV) sistema de corpo dágua principal; (V) sistema de fluxos gravitacionais subaquáticos; e (VI) sistema de plataforma carbonática. Esses sistemas foram classificados em 3 tratos tectônicos, sendo os 3 primeiros sistemas deposicionais, essencialmente siliciclásticos e continentais, referentes ao trato de iniciação do rift; os sistemas de corpo dágua principal e de fluxos gravitacionais associados correspondentes ao clímax do rift; e a plataforma carbonática referente ao pós-rift. Esse último caracterizado pela transição entre as formações Urucum e Bocaina, de modo que a classificação em tratos tectônicos reflete os significados geodinâmicos dos grupos Jacadigo e Corumbá. A distribuição espacial dos sistemas deposicionais e dos padrões de paleocorrentes levou à interpretação de uma orientação WNW-ESE para a zona de falhas mestras da Bacia Jacadigo. Essa interpretação implica na correlação do Grupo Jacadigo com a Faixa Chiquitos-Tucavaca e não com a Faixa Paraguai como proposto anteriormente. A distribuição das unidades neoproterozóicas no contexto geotectônico das faixas Chiquitos-Tucavaca e Paraguai levou a corroboração de um posicionamento adjacente da Bacia Jacadigo a uma junção tríplice supostamente soerguida por plumas mantélicas. Toda a sucessão do Grupo Jacadigo mais a sucessão do Morro do Puga, usualmente interpretadas como produtos de processos sedimentares sob influência glacial, foram interpretadas como resposta da sedimentação à tectônica na Bacia Jacadigo, sem necessariamente associação com processos glaciais. Foram distinguidos elementos estruturais da tectônica deformadora daqueles relativos à tectônica formadora do Grupo Jacadigo e sugerida uma conformação braquianticlinal das rochas aflorantes na área urbana de Corumbá, no Maciço do Urucum e nas áreas adjacentes. / At the south of Corumbá, Mato Grosso do Sul state, there are huge topographic elevations made of Jacadigo Groups neoproterozoic sedimentary deposits. Those mountains are known as Maciço do Urucum. The basal unit named Urucum Formation is composed by siliciclastic rocks with maximum thickness of 200 to 300m. The sucession continues with mixed GIF (granular iron formation) and siliciclastic deposits for approximately 100m, and more 300m of almost only BIFs (banded iron formations). In the surroundings of Maciço do Urucum there are carbonatic rocks from the Corumbá Group, mainly from Bocaina and Tamengo formations. This research presents detailed information about sedimentology and stratigraphy of the Maciço do Urucum area and surrounding rocks. The integrated facies and paleocurrents analysis produced the following interpretations: tectonic mechanisms responsible for accommodation spaces, sedimentary basin orientation, filling styles, regional geotectonic implication and iron formation depositional models. About the filling style, six depositional systems of the here named Jacadigo Basin were interpreted: (I) alluvial fan system; (II) lacustrine system; (III) fluvial braided system; (IV) main water body system; (V) subaquatic gravitational flow system; and (VI) carbonate platform system. Those systems were classified in three tectonic system tracts. The first three depositional systems are made of continental siliciclastics and refer to the rift initiation; the main water body and associated gravitational flow systems corresponds to the rift climax; and the carbonate platform to the post rift. The post rift is characterized by the transition between Urucum and Bocaina formations. This transition reflects the geodynamic significance of Jacadigo and Corumbá groups. The spatial distribution of the depositional systems and associated paleocurrent patterns indicated a WNW-ESE orientation to the master fault zone of Jacadigo Basin. This interpretation implies the correlation of Jacadigo Group and Chiquitos-Tucavaca Belt instead of Paraguai Belt, as proposed before. The neoproterozoic units distribution at the geotectonic context of Chiquitos-Tucavaca and Paraguai belts corroborated the adjacent position of Jacadigo Basin to a triple junction supposedly a plume generated uplift. Rocks of Jacadigo Group and Morro do Puga, usually interpreted as glacial deposits, are interpreted here as sedimentation response to tectonics with no necessary relation to glacial processes. Deformation and formation tectonic structural elements were distinguished and a braquianticlinal structure is suggested for the units in the Corumbá and Maciço do Urucum area.
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Caracterização geoquímica e geocronológica do Complexo Granjeiro, Província Borborema, NE Brasil: implicações para a evolução crustal paleoarqueana do distrito ferrífero de Curral Novo / Lithochemistry and LA-ICP-MS U-Pb geochronology of the Southern Granjeiro Complex, Borborema Province: Implications for the Paleoarchean crustal evolution of the Curral Novo do Piauí iron mineral districtDo Vale, José Alberto Rodrigues 23 November 2018 (has links)
O distrito ferrífero de Curral Novo é hospedado pelo Complexo Granjeiro Sul, situado na Zona Transversal, na porção sudoeste da Província Borborema, no estado do Piauí. Nesse distrito, formações ferríferas bandadas apresentam teor médio de 27,5% de Fe em recursos de mais de um bilhão de toneladas. Dados de campo, petrográficos, isotópicos, geoquímicos e geocronológicos possibilitaram a caracterização de uma associação de gnaisses e migmatitos com afinidade TTG e uma sequência metavulcanossedimentar com evidências de atividade exalativa de fundo oceânico com idade paleoarqueana. A suíte TTG do Complexo Granjeiro Sul apresenta grande variação química. Inclui tipicamente rochas magnesianas de composição cálcica a álcali-cálcica com baixo conteúdo de minerais máficos. Essas rochas possuem baixa concentração em elementos LILE e HFSE, significativo fracionamento de ETRL (La/YbN = 9,78-139,12) e anomalias levemente negativas de Eu (Eu/Eu* = 0,62-0,97), características de magmas gerados a partir de uma fonte de baixa pressão. Idades U-Pb em zircão obtidas em gnaisses TTG indicam cristalização do magma em 3349 ±15 Ma (MSWD = 0,62). A sequência metavulcanossedimentar do Complexo Granjeiro Sul é constituída por rochas metamáficas, metaultramáficas e formações ferríferas bandadas e interpretada como de idade próxima à da geração das rochas TTG do complexo. As rochas derivadas de protólitos ultramáficos e máficos apresentam composição komatiítica a basáltica e possuem gênese associada à fase de subducção entre duas placas oceânicas, apresentando afinidade química análoga a de rochas de arcos de ilhas modernos. As formações ferríferas bandadas apresentam fácies sedimentares óxido e silicato, com forte empobrecimento em HFSE e ETR e anomalias negativas de Ce (Ce/CeN = 0,04-0,37). Todo este conjunto de rochas arqueanas foi intrudido por corpos sienograníticos de idade de 2,651.8 ±8.9 Ma (MSWD = 1,5), pós- colisionais do tipo A2. Os sienitos são quimicamente classificadas como rochas metaluminosas a peraluminosas, cálcio-alcalinas de alto-K e ferrosas. Possuem leve enriquecimento de ETRL em relação aos ETRP e apresentam altos conteúdos de LILE e HFSE. Processos de alteração hidrotermal presentes nas encaixantes do minério de ferro e nas próprias formações ferríferas bandadas incluem silicificação, albitização, potassificação, carbonatização, sulfetação e reconcentração do ferro. Assinaturas de isótopos de enxofre (\'delta\'\'POT 34\'S = -3,11 a 2,03) em sulfetos hidrotermais sugerem fontes magmáticas para o enxofre associado ao sistema hidrotermal. As rochas do Complexo Granjeiro registraram ainda forte retrabalhamento crustal no Paleoproterozoico a partir do Riaciano (ca. 2,2 Ga), que resultou em metamorfismo das rochas metavulcanossedimentares, com picos que perduram até o Estateriano (ca. 1,7 Ga). / The Southern Granjeiro Complex hosts the Curral Novo do Piauí iron district, located in the Transversal Zone of the Borborema Province. In this district, banded iron formations have an average grade of 27.5% of Fe in resources of more than one billion tons. Field, petrographic, isotopic, geochemical, and geochronological data allowed the characterization of an association of gneisses and migmatites with TTG affinity and a Paleoarchean greenstone belt sequence with evidence of ocean floor exhalative activity. The TTG suite of the Southern Granjeiro Complex includes magnesian rocks of calcic to alkali-calcic affinity and low content of mafic minerals. These rocks have a low concentration of LILE and HFSE elements, significant fractionation of ETRL (La/YbN = 9.78-139.12) and slightly negative Eu anomaly (Eu/Eu* = 0.62-0.97). These characteristics are similar to that of TTG magmas generated from low-pressure sources. LA-ICP-MS U-Pb zircon ages obtained in TTG gneisses indicate magma crystallization at 3.349 ±15 Ma (MSWD = 0.62). The Southern Granjeiro metavolcanosedimentary sequence comprises metamafic and metaultramafic volcanic rocks and banded iron formation. These rocks derived from basaltic and komatiitic protoliths with chemical affinity to those formed in modern island arcs. The banded iron formation has oxide (magnetite-quartz) and silicate (grunerite-quartz) facies, with strong impoverishment in HFSE and ETR and negative Ce anomaly (Ce/CeN = 0.04-0.37). Post-collisional A2-type syenogranites (2.651.8 ±8.9 Ma; MSWD = 1.5) crosscut the Southern Granjeiro Complex. The syenogranites are ferroan, metaluminous to peraluminous and have a high-K calc-alkaline affinity. They have a slight enrichment of ETRL concerning ETRP and high contents of LILE and HFSE. Hydrothermal alteration processes in the banded iron formations and associated volcanic rocks include silicification, albitization, potassic alteration, carbonation, sulfide formation and iron reconcentration. Sulfur isotopes signatures (\'delta\'\'POT.34\'S = -3.11 to 2.03) of hydrothermal sulfides suggest magmatic sulfur sources associated with the hydrothermal system. The rocks of the Southern Granjeiro Complex still recorded strong crustal reworking and metamorphism in the Riacian (ca. 2.2 Ga) until the Staterian (ca. 1.7 Ga).
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THE STRATIGRAPHY AND GEOCHEMISTRY OF THE RAPITAN IRON FORMATION, NORTHWEST TERRITORIES AND YUKON, CANADABaldwin, Geoffrey James 16 May 2014 (has links)
The Neoproterozoic was a time of major change in Earth’s surficial history, including a major rise in atmospheric oxygen, the first appearance of complex metazoan life, and a series of worldwide glaciations. A particular interesting element of these so called “snowball Earth” glacial deposits is the presence of iron formation, a distinctive Precambrian rock type that is largely absent from the post-Paleoproterozoic record. Despite being relatively poorly studied with respect to their geochemistry and sedimentology, Neoproterozoic iron formations are used to support many models for the record of oxygen concentrations of the Earth. The classical example of Neoproterozoic iron formation is the Rapitan iron formation of northwestern Canada. This hematite-jasper iron formation is associated with glaciogenic turbidites and diamictites. Despite being the archetype, the Rapitan iron formation has not been studied in the context of recent ideas about the Neoproterozoic. In this thesis, the stratigraphy, geochemistry, and basin architecture of the Rapitan iron formation are reassessed. Using the REE+Y and the redox-sensitive elements Mo and U, it is shown that the Rapitan iron formation was deposited in a partially restricted basin from biogenically reduced iron under variable redox conditions. Elemental Re and Mo isotopes further show that although oxic and ferruginous conditions predominated during deposition of the iron formation, a transition towards a sulfidic water column locally terminated deposition. Finally, regional stratigraphy and geochemistry show that the iron formation was preferentially deposited in deep, newly formed basins that were protected from significant siliciclastic sedimentation. These basins were delimited by inferred crustal-scale faults trending roughly perpendicular to the axis of the rift basin, and allowed significant changes in thickness and sedimentological character over short distances along strike. These factors help build an overall geotectonic regime under which Neoproterozoic iron formations were deposited: young, deep rift basins that had undergone marine incursion, and were intermittently sealed by an ice shelf, allowing for the generation of an anoxic, iron-rich water column. The absence of the Eu anomaly and the heavy Mo isotopic signature indicate that the open ocean was fully oxygenated at the time of Rapitan iron formation deposition, as opposed to ferruginous as previously suggested.
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Tectônica e sedimentação do Grupo Jacadigo (Neoproterozóico, MS) / Tectonics and sedimentation of Jacadigo Group (Neoproterozoic, MS)Bernardo Tavares Freitas 26 April 2010 (has links)
Ao sul da cidade de Corumbá, MS, ocorrem imponentes elevações topográficas constituídas por depósitos sedimentares neoproterozóicos do Grupo Jacadigo. Nessas montanhas, cujo conjunto é referido como Maciço do Urucum, assentam-se discordantemente sobre o embasamento rochas siliciclásticas da Formação Urucum com espessuras máximas da ordem de 200 a 300m. A seção continua com depósitos mistos de componentes siliciclásticos e GIFs (granular iron formations), por aproximadamente 100m, e com mais 300m de predomínio de BIFs (banded iron formations). Na periferia do Maciço do Urucum ocorrem rochas carbonáticas do Grupo Corumbá, principalmente das formações Bocaina e Tamengo. Foi esse o conjunto de rochas abordado no presente trabalho por estudos sedimentológicos e estratigráficos em escala de detalhe. A análise integrada de fácies e paleocorrentes permitiu interpretar os mecanismos tectônicos geradores de espaço de acomodação, a orientação da bacia sedimentar, a estruturação de seu preenchimento, implicações geotectônicas regionais e para modelos de deposição de formações ferríferas. Para o preenchimento da bacia, definida na presente dissertação como Bacia Jacadigo, foram interpretados 6 sistemas deposicionais: (I) sistemas de leques aluviais; (II) sistema lacustre; (III) sistema fluvial entrelaçado; (IV) sistema de corpo dágua principal; (V) sistema de fluxos gravitacionais subaquáticos; e (VI) sistema de plataforma carbonática. Esses sistemas foram classificados em 3 tratos tectônicos, sendo os 3 primeiros sistemas deposicionais, essencialmente siliciclásticos e continentais, referentes ao trato de iniciação do rift; os sistemas de corpo dágua principal e de fluxos gravitacionais associados correspondentes ao clímax do rift; e a plataforma carbonática referente ao pós-rift. Esse último caracterizado pela transição entre as formações Urucum e Bocaina, de modo que a classificação em tratos tectônicos reflete os significados geodinâmicos dos grupos Jacadigo e Corumbá. A distribuição espacial dos sistemas deposicionais e dos padrões de paleocorrentes levou à interpretação de uma orientação WNW-ESE para a zona de falhas mestras da Bacia Jacadigo. Essa interpretação implica na correlação do Grupo Jacadigo com a Faixa Chiquitos-Tucavaca e não com a Faixa Paraguai como proposto anteriormente. A distribuição das unidades neoproterozóicas no contexto geotectônico das faixas Chiquitos-Tucavaca e Paraguai levou a corroboração de um posicionamento adjacente da Bacia Jacadigo a uma junção tríplice supostamente soerguida por plumas mantélicas. Toda a sucessão do Grupo Jacadigo mais a sucessão do Morro do Puga, usualmente interpretadas como produtos de processos sedimentares sob influência glacial, foram interpretadas como resposta da sedimentação à tectônica na Bacia Jacadigo, sem necessariamente associação com processos glaciais. Foram distinguidos elementos estruturais da tectônica deformadora daqueles relativos à tectônica formadora do Grupo Jacadigo e sugerida uma conformação braquianticlinal das rochas aflorantes na área urbana de Corumbá, no Maciço do Urucum e nas áreas adjacentes. / At the south of Corumbá, Mato Grosso do Sul state, there are huge topographic elevations made of Jacadigo Groups neoproterozoic sedimentary deposits. Those mountains are known as Maciço do Urucum. The basal unit named Urucum Formation is composed by siliciclastic rocks with maximum thickness of 200 to 300m. The sucession continues with mixed GIF (granular iron formation) and siliciclastic deposits for approximately 100m, and more 300m of almost only BIFs (banded iron formations). In the surroundings of Maciço do Urucum there are carbonatic rocks from the Corumbá Group, mainly from Bocaina and Tamengo formations. This research presents detailed information about sedimentology and stratigraphy of the Maciço do Urucum area and surrounding rocks. The integrated facies and paleocurrents analysis produced the following interpretations: tectonic mechanisms responsible for accommodation spaces, sedimentary basin orientation, filling styles, regional geotectonic implication and iron formation depositional models. About the filling style, six depositional systems of the here named Jacadigo Basin were interpreted: (I) alluvial fan system; (II) lacustrine system; (III) fluvial braided system; (IV) main water body system; (V) subaquatic gravitational flow system; and (VI) carbonate platform system. Those systems were classified in three tectonic system tracts. The first three depositional systems are made of continental siliciclastics and refer to the rift initiation; the main water body and associated gravitational flow systems corresponds to the rift climax; and the carbonate platform to the post rift. The post rift is characterized by the transition between Urucum and Bocaina formations. This transition reflects the geodynamic significance of Jacadigo and Corumbá groups. The spatial distribution of the depositional systems and associated paleocurrent patterns indicated a WNW-ESE orientation to the master fault zone of Jacadigo Basin. This interpretation implies the correlation of Jacadigo Group and Chiquitos-Tucavaca Belt instead of Paraguai Belt, as proposed before. The neoproterozoic units distribution at the geotectonic context of Chiquitos-Tucavaca and Paraguai belts corroborated the adjacent position of Jacadigo Basin to a triple junction supposedly a plume generated uplift. Rocks of Jacadigo Group and Morro do Puga, usually interpreted as glacial deposits, are interpreted here as sedimentation response to tectonics with no necessary relation to glacial processes. Deformation and formation tectonic structural elements were distinguished and a braquianticlinal structure is suggested for the units in the Corumbá and Maciço do Urucum area.
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