The primary objective of this work is to determine the Kalina cycle's suitability for thermal power conversion from a pressurized water reactor. Several previous papers have examined this application, but these either lack proof of concept or make unfeasible assumptions. This work expands current knowledge by simulating the Kalina cycle and comparing it to current pressurized water reactor Rankine cycles in order to identify which is more efficient. Prerequisite to the modeling is a simulation tool capable of modeling the thermodynamics of ammonia/water mixtures. Instead of using an existing program, a new one called Clearwater is used. This tool is based on a preexisting Gibbs free energy "super" equation of state. Algorithms for vapor-liquid equilibrium calculations and phase identification are presented. Clearwater will be distributed online as open-source code to aid future developers of ammonia/water power and refrigeration cycles. A comparison of single-stage Kalina and Rankine cycles driven by heat from PWR core coolant suggests that the Kalina cycle is not well suited to the application. Any benefit from the Kalina cycle's ability to match temperature profiles in the boiling region of the steam generator is outweighed by other drawbacks. These include the cycle's 1) increased turbine exhaust pressure and 2) lower average heat absorption temperature caused by its working fluid's relatively high liquid heat capacity, both of which lower efficiency. Having concluded this, an attempt is made to quantify the conditions under which the Kalina cycle produces more power than the Rankine cycle. Both cycles are optimized for a range of heat source inlet and outlet temperatures between 350 ℃ and 525 ℃. When both cycles absorb the same amount of heat from the source"”i.e., when source outlet temperature is constrained"” the Kalina cycle is less effective for small source temperature drops. When outlet temperature is unconstrained, the Kalina cycle outperforms the Rankine cycle for all but the lowest inlet temperature. This is due to the Kalina cycle's non-isothermal boiling profile, which allows it to absorb low temperature heat at relatively high pressure. Because of its isothermal boiling profile, the Rankine cycle cannot capture low temperature heat as effectively, so it performs worse over large, unconstrained source temperature drops.

Zugl.: Berlin, Techn. Univ., Diss, 2005

Ingeniero Civil Mecánico / Chile tiene uno de los recursos solares de mayor calidad en el mundo, el cual no está siendo aprovechado mayormente. Una forma en que se puede utilizar este recurso es captándolo como energía solar térmica. El ciclo Kalina, inventado a principios de la década de 1980, es un ciclo de potencia cuya principal característica es el fluido de trabajo que utiliza, que es una mezcla binaria, típicamente amoníaco agua. En este trabajo se encuentran rangos favorables de condiciones de operación del ciclo Kalina, para generación eléctrica de 0,5 a 4 [MW], a partir de energía solar térmica de baja temperatura (80 200 [°C]). Se desarrollan y validan modelos termodinámicos por la primera y segunda leyes de la termodinámica de los ciclos Kalina y Rankine Orgánico, este último con los fluidos de trabajo R123, R134a y R152a. Los modelos son validados reproduciendo resultados de la literatura encontrándose una buena concordancia. Se realiza un análisis paramétrico a los ciclos Kalina y Rankine Orgánico, investigando la sensibilidad de los rendimientos térmico y exergético al variar la presión en el evaporador solar, la concentración de amoníaco, la temperatura de la fuente de calor, el pinchpoint y la potencia neta. Se encuentra en el ciclo Kalina que se debe evitar un título de vapor excesivamente bajo a la salida del evaporador solar, porque esto tiene un efecto negativo sobre los rendimientos térmico y exergético. Los componentes con la mayor destrucción de exergía son el condensador, la turbina, el evaporador solar y el regenerador. Al variar la potencia neta las variables extensivas crecen linealmente con ésta. Por último, se encuentran las condiciones de operación más favorables del ciclo Kalina en función de la temperatura de la fuente de calor, para alcanzar el máximo rendimiento exergético. En el ciclo Rankine Orgánico se encuentra que el máximo rendimiento exergético se alcanza a la máxima presión admisible en el evaporador solar, y con R152a como fluido de trabajo. Al comparar los ciclos Kalina y Rankine Orgánico se encuentra que el primero alcanza un mayor rendimiento térmico y exergético que el segundo, sin embargo, requiere de una presión en el evaporador solar de un 40% mayor. A bajas presiones en el evaporador solar la diferencia entre ambos ciclos, a favor del ciclo Kalina, es significativamente mayor que a altas presiones. El mayor rendimiento del ciclo Kalina significa que requiere de una menor área de colectores solares, lo cual generalmente resulta crítico en aplicaciones de energía solar.

Thermodynamic and thermoeconomic aspects of 12.5 kW residential solar-thermal power generating systems suitable for distributed, decentralized power generation paradigm are presented in this thesis. The design of a meso-scale power system greatly differs from centralized power generation. As a result, this thesis provides guidance in the selection of the power cycle and operating parameters suitable for meso-scale power generation. Development of standard thermodynamic power cycle computer simulations provides means for evaluation of the feasibility of meso-scale solar-thermal power generation. The thermodynamic power cycles considered in this study are the Rankine cycle, the organic Rankine cycle with toluene, R123, and ethylbenzene as working fluids, the Kalina cycle, and the Maloney-Robertson cycle. From a strictly thermodynamic perspective, the cycles are evaluated based on first- and second-law efficiencies. Additionally, the study includes economic feasibility through thermoeconomic characterization that encompasses a meso-scale cost model for solar-thermal power generation systems. Key results from this study indicate that a R123 organic Rankine cycle is the most cost-effective cycle implementation for operating conditions in which the maximum temperature is limited below 240C. For temperatures greater than 240C and less than 375C, the toluene and ethylbenzne organic Rankine cycles outperform the other cycles. The highest first law efficiency of 28% of the Kalina cycle exceeds all other cycles at temperatures between 375C and 500C. However, when considering cycle cost and overall feasibility, including thermodynamic and thermoeconomic performance, the Maloney-Robertson and Kalina cycles have poor performance on a cost-to-efficiency basis.

This master’s thesis analyses Kalina cycle, a power cycle where ammonia – water solution is used as a working fluid. The first part of this study introduces us to the Kalina cycle, presents its advantages and disadvantages, characteristics of the working fluid and its applications. Second section concerns with the method of cycle design and describes the calculation model made in this thesis. The calculation model is attached in a separate .XLSM file. The third part shows calculation of the cycle for given parameters, determination of cycle efficiency and main proportions of the thermal turbine. In the conclusion are the interpretations of the calculations results.

The world demand for electrical power increasescontinuously, requiring efficient and low-cost methods forpower generation. This thesis investigates two advanced powercycles with mixtures as the working fluid: the Kalina cycle,alternatively called the ammonia-water cycle, and theevaporative gas turbine cycle. These cycles have the potentialof improved performance regarding electrical efficiency,specific power output, specific investment cost and cost ofelectricity compared with the conventional technology, sincethe mixture working fluids enable efficient energyrecovery. This thesis shows that the ammonia-water cycle has a betterthermodynamic performance than the steam Rankine cycle as abottoming process for natural gas-fired gas and gas-dieselengines, since the majority of the ammonia-water cycleconfigurations investigated generated more power than steamcycles. The best ammonia-water cycle produced approximately40-50 % more power than a single-pressure steam cycle and 20-24% more power than a dual-pressure steam cycle. The investmentcost for an ammonia-water bottoming cycle is probably higherthan for a steam cycle; however, the specific investment costmay be lower due to the higher power output. A comparison between combined cycles with ammonia-waterbottoming processes and evaporative gas turbine cycles showedthat the ammonia-water cycle could recover the exhaust gasenergy of a high pressure ratio gas turbine more efficientlythan a part-flow evaporative gas turbine cycle. For a mediumpressure ratio gas turbine, the situation was the opposite,except when a complex ammonia-water cycle configuration withreheat was used. An exergy analysis showed that evaporativecycles with part-flow humidification could recover energy asefficiently as, or more efficiently than, full-flow cycles. Aneconomic analysis confirmed that the specific investment costfor part-flow cycles was lower than for full-flow cycles, sincepart-flow humidification reduces the heat exchanger area andhumidification tower volume. In addition, the part-flow cycleshad lower or similar costs of electricity compared with thefull-flow cycles. Compared with combined cycles, the part-flowevaporative cycles had significantly lower total and specificinvestment costs and lower or almost equal costs ofelectricity; thus, part-flow evaporative cycles could competewith the combined cycle for mid-size power generation. <b>Keywords:</b>power cycle, mixture working fluid, Kalinacycle, ammonia-water mixture, reciprocating internal combustionengine, bottoming cycle, gas turbine, evaporative gas turbine,air-water mixture, exergy

<p>The world demand for electrical power increasescontinuously, requiring efficient and low-cost methods forpower generation. This thesis investigates two advanced powercycles with mixtures as the working fluid: the Kalina cycle,alternatively called the ammonia-water cycle, and theevaporative gas turbine cycle. These cycles have the potentialof improved performance regarding electrical efficiency,specific power output, specific investment cost and cost ofelectricity compared with the conventional technology, sincethe mixture working fluids enable efficient energyrecovery.</p><p>This thesis shows that the ammonia-water cycle has a betterthermodynamic performance than the steam Rankine cycle as abottoming process for natural gas-fired gas and gas-dieselengines, since the majority of the ammonia-water cycleconfigurations investigated generated more power than steamcycles. The best ammonia-water cycle produced approximately40-50 % more power than a single-pressure steam cycle and 20-24% more power than a dual-pressure steam cycle. The investmentcost for an ammonia-water bottoming cycle is probably higherthan for a steam cycle; however, the specific investment costmay be lower due to the higher power output.</p><p>A comparison between combined cycles with ammonia-waterbottoming processes and evaporative gas turbine cycles showedthat the ammonia-water cycle could recover the exhaust gasenergy of a high pressure ratio gas turbine more efficientlythan a part-flow evaporative gas turbine cycle. For a mediumpressure ratio gas turbine, the situation was the opposite,except when a complex ammonia-water cycle configuration withreheat was used. An exergy analysis showed that evaporativecycles with part-flow humidification could recover energy asefficiently as, or more efficiently than, full-flow cycles. Aneconomic analysis confirmed that the specific investment costfor part-flow cycles was lower than for full-flow cycles, sincepart-flow humidification reduces the heat exchanger area andhumidification tower volume. In addition, the part-flow cycleshad lower or similar costs of electricity compared with thefull-flow cycles. Compared with combined cycles, the part-flowevaporative cycles had significantly lower total and specificinvestment costs and lower or almost equal costs ofelectricity; thus, part-flow evaporative cycles could competewith the combined cycle for mid-size power generation.</p><p><b>Keywords:</b>power cycle, mixture working fluid, Kalinacycle, ammonia-water mixture, reciprocating internal combustionengine, bottoming cycle, gas turbine, evaporative gas turbine,air-water mixture, exergy</p>

This Diploma thesis describes design of the computational model of Uehara power cycle, with ammonia-water mixture used as working fluid. First part is dedicated to issue of determination working mixture thermodynamic properties, which are essential for computational model design. The second part of this thesis describes the methodology of computing power cycle by system matrix solving method. For purposes of methodology testing, model of Kalina power cycle was also created. Computational models of Uehara and Kalina cycles are designed in Excel and are an integral part of this thesis. Text part also includes a description of their user interface, calculation algorithm and detailed description of the design methodology.

An investigation into the performance of several combined gas-steam power generating plants’ cycles was undertaken at the School of Engineering and Technology at the University of Hertfordshire and it is predominantly analytical in nature. The investigation covered in principle the aspect of the fundamentals and the performance parameters of the following cycles: gas turbine, steam turbine, ammonia-water, partial oxidation and the absorption chiller. Complete thermal analysis of the individual cycles was undertaken initially. Subsequently, these were linked to generate a comprehensive computer model which was employed to predict the performance and characteristics of the optimized combination. The developed model was run using various input parameters to test the performance of the cycle’s combination with respect to the combined cycle’s efficiency, power output, specific fuel consumption and the temperature of the stack gases. In addition, the impact of the optimized cycles on the generation of CO2 and NOX was also investigated. This research goes over the thermal power stations of which most of the world electrical energy is currently generated by. Through which, to meet the increase in the electricity consumption and the environmental pollution associated with its production as well as the limitation of the natural hydrocarbon resources necessitated. By making use of the progressive increase of high temperature gases in recent decades, the advent of high temperature material and the use of large compression ratios and generating electricity from high temperature of gas turbine discharge, which is otherwise lost to the environment, a better electrical power is generated by such plant, which depends on a variety of influencing factors. This thesis deals with an investigation undertaken to optimize the performance of the combined Brayton-Rankine power cycles' performance. This work includes a comprehensive review of the previous work reported in the literature on the combined cycles is presented. An evaluation of the performance of combined cycle power plant and its enhancements is detailed to provide: A full understanding of the operational behaviour of the combined power plants, and demonstration of the relevance between power generations and environmental impact. A basic analytical model was constructed for the combined gas (Brayton) and the steam (Rankine) and used in a parametric study to reveal the optimization parameters, and its results were discussed. The role of the parameters of each cycle on the overall performance of the combined power cycle is revealed by assessing the effect of the operating parameters in each individual cycle on the performance of the CCPP. P impacts on the environment were assessed through changes in the fuel consumption and the temperature of stack gases. A comprehensive and detailed analytical model was created for the operation of hypothetical combined cycle power and power plant. Details of the operation of each component in the cycle was modelled and integrated in the overall all combined cycle/plant operation. The cycle/plant simulation and matching as well as the modelling results and their analysis were presented. Two advanced configurations of gas turbine cycle for the combined cycle power plants are selected, investigated, modelled and optimized as a part of combined cycle power plant. Both configurations work on fuel rich combustion, therefore, the combustor model for rich fuel atmosphere was established. Additionally, models were created for the other components of the turbine which work on the same gases. Another model was created for the components of two configurations of ammonia water mixture (kalina) cycle. As integrated to the combined cycle power plant, the optimization strategy considered for these configurations is for them to be powered by the exhaust gases from either the gas turbine or the gases leaving the Rankine boiler (HRSG). This included ChGT regarding its performance and its environmental characteristics. The previously considered combined configuration is integrated by as single and double effect configurations of an ammonia water absorption cooling system (AWACS) for compressor inlet air cooling. Both were investigated and designed for optimizing the triple combination power cycle described above. During this research, tens of functions were constructed using VBA to look up tables linked to either estimating fluids' thermodynamic properties, or to determine a number of parameters regarding the performance of several components. New and very interesting results were obtained, which show the impact of the input parameters of the individual cycles on the performance parameters of a certain combined plant’s cycle. The optimized parameters are of a great practical influence on the application and running condition of the real combined plants. Such influence manifested itself in higher rate of heat recovery, higher combined plant thermal efficiency from those of the individual plants, less harmful emission, better fuel economy and higher power output. Lastly, it could be claimed that various concluding remarks drawn from the current study could help to improve the understanding of the behaviour of the combined cycle and help power plant designers to reduce the time, effort and cost of prototyping.