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Evaporation, wetting and multiphase flows of drops and bubbles are everyday life phenomena with potential impact in many industrial, biological, medical or engineering applications. The understanding and controlling of the physical and chemical mechanisms governing these phenomena have become of paramount importance. This thesis encompasses three topics: evaporation of sessile droplets of polymer solutions, the role of thermocapillarity on self-rewetting fluid dynamics and migration of bubbles in liquid flows. Firstly, the evaporative behaviour of sessile droplets of aqueous polymer solutions and the effect of different molecular weights on the drying process has been studied. Drop shape analysis allowed monitoring the evolution of all stages during drying and indicating the transitions between stages. The mechanisms taking place during the crucial stages of pinning and depinning were illustrated, revealing the effects of adhesion and contact line friction forces on the final morphology of the dried polymeric deposits. Additionally, the effect of varying substrates from hydrophilic to hydrophobic was examined demonstrating the importance of interfacial interaction phenomena. The initial spreading dynamics of binary alcohol mixtures (and pure liquids) deposited on different substrates in partially wetting situations, under non-isothermal conditions was systematically investigated. Moreover, the temporal and spatial thermal dynamics within pure droplets and alcohol mixtures using IR thermography revealed the existence of characteristic thermal patterns due to thermal and/or solutal instabilities. The contribution of the Marangoni effect as an important heat transport mechanism within the evaporating droplets was investigated. The motion of buoyancy-driven bubbles in a vertical microchannel and the significant role of thermocapillarity was reported in this series of experiments. The behaviour of the bubbles in self-rewetting fluid flows departed considerably from that of pure liquids flows. Furthermore, heat transfer coefficient calculations in the single and two phase flows demonstrated that the presence of Marangoni (surface tension) stresses resulted in the enhancement of the heat transfer distribution in the self-rewetting fluid flows compared with the pure ones.

This dissertation considers the genesis and dynamics of interfacial instability in vertical laminar gas-liquid flows, using as a model the two-dimensional channel flow of a thin falling film sheared by counter-current gas. The methodology is linear stability theory by means of Orr-Sommerfeld analysis together with direct numerical simulation of the two-phase flow in the case of nonlinear disturbances. The influence of two main flow parameters on the interfacial dynamics, namely the film thickness and pressure drop applied to drive the gas stream, is investigated. To make contact with existing studies in the literature, the effect of various density and viscosity contrasts as well as surface tension is also examined. Energy budget analyses based on the Orr-Sommerfeld theory reveal various coexisting unstable modes (interfacial, shear, internal) in the case of high density contrasts, which results in mode coalescence and mode competition, but only one dynamically relevant unstable interfacial mode for low and intermediate density contrast. Furthermore, high viscosity contrast and increases in surface tension lead to some amount of mode competition for thin film. A study of absolute and convective instability for low density contrast shows that the system is absolutely unstable for all but two narrow regions of the investigated parameter space. These regions are extended at intermediate density contrast and exhibit only small changes with increased viscosity contrast or surface tension. Direct numerical simulations of the system with low density contrast show that linear theory holds up remarkably well upon the onset of large-amplitude waves as well as the existence of weakly nonlinear waves. For high density contrasts corresponding more closely to an air-water-type system, linear stability theory is also successful at determining the most-dominant features in the interfacial wave dynamics at early-to-intermediate times. Nevertheless, the short waves selected by the linear theory undergo secondary instability and the wave train is no longer regular but rather exhibits chaotic motion. Furthermore, linear stability theory also predicts when the direction of travel of the waves changes - from downwards to upwards. The practical implications of this change in terms of loading and flooding is discussed. The change in direction of the wave propagation is represented graphically for each investigated system in terms of a flow map based on the liquid and gas flow rates and the prediction carries over to the nonlinear regime with only a small deviation. Besides the semi-analytical and numerical analyses, experiments with an practically relevant setup and flow system have been carried out to benchmark and validate the models developed in this work.

The dynamic response of turbine flowmeters in low pressure gas flows (i. e. where the rotational inertia of the fluid is negligible) is well understood and methods for correcting meter signals for a lack of response are available. For liquid flows there has been a limited amount of experimental work on the response of meters to step changes but no reports have been found of the response of meters to sinusoidally pulsating flows. "Small" turbine meters are expected to behave differently from "large" meters for a number of reasons: a smaller meter would generally have: (1) a larger percentage of tip clearance leakage flow; (2) less fluid momentum between the meter blading; and, (3) less fluid friction forces on the effective surface area. In this research, arbitrarily, meters up to size 25 mm were defined as small; and within this study, meters of size 6 mm to 25 mm were investigated. The aim of the research was to investigate and to understand the response of small turbine meters to pulsating liquid flows and to provide methods for correction. Three approaches were used: (1) application of an existing theoretical model of turbine meter behaviour; (2) an experimental investigation of meter performance in pulsating flows; and (3) simulation of flow behaviour through one selected meter using CFD and extending the simulation to predict the rotor dynamics and, hence, the response of this meter to specified cases of pulsating flow. A theoretical model developed by Dijstelbergen (1966) assumes frictionless behaviour and that flow is perfectly guided by meter blading through the rotor and that fluid within the rotor envelope rotates as a "solid body". Results from this theoretical model applied for pulsating flows showed that there was likely to be positive error in predicted mean flow rate (over-registration) and negative error for predicted values of the amplitude of the pulsations (amplitude attenuation). This behaviour is due to the fundamental asymmetry between flows with increasing and decreasing angle of attack relative to the meter blades, throughout a pulsation cycle. This qualitative behaviour was confirmed by experimental work with meters up to size 25mm working with pulsation frequencies up to 300 Hz. For low frequency pulsations (below 10 Hz), the over-registration errors were within the limits of specified meter accuracy. At higher frequencies and larger pulsation amplitudes, the largest over-registration observed was 5.5 % and amplitude attenuation could be as large as 90 %. The dependence of these errors on both the flow pulsation amplitude and frequency were investigated. The theoretical model was also used as a basis for generating correction procedures, to be applied to both the mean flow and the pulsation amplitude measurements. The results from the CFD simulation showed qualitative good agreement with the experimental data. The same kind of meter error trends were observed and it was shown to provide a better correlation with the experimental trends than the theoretical model derived from Dijstelbergen. From the CFD simulation, the causes of over-registration and amplitude attenuation in turbine flowmetering were understood through the investigation of rotor dynamics coupled with fluid behaviour around meter blading within the pulsation cycle. The CFD results were used to evaluate fluid angular momentum flux and to review the validity of the assumption that fluid within the rotor "envelope" rotated as a solid body. For the case investigated, whilst the assumption that flow is perfectly guided is not inappropriate, the volume of fluid assumed to rotate as a "solid body" was found to be significantly less than the rotor envelope volume.

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Les écoulements gaz-liquide constituent un axe de recherche très actif en microfluidique. Le rapport des débits entre les deux phases, la formation de bulles et les champs de vitesse des microcanaux ont été étudiés dans cette thèse, en utilisant une caméra numérique rapide et un microsystème de Particule Image Velocimetry (micro-PIV). En particulier, le diagramme des phases gaz-liquide ont été établi dans des microcanaux carrés ; la formation des bulles en fluides tant newtoniens que non newtoniens a été étudiée en détail dans plusieurs configurations géométriques telles que T-injonction et flow-focusing. Les mécanismes régissant la formation d'une bulle ont été modélisés pour chaque étape : expansion, amincissement et rupture. L'étape amincissement de la traînée d'une bulle est notamment contrôlée par une pression orthogonale qui dépend du débit du liquide. Dans le cadre de flow-focusing, le mécanisme de la rupture du film gazeux peut être décrit par une loi d'échelle reliant l'épaisseur minimale du film au temps restant juste avant la rupture avec un exposant 1/3. Le caractère non newtonien de fluides PAAm allonge la traînée d'une bulle par rapport aux fluides newtoniens. Enfin, l'étude de la coalescence entre bulles a été entreprise à l'échelle microscopique ainsi que le comportement complexe des trains de bulles dans des réseaux de microcannaux / Gas-liquid two-phase flow is an important research project in microfluidics. The gas-liquid two-phase flow, the bubble formation and moving behaviours in microchannels were investigated, by using a high speed digital camera and a micro Particle Image Velocimetry (micro-PIV). The gas-liquid two-phase flow in vertical rectangular microchannels was investigated and a flow pattern map was constructed; the bubble formation in both Newtonian and non-Newtonian fluids in cross-flowing microfluidic T-junctions and flow-focusing devices was investigated; the bubble formation process could be divided into expansion, collapse and pinch-off stages; the collapse speed of the gaseous thread in the second stage is controlled by the squeezing pressure, and is proportional to the liquid flow rates; while the minimum width of the neck of the gaseous thread in the third stage for bubble formation in flow-focusing devices could be scaled with the remaining time to the ultimate pinch-off as a power law relationship with an exponent of 1/3; the PAAm solutions prolong the gaseous thread in the tangential direction of the neck; bubble coalescence in a microchannel with an expansion section was studied; the bubble behavior in a microchannel with a loop was also investigated