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In this work, we sought to provide a deeper understanding of the energy-absorbing capabilities of cast lattice structures. These structures absorb large amounts of energy via plastic deformation, but their most attractive characteristic from a structural standpoint is the favorable energy absorption-to-weight ratio. Conventional machining techniques are not well suited for manufacturing such complex features; therefore, we combined additive manufacturing (AM) with a well-known understanding of the metalcasting process. We used AM to produce sand molds in different sizes and with additional features for various applications — these molds were then filled with molten metal. Current literature suggests that this when appropriately applied, this methodology results in complex geometries castings comparable properties to parts made with traditionally produced sand molds. We chose to study periodic lattice structures for their repeatability and subsequent ease of making predictions via computer simulations. We first produced lightweight cast metal-ceramic composite panels of 225 x 225 x 60 mm. Our AM molds included provisions to install ceramic or hard metal tiles before pouring the molten metal. The tiles were encapsulated in the final casting to yield a composite structure. The initial material selection consisted of an aluminum A356-T6 alloy matrix with silicon carbide tiles. The composite lattice structures were tested against high-velocity projectiles — 0.30 caliber armor-piercing (AP M2) and NATO 7.62 mm ball rounds. We anticipated that the metal matrix alone would not be able to defeat these threats. However, the panels did reduce the striking velocity by approximately 20%. The thickness of the ceramic tiles varied from 4 mm to 8 mm at 2 mm increments. As expected, the hard ceramic tiles proved effective at improving the penetration resistance of the composite lattice structures — the impacts on regions with 4 mm thick tiles resulted in the reduction of striking velocity up to 49%; moreover, as the thickness was increased to 8 mm, the panels defeated the projectiles. We used these results to produce and validate a finite element (FE) model capable of replicating the experimental data within 5%. This model was later used to study how the ceramic material interacts with the lattice to absorb large amounts of kinetic energy from incident projectiles. Following, we manufactured smaller versions of these panels—50 x 50 x 90 mm test specimens for uniaxial compression testing for this instance. Once again, we relied on the capabilities of the FE method to replicate the test results within 10% for peak load and maximum displacement. We utilized computer simulations to optimize the design of the lattice structure. Its energy-absorbing capabilities were improved significantly — in this case, a 30% increase in the specific internal energy (internal energy per unit mass) as the evaluating criteria. The FE model was also used to study the performance of several other truss topologies. Lastly, we used computer simulations to evaluate the feasibility of making these cast lattice structures with ferrous alloys. We chose to work with Fe30Mn4Al0.9C due to its lower density and higher toughness than other steel grades. The first challenge was the lack of thermophysical property data in the literature for this alloy system. Hence, we used the CALPHAD method to calculate all the datasets needed to perform the mold filling and solidification simulation. Several of these calculations were validated experimentally. The location and severity of porosity between the model and the casting were in good agreement. / Doctor of Philosophy / The advent of additive manufacturing (AM), commonly known as 3D printing is a group of different digital-era technologies that has facilitated the production of complex designs that are not feasible to manufacture using conventional techniques. In the realm of metallic components one such technique involves the use of a laser beam to consolidate metallic powders via a layer-by-layer deposition process. Despite its advantages, this process has unique challenges, such as limited material selection and relatively small part volume. In this work, we have employed a hybrid approach that combines the use of AM with expertise in metalcasting to produce lightweight components with complex geometries. We used 3D printed sand molds that are then filled with molten metal of different alloy systems such as aluminum and steel. At first, we incorporate hard ceramic materials to increase the performance of the final parts under ballistics testing. Our aim is to upscale the size of current designs such that these devices can be used in various applications that require high absorption of kinetic energy, and that are lightweight and easy to replace.

The purpose of this investigation is to determine through routine checks the number of organisms present in the various raw ingredients used for the preparation of foods. The problem has consisted of, first, a determination of the total bacterial population by numbers; second, a determination of the incidence of colon bacteria in the samples examined; third, a determination of the presence of yeasts and molds; and fourth, an attempt to utilize this information obtained in judging the methods of handling the raw ingredients before they are used in the processing of foods.

As estruturas de concreto são moldadas em formas tratadas com desmoldantes e sua presença dificulta a adesão da argamassa fresca, com posterior descolamento no estado endurecido. Este estudo tem por objetivo explorar o potencial de uso de agentes retardadores em substituição aos desmoldantes convencionais na moldagem de concreto para obtenção de superfícies com maior capacidade de ancoragem das argamassas. A viabilidade do uso de agentes retardadores foi verificada determinando-se de modo comparativo a resistência de aderência à tração da argamassa e do chapisco aplicados sobre corpos de prova de concreto moldados em formas de madeira plastificada tratadas com agente retardador e com desmoldante convencional. O ensaio de aderência mostrou que a utilização de agentes retardadores possibilita maior facilidade para a remoção da camada superficial do concreto, resultando em aumento de rugosidade e absorção superficial, permitindo maior resistência de aderência da argamassa e chapisco. Posteriormente, foram coletados agentes retardadores do mercado e avaliados: desempenho na aplicação sobre as formas, impacto dos produtos na saúde do trabalhador e no meio ambiente, e o efeito retardador na hidratação do cimento. Também foram avaliados quanto: a aplicabilidade dos produtos e sua influência no preparo da superfície para o recebimento da argamassa quando tratadas com produtos retardadores e convencionais em três tipos de formas. O estudo mostrou que o uso de agente retardador pode ser uma técnica viável para reduzir os problemas de descolamento do revestimento aplicado sobre superfícies de concreto. Através dos ensaios específicos desenvolvidos e adaptados para esta pesquisa, foi possível identificar que existem diferenças de comportamentos entre os produtos, sendo eles convencionais ou retardadores, e que os tipos de forma influenciam nestes comportamentos. Foi verificado também que as formas mais simples e com custos menores podem ser mais apropriadas para utilização destes produtos. / The concrete structures are cast in molds treated with a release agent (demolding product), and its presence hinders the mortars initial adhesion in the plastic state, as well as the bond strength after hardening. The study aims is to explore the potential use of retarding agents to replace conventional release agents in the concrete formwork. The technical viability of using a retarding agent was verified by comparing the tensile bond strength of rendering mortars applied on concrete surfaces cast with a conventional release agent and on concrete surfaces cast with a retarding release agent. The results showed that, through the use of retarding products, the removal of the concrete surface layer was possible by increasing the surface roughness, the surface water absorption and the tensile bond strength of the mortar to this concrete. Performance tests were also done with retarding products commercially available in the Brazilian market to verify the behavior of such products during application on molds, their impact on workers health and on the environment, and the retarding effect in cement hydration. It was also evaluated the applicability of these products and their influence on surface preparation to receive mortar when treated with retarding and conventional products, in three types of molds. Retarding products showed to be a viable technique for reducing the detachment problems of rendering mortars applied on concrete surfaces. Through the specific tests developed and adapted for this study, it was observed that there are differences in behavior between the conventional or retarding products, and also observed how these types of molds can influence the performance of the products. It was also observed that the simplest molds with lower cost can be more suitable in this application.

Modernas empresas buscam a melhoria dos seus sistemas de produção a fim de aumentar a produtividade e a qualidade de produtos. A tecnologia de usinagem com alta velocidade de corte (HSC – High Speed Cutting) permite aumentar as taxas de remoção de material, as tolerâncias dimensionais das partes, assim como a melhoria do acabamento superficial. Esta tecnologia tem sido muito utilizada na área de moldes e matrizes, pois minimiza o problema de tempos de usinagem longos na produção e facilita a obtenção de elevada qualidade, normalmente requerida em produtos injetados/estampados. Atualmente diversos estudos em HSC buscam a compreensão de todos os fatores envolvidos nesta nova tecnologia, a qual ainda apresenta diversas lacunas para o seu domínio completo. Este trabalho apresenta um estudo teórico-experimental da condução de calor nos materiais utilizados na fabricação de moldes e matrizes, submetidos à usinagem com altas velocidades de corte. Os materiais utilizados foram os aços AISI D2 e AISI H13, muito utilizados nas indústrias de moldes e matrizes. Os ensaios foram realizados com fresas de ponta esférica (Ball-Nose) com e sem angulação de hélice e com ângulo de saída neutro, com revestimento de ('TI'AL')N e com uma ferramenta com uma placa de PcBN soldada. A geometria dos corpos-de-prova foi projetada para aproximar-se dos casos reais encontrados na indústria, casos em que superfícies complexas e paredes finas são comumente usinadas em matrizes e moldes. Dois sistemas de resfriamento foram utilizados o ar comprimido e o ar gelado utilizando o princípio de vórtice. Os resultados demonstraram uma pequena variação da temperatura em função dos materiais empregados e das ferramentas utilizadas em todos os testes. Os dois sistemas de resfriamento alternativos à usinagem sem sistema de resfriamento, o ar comprimido e o ar frio, também se mostraram influentes na variação da temperatura, apresentando-se como sistemas capazes de remover o calor no processo durante a usinagem. Os desvios de forma encontrados nos corpos-de-prova devem ser considerados na usinagem de perfis muito precisos. Foram encontrados valores da ordem de 0,05 mm, oriundos da combinação de distorções térmicas e tensões residuais, os quais podem ser signifcativos, por exemplo, na área de matrizaria / Modern industries improve their production systems aiming at increasing productivity and product quality. The high speed cutting (HSC) technology allows increasing material removal rates, workpiece dimensional tolerance and surface finishing as well. Such technology has been extensively used in mold and dies areas, since it minimizes long lead time problems and facilitates high quality machining, normally required in injected/formed products. Nowadays, several studies in HSC search for understanding all aspects involved in that new technology, which still presents many blanks for its complete knowledge. The present work shows a theoretical and experimental study on heat conduction flux in materials applied to mold and die manufacturing, submitted to HSC. It was used AISI D2 and AISI H13, which are very common in mold and die industry. Two types of cylindrical ball nose end milling tool were used in the experiments: coated with ('TI'AL')N and tipped with PcBN. The workpiece geometry was conceived to simulate real cases found in industry, in which complex surfaces and slim walls are commonly machined in molds and dies. Two cooling systems were used in the tests, compressed air and frozen air using vortex principle. Results indicated a small temperature variation as a function of machined materials and tools throughout the tests. Both alternative cooling systems, besides dry machining, compressed air and cool air, also demonstrated to affect temperature variation. They presented themselves as capable of remove heat from the process during the cutting operation. The form deviation found in the workpiece after machining must be considered when machining very precise profiles. Variation values of around 0.05 mm were found, coming from a combination of thermal distortion and residual stress, which could be significant, for example, in die manufacturing area

A cadeia sucroenergética tem uma grande influência para economia nacional. Ao longo da safra 2013/2014, a cadeia movimentou cerca de US$ 100 bilhões, sendo que somente o açúcar gerou uma arrecadação de cerca de US$ 5.55 bilhões as usinas. O Produto Interno Bruto chegou a US$ 43 bilhões, representando assim aproximadamente 2,0% do PIB Nacional. Todavia, o setor está atravessando uma crise econômica que foi potencializada pela queda no valor da saca de açúcar e por uma severa seca que atingiu em especial o estado de São Paulo. A diminuição de perdas se torna essencial em momentos de dificuldades e uma maneira de atingir esse objetivo é melhorando o monitoramento do processo. Nesse cenário, o presente pesquisa monitorou a degradação de sacarose ao coletar amostras em uma usina da região de Piracicaba-SP, associando como causador não somente as elevadas temperaturas, como outros fatores e medidas utilizadas pela indústria. Conforme esperado aumentou a concentração de sacarose ao longo do processo, iniciando com média de 137,69 g/L na moenda e finalizando com 812,91 g/L no açúcar que saiu do secador. Todavia também apresentou um aumento de açúcares redutores (182,38 g/L no caldo da moenda para 245,81 g/L no xarope), indicando a degradação de sacarose. Inclusive, percebe-se uma razão de inversão maior durante da evaporação do que no tratamento (0,46 e 0,28, respectivamente). A justificativa pode estar associada a possível queda no pH, a evidente utilização de maior quantidade de calor em especial no primeiro efeito, a um tempo de residência maior do que o normal nos evaporadores ou mesmo através da entrada de vapor nos corpos, sendo o último mais raro. Os outros parâmetros levantados da degradação térmica de sacarose, 5-hidroximetilfurfural, furfural e as melanoidinas apresentaram uma alta correlação em função da concentração de açúcares redutores (0,99 para o HMF, 0,98 furfural e 0,96 melanoidinas), confirmando a tendência de perdas da molécula de interesse. Também foram levantadas as populações de bactérias mesófilas totais, cujas presenças estão associadas com as condições sanitárias em que o alimento foi processado e fungos (bolores e leveduras) que também diminuem o valor do produto. O tratamento de caldo mostrou-se eficiente na diminuição dos micro-organismos. Considerando a média dos dois meses, a queda foi de 4,10 x 106 UFC/mL para 6,62x102 UFC/mL para bactérias mesófilas, já para fungos a redução foi de 1,40 x 104 UFC/mL para 1,80 x 101 UFC/mL. Todavia, as altas concentrações encontradas no início e no final (bactérias apresentaram em média 3,00 x 103 UFC/g no xarope e 2,26 x 103 UFC/g no açúcar do secador, enquanto que para os fungos foram encontrados 3,50 x 101 UFC/g no xarope e 1,49 x 103 UFCmL no açúcar do secador) são indicativos de descuidos com a assepsia, aproveitando a falta de exigência de qualidade no açúcar VHP. A alta concentração do caldo da moenda apresentou potencial de estar relacionado com a perda de sacarose. Por fim, ao avaliar a situação e considerando que investimento em equipamentos novos é algo fora da realidade financeira da usina, sugere-se trabalhar em aprimorar as operações realizadas dentro e fora da indústria para se evitar as perdas. / The sugar-energy industry chain has a great influence on the Brazilian economy. Along the 2013/2014 crop, the industry accounted for about US$ 100 billion, and sugar alone yielded about US$ 5.55 billion to sugar mills. The industry yielded US$ 43 billion, accounting for approximately 2,0% of the Brazilian GDP. Nevertheless, the industry is facing an economic crisis aggravated by the drop prices of sugar bag and a severe drought that hit particularly the state of São Paulo in Brazil. Minimizing losses becomes essential in times of difficulties and a way to achieve it is to improve process monitoring. In this scenario, the present project monitored sucrose degradation in samples collected at sugar mill in the region of Piracicaba-SP, associating the degradation to high temperatures as well as other factors and measures used by the mill. As expected, sucrose concentration increased throughout the process, starting with an average of 137,69 g/L at milling and finishing with 812,91 g/L in sugar out of the dryer. However, there was also an increase of reducing sugars (182,38 g/L in milling juice to 245,81 g/L in syrup), indicating sucrose degradation. There was a larger reversal rate during evaporation than in the treatment (0,46 and 0,28, respectively). This is possibly attributed to a pH decrease, an evident use of greater amount of heat in particular in the first effect, a longer time than normal in evaporators or even due to steam inlet into the bodies, which is rarer. The other parameters arising from sucrose thermal degradation, 5-hydroxymethylfurfural, furfural and melanoidins, showed a high correlation with the concentration of reducing sugars (0,99 for HMF, 0,98 for furfural and 0,96 for melanoidins), confirming the trend for loss of the molecule of interest. We also investigated the total populations of mesophilic bacteria, whose presence is associated with health conditions where the food was processed, as well as fungi (molds and yeasts), which also decreases the value of the final product, may produce mycotoxins. The syrup treatment was effective to reduce microorganisms. Considering the average, the population of mesophilic bacteria decrease from 4,10 x 106 cfu/mL to 6,62 x102 cfu/mL. For fungi, the reduction was 1,40 x 104 cfu/mL to 1,80 x 101 cfu/mL. However, the high concentrations found at the beginning and end (Bacteria on average 3,00 x 103 cfu/g in syrup and 2,26 x 103 cfu/g in sugar at the dryer. Fungi 3,50 x 101 cfu/g in syrup and 1,49 x 103 cfu/mL in sugar at the dryer) of the process are indicative of oversights with asepsis, using the lack of demand for quality VHP sugar. The high concentration of juice at milling showed potential to be related sucrose loss. Finally, assessing the scenario and considering that investment in new equipment is something out of the financial reality of the sugar mill, improving the operations inside and outside the mill to avoid losses is suggested.

Modernas empresas buscam a melhoria dos seus sistemas de produção a fim de aumentar a produtividade e a qualidade de produtos. A tecnologia de usinagem com alta velocidade de corte (HSC – High Speed Cutting) permite aumentar as taxas de remoção de material, as tolerâncias dimensionais das partes, assim como a melhoria do acabamento superficial. Esta tecnologia tem sido muito utilizada na área de moldes e matrizes, pois minimiza o problema de tempos de usinagem longos na produção e facilita a obtenção de elevada qualidade, normalmente requerida em produtos injetados/estampados. Atualmente diversos estudos em HSC buscam a compreensão de todos os fatores envolvidos nesta nova tecnologia, a qual ainda apresenta diversas lacunas para o seu domínio completo. Este trabalho apresenta um estudo teórico-experimental da condução de calor nos materiais utilizados na fabricação de moldes e matrizes, submetidos à usinagem com altas velocidades de corte. Os materiais utilizados foram os aços AISI D2 e AISI H13, muito utilizados nas indústrias de moldes e matrizes. Os ensaios foram realizados com fresas de ponta esférica (Ball-Nose) com e sem angulação de hélice e com ângulo de saída neutro, com revestimento de ('TI'AL')N e com uma ferramenta com uma placa de PcBN soldada. A geometria dos corpos-de-prova foi projetada para aproximar-se dos casos reais encontrados na indústria, casos em que superfícies complexas e paredes finas são comumente usinadas em matrizes e moldes. Dois sistemas de resfriamento foram utilizados o ar comprimido e o ar gelado utilizando o princípio de vórtice. Os resultados demonstraram uma pequena variação da temperatura em função dos materiais empregados e das ferramentas utilizadas em todos os testes. Os dois sistemas de resfriamento alternativos à usinagem sem sistema de resfriamento, o ar comprimido e o ar frio, também se mostraram influentes na variação da temperatura, apresentando-se como sistemas capazes de remover o calor no processo durante a usinagem. Os desvios de forma encontrados nos corpos-de-prova devem ser considerados na usinagem de perfis muito precisos. Foram encontrados valores da ordem de 0,05 mm, oriundos da combinação de distorções térmicas e tensões residuais, os quais podem ser signifcativos, por exemplo, na área de matrizaria / Modern industries improve their production systems aiming at increasing productivity and product quality. The high speed cutting (HSC) technology allows increasing material removal rates, workpiece dimensional tolerance and surface finishing as well. Such technology has been extensively used in mold and dies areas, since it minimizes long lead time problems and facilitates high quality machining, normally required in injected/formed products. Nowadays, several studies in HSC search for understanding all aspects involved in that new technology, which still presents many blanks for its complete knowledge. The present work shows a theoretical and experimental study on heat conduction flux in materials applied to mold and die manufacturing, submitted to HSC. It was used AISI D2 and AISI H13, which are very common in mold and die industry. Two types of cylindrical ball nose end milling tool were used in the experiments: coated with ('TI'AL')N and tipped with PcBN. The workpiece geometry was conceived to simulate real cases found in industry, in which complex surfaces and slim walls are commonly machined in molds and dies. Two cooling systems were used in the tests, compressed air and frozen air using vortex principle. Results indicated a small temperature variation as a function of machined materials and tools throughout the tests. Both alternative cooling systems, besides dry machining, compressed air and cool air, also demonstrated to affect temperature variation. They presented themselves as capable of remove heat from the process during the cutting operation. The form deviation found in the workpiece after machining must be considered when machining very precise profiles. Variation values of around 0.05 mm were found, coming from a combination of thermal distortion and residual stress, which could be significant, for example, in die manufacturing area

A cadeia sucroenergética tem uma grande influência para economia nacional. Ao longo da safra 2013/2014, a cadeia movimentou cerca de US$ 100 bilhões, sendo que somente o açúcar gerou uma arrecadação de cerca de US$ 5.55 bilhões as usinas. O Produto Interno Bruto chegou a US$ 43 bilhões, representando assim aproximadamente 2,0% do PIB Nacional. Todavia, o setor está atravessando uma crise econômica que foi potencializada pela queda no valor da saca de açúcar e por uma severa seca que atingiu em especial o estado de São Paulo. A diminuição de perdas se torna essencial em momentos de dificuldades e uma maneira de atingir esse objetivo é melhorando o monitoramento do processo. Nesse cenário, o presente pesquisa monitorou a degradação de sacarose ao coletar amostras em uma usina da região de Piracicaba-SP, associando como causador não somente as elevadas temperaturas, como outros fatores e medidas utilizadas pela indústria. Conforme esperado aumentou a concentração de sacarose ao longo do processo, iniciando com média de 137,69 g/L na moenda e finalizando com 812,91 g/L no açúcar que saiu do secador. Todavia também apresentou um aumento de açúcares redutores (182,38 g/L no caldo da moenda para 245,81 g/L no xarope), indicando a degradação de sacarose. Inclusive, percebe-se uma razão de inversão maior durante da evaporação do que no tratamento (0,46 e 0,28, respectivamente). A justificativa pode estar associada a possível queda no pH, a evidente utilização de maior quantidade de calor em especial no primeiro efeito, a um tempo de residência maior do que o normal nos evaporadores ou mesmo através da entrada de vapor nos corpos, sendo o último mais raro. Os outros parâmetros levantados da degradação térmica de sacarose, 5-hidroximetilfurfural, furfural e as melanoidinas apresentaram uma alta correlação em função da concentração de açúcares redutores (0,99 para o HMF, 0,98 furfural e 0,96 melanoidinas), confirmando a tendência de perdas da molécula de interesse. Também foram levantadas as populações de bactérias mesófilas totais, cujas presenças estão associadas com as condições sanitárias em que o alimento foi processado e fungos (bolores e leveduras) que também diminuem o valor do produto. O tratamento de caldo mostrou-se eficiente na diminuição dos micro-organismos. Considerando a média dos dois meses, a queda foi de 4,10 x 106 UFC/mL para 6,62x102 UFC/mL para bactérias mesófilas, já para fungos a redução foi de 1,40 x 104 UFC/mL para 1,80 x 101 UFC/mL. Todavia, as altas concentrações encontradas no início e no final (bactérias apresentaram em média 3,00 x 103 UFC/g no xarope e 2,26 x 103 UFC/g no açúcar do secador, enquanto que para os fungos foram encontrados 3,50 x 101 UFC/g no xarope e 1,49 x 103 UFCmL no açúcar do secador) são indicativos de descuidos com a assepsia, aproveitando a falta de exigência de qualidade no açúcar VHP. A alta concentração do caldo da moenda apresentou potencial de estar relacionado com a perda de sacarose. Por fim, ao avaliar a situação e considerando que investimento em equipamentos novos é algo fora da realidade financeira da usina, sugere-se trabalhar em aprimorar as operações realizadas dentro e fora da indústria para se evitar as perdas. / The sugar-energy industry chain has a great influence on the Brazilian economy. Along the 2013/2014 crop, the industry accounted for about US$ 100 billion, and sugar alone yielded about US$ 5.55 billion to sugar mills. The industry yielded US$ 43 billion, accounting for approximately 2,0% of the Brazilian GDP. Nevertheless, the industry is facing an economic crisis aggravated by the drop prices of sugar bag and a severe drought that hit particularly the state of São Paulo in Brazil. Minimizing losses becomes essential in times of difficulties and a way to achieve it is to improve process monitoring. In this scenario, the present project monitored sucrose degradation in samples collected at sugar mill in the region of Piracicaba-SP, associating the degradation to high temperatures as well as other factors and measures used by the mill. As expected, sucrose concentration increased throughout the process, starting with an average of 137,69 g/L at milling and finishing with 812,91 g/L in sugar out of the dryer. However, there was also an increase of reducing sugars (182,38 g/L in milling juice to 245,81 g/L in syrup), indicating sucrose degradation. There was a larger reversal rate during evaporation than in the treatment (0,46 and 0,28, respectively). This is possibly attributed to a pH decrease, an evident use of greater amount of heat in particular in the first effect, a longer time than normal in evaporators or even due to steam inlet into the bodies, which is rarer. The other parameters arising from sucrose thermal degradation, 5-hydroxymethylfurfural, furfural and melanoidins, showed a high correlation with the concentration of reducing sugars (0,99 for HMF, 0,98 for furfural and 0,96 for melanoidins), confirming the trend for loss of the molecule of interest. We also investigated the total populations of mesophilic bacteria, whose presence is associated with health conditions where the food was processed, as well as fungi (molds and yeasts), which also decreases the value of the final product, may produce mycotoxins. The syrup treatment was effective to reduce microorganisms. Considering the average, the population of mesophilic bacteria decrease from 4,10 x 106 cfu/mL to 6,62 x102 cfu/mL. For fungi, the reduction was 1,40 x 104 cfu/mL to 1,80 x 101 cfu/mL. However, the high concentrations found at the beginning and end (Bacteria on average 3,00 x 103 cfu/g in syrup and 2,26 x 103 cfu/g in sugar at the dryer. Fungi 3,50 x 101 cfu/g in syrup and 1,49 x 103 cfu/mL in sugar at the dryer) of the process are indicative of oversights with asepsis, using the lack of demand for quality VHP sugar. The high concentration of juice at milling showed potential to be related sucrose loss. Finally, assessing the scenario and considering that investment in new equipment is something out of the financial reality of the sugar mill, improving the operations inside and outside the mill to avoid losses is suggested.

Tez (Yüksek Lisans) - Süleyman Demirel Üniversitesi, Fen Bilimleri Enstitüsü, Gıda Mühendisliği Anabilim Dalı, 2008. / Kaynakça var.

Indirect additive processing of ferrous metals offers the potential to freeform fabricate parts with good surface finish and minimal dimensional variation from the computer solid model. The approach described here is to mix a ferrous powder with a transient binder followed by selective laser sintering (SLS) in a commercial polymer machine to create a “green” part. This part is post-processed to burn off the transient binder and to infiltrate the porous structure with a lower melting point metal/alloy. Commercially available SLSed ferrous components contain copper-based infiltrant in a ferrous preform. The choice of copper alloy infiltrant has led to inferior mechanical properties of these components limiting their use in many non-injection-molding structural applications, particularly at elevated temperature. In the present work, an attempt has been made to replace the copper-based infiltrant considering cast iron as a potential infiltrant because of its fluidity, hardness and stability at comparatively high temperature. A critical consideration is loss of part structural integrity by over-melting after infiltration as chemical diffusion of alloying elements, principally carbon, occurs resulting in a decrease in the melting temperature of tool steel preform. A predictive model was developed which defines the degree of success for infiltration based on final part geometry and depending on the relative density of the preform and infiltration temperature. The processing regime is defined as a function of controllable process parameters. An experimental program was undertaken using commercially available LaserForm[superscript tm] A6 tool steel that was infiltrated with ASTM A532 white cast iron. Guided by Ashby densification maps, pre-sintering of the A6 tool steel SLS part was performed to increase the part initial relative density prior to infiltration. The final infiltrated parts were analyzed for geometry, microstructure and hardness. The model may be extended to other ferrous powder and infiltrant compositions in an effort to optimize the properties and utility of the final infiltrated part. / text