The reactions of organomagnesium akoxides EtMgOR (R= Me, Et) with dialkynyl magnesium complexes Mg(CoCR¢F) (R¢F= tBu, SiMe3) give a series of the tetranuclear magnesium complexes [Mg4(OR)2Et2(CoCR¢F)4(THF)4] (R= Me, Et; R¢F= tBu, SiMe3). The reactions of diethyl magnesium complexes MgEt2 with alkynes HCoCR (R= tBu, SiMe3) give two different kinds magnesium complexes. One kind is [Mg4(OEt)2-Et2(CoCR)4(THF)4] (R= tBu, SiMe3); another kind is [Mg4O(CoCR)6(THF)4] (R= tBu, SiMe3). Besides, the reaction of diisopropylamide magnesium complex Mg(NiPr2)2 with alkyne HCoCtBu give first example including two different kind bridge ligands trinuclear magnesium complex Mg3(NiPr2)2(CoCtBu)4(THF)2.

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Thesis (Ph. D.)--Ohio State University, 1926. / Available online via OhioLINK's ETD Center

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Part of Thesis (Ph. D.)--University of Chicago, 1932. / Lithoprinted. "Private edition, distributed by the University of Chicago libraries, Chicago, Illinois."

Thesis (Ph. D.)--University of Michigan, 1929.

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At the time this work was begun, there was some confusion about the technique necessary for the successful synthesis of organomagnesium compounds in hydrocarbon solvents and without solvents. It was decided to repeat the work of Bryce-Smith and Zakharkin. Thus began the study of the synthesis of organomagnesium compounds without solvents; the study of the reaction products of these organomagnesium compounds in hydrocarbons plus 2-butanone compared to the reaction products of the corresponding etheral Grignard reagent plus 2-butanone; and a preliminary study of the nature of these organomagnesium compounds in hydrocarbon solvents.

Thesis (Ph. D.)--University of California, San Diego and San Diego State University, 2002. / Vita. Includes bibliographical references (leaves 124-134).