Thesis (Ph. D.)--University of Florida, 2000. / Title from first page of PDF file. Document formatted into pages; contains xxii, 263 p.; also contains graphics. Abbreviated abstract copied from student-submitted information. Vita. Includes bibliographical references (p. 252-262).

Thesis (Ph. D.)--University of Florida, 2000. / Title from first page of PDF file. Document formatted into pages; contains xxii, 263 p.; also contains graphics. Abbreviated abstract copied from student-submitted information. Vita. Includes bibliographical references (p. 252-262).

No description available.

Underground pipelines are used in various process piping systems to transport gasses or fluids and are usually subjected to the effects of external corrosion. Corrosion can be defined as the deterioration of a material due to a reaction with its environment or the destruction of the material by means that are not mechanical (Fontana and Greene, 1967:2). External corrosion, due to the interaction between the pipe and the soil, is generally a slow process and the corrosion rate is influenced by a variety of external factors. Some of these factors include the ambient pH and salinity, the presence of moisture and bacteria, temperature, the electrical potential difference between the pipe and other structures and the implementation of preventative measures (such as cathodic protection and wrapping). Although the external corrosion of underground pipelines is generally a slow process in mild environments, pipe degradation as a result of external corrosion remains one of the prevalent reasons for the failure of underground pipelines. As with many mechanical systems that are prone to fail at one time or the other, the high costs involved with unforeseen failure necessitate some quantitative (or qualitative) indication of the condition of the pipe system. Some of the costs that can be expected as a result of unforeseen pipeline failure are, amongst others: • costs as a result of the failure of dependent systems; • costs as a result of the loss of production; • costs as a result of the loss of product (in distribution networks); • the cost of unscheduled maintenance (logistical costs); • costs as a result of damage to public property; • fines imposed by customers (in distribution networks); • costs related to pollution control, and • the loss of life The single most important parameter associated with the condition of a system is its profitable remaining life. This is the time during which a sub-system contributes to the well-being of a larger system and the organisation. Therefore, it is necessary to determine, with reasonable accuracy, the extent of the remaining life of a system so that managerial decisions (i.e. investments, cash-flow analyses, maintenance task scheduling and replacement programmes), based on this figure, can be made. Done correctly, this can directly lead to a decrease in maintenance costs and subsequently to an increase in profit. The extent of a corrosive attack on the pipeline might be highly localised or might be fairly uniform over the length of the installation. The fact of the matter is that, since the pipe is buried, it is very difficult to quantify the external damage caused by corrosion. A variety of techniques are in use to survey pipelines and detect anomalies. However, for large pipelines, most of these techniques are either inefficient or too expensive. There will always remain some uncertainty regarding the integrity of the pipeline. The work presented in this study is explained with valid generic examples and aims: 1. to provide the reader with sufficient background information so that the need for determining the integrity of a pipeline becomes apparent; 2. to indicate why a reliability-centred approach is necessary (Chapter 1); 3. to explain the basic principles of corrosion and the electrochemical nature of corrosion (Chapter 2); 4. to indicate areas, based on the basic principles of corrosion, where severe corrosion can be expected (Chapters 2 and 7); 5. to provide and elaborate on information regarding pipe surveillance techniques that are currently available (Chapter 3); 6. to establish the criteria for pipeline failure, in the form of a limit state Junction, for pipes that are subjected to near-constant internal pressures (static failure domain) as well as for pipes subjected to varying internal pressures (fatigue domain) (Chapters 5 and 6); 7. to indicate the sensitivity of the fatigue domain solution to changes in the system variables and to indicate that a significant reduction in the system variables does not necessarily reduce the solution accuracy (Chapter 6), and 8. to integrate the above-mentioned into a practical and workable guideline that can be used to determine the remaining life of an underground pipe network (Chapter 7). / Dissertation (MEng (Mechanical Engineering))--University of Pretoria, 2002. / Mechanical and Aeronautical Engineering / unrestricted

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Today, ethanol, as well as other biofuels, has been increasingly gaining popularity as a major alternative liquid fuel to replace conventional gasoline for road transportation. One of the key challenges for the future use of bioethanol is to increase its availability in the market via an efficient and economic way. However, one major concern in using the existing gas-pipelines to transport fuel-grade ethanol or blended fuel is the potential corrosion and stress corrosion cracking (SCC) susceptibility of carbon steel pipelines in these environments. Both phenomenological and mechanistic investigations have been carried out in order to address the possible degradation phenomena of X-65 pipeline carbon steel in simulated fuel-grade ethanol (SFGE). Firstly, the susceptibilities of stress corrosion cracking of this steel in SFGE were studied. Ethanol chemistry of SFGE was shown to have great impact on the stress corrosion crack initiation/propagation and the corrosion mode transition. Inclusions in the steel can increase local plastic strain and act as crack initiation sites. Secondly, the anodic behavior of carbon steel electrode was investigated in detail under different ethanol chemistry conditions. General corrosion and pitting susceptibility under unstressed condition were found to be sensitive to the ethanol chemistry. Low tendency to passivate and the sensitivity to ethanol chemistry are the major reasons which drive corrosion process in this system. Oxygen plays a critical role in controlling the passivity of carbon steel in ethanol. Thirdly, the detailed study was carried out to understand the SCC mechanism of carbon steel in SFGE. A film related anodic dissolution process was identified to be a major driving force during the crack propagation. Fourthly, more detailed electrochemical impedance spectroscopy (EIS) studies using phase angle analysis and transmission line simulation reveal a clearer physical picture of the stress corrosion cracking process in this environment. Fifthly, the cathodic reactions of carbon steel in SFGE were also investigated to understand the oxygen and hydrogen reactions. Hydrogen uptake into the pipeline steel and the conditions of the fractures related to hydrogen embrittlement were identified and studied.