Spelling suggestions: "subject:"pnictides""
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Zur Darstellung und Kristallchemie von Pnictidostannaten sowie Pnictidoxiden und damit verwandten Pnictiden der Alkali- und ErdalkalimetalleRössler, Ute. January 1999 (has links) (PDF)
Darmstadt, Techn. Universiẗat, Diss., 1999.
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Untersuchung tiefliegender Elektronenzustände der Hauptgruppe V-Halogenide und Hydride (Deuteride) mittels Fourier-Transform-EmissionsspektroskopieBeutel, Markus. January 1999 (has links) (PDF)
Wuppertal, Universiẗat, Diss., 2000.
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Pentahalogenide und Oxidhalogenide der Elemente der fünften HauptgruppeHaupt, Silvia. January 2002 (has links)
Berlin, Freie Universiẗat, Diss., 2002. / Dateiformat: zip, Dateien im PDF-Format.
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Tri(alkyl)silylsubstituierte Pentelide und Penteldiide der ersten und dritten HauptgruppeWeinrich, Sabine. Unknown Date (has links) (PDF)
Universiẗat, Diss., 2003--München.
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Pentelide und Penteldiide der Erdalkalimetalle und des Yttriums Synthese und Reaktivität /Schneiderbauer, Stefan. Unknown Date (has links) (PDF)
Universiẗat, Diss., 2002--München.
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Investigation and Characterization of Rare-earth Pnictide Suboxides for Thermoelectric ApplicationsForbes, Scott 11 1900 (has links)
Several rare-earth pnictide suboxides were investigated for their structures, chemistry, and physical properties. The goal of this research was to develop a highly stable material that could combine the thermally insulating properties of a rare-earth oxide framework with the electrically conductive properties of a rare-earth pnictide framework. These materials were synthesized by solid state reactions at high temperatures, producing highly pure products for measurement. All phases were subjected to several different forms of analysis, including X-ray powder and single crystal diffraction, energy dispersive X-ray spectroscopy (EDS), electron microprobe analysis (EPMA), magnetization, and hall resistivity measurements. Sufficiently pure bulk samples were then measured for thermoelectric properties in terms of electrical resistivity, Seebeck coefficient, and thermal conductivity, where applicable. The roles of structure and chemistry for each phase were then discussed with respect to the obtained physical properties and calculated electronic structures.
Seven distinct classes of rare-earth pnictide suboxides were investigated in this dissertation: the tetragonal (REIREII)3SbO3 phases (space group C2/m), the CaRE3SbO4 phases (space group I4/m), the Ca2RE8Sb3O10 phases (space group C2/m), the Gd3BiO3 phase and Gd8Bi3O8 phases (space groups C2/m), and the Ca2RE7Sb5O5 phase and Ca2RE7Bi5O5 phases (space groups P4/n). All of these phases share many common structural features, and can be related by different RE4O tetrahedral building block stacking sequences and locations of the pnictide atoms.
Structurally speaking, the simplest possible arrangement of the RE-O and RE-Pn frameworks we investigated are found in the CaRE3SbO4 phase. This phase contains the smallest unit cell of all known rare-earth pnictide suboxides with only a two unit RE4O tetrahedral building block and ordered antimony atoms. Extended heat treatments gradually convert this phase into the corresponding Ca2RE8Sb3O10 phase, with a significantly more complicated arrangement of RE4O building blocks. By controlling the loading composition and reaction conditions, the CaRE3SbO4 phase can be prepared as a kinetic product, while the Ca2RE8Sb3O10 phase forms as the thermodynamic product. Likewise, the tetragonal (REIREII)3SbO3 phases can also be prepared through high temperature reactions. This phase contains a unique three RE4O unit (RE8O3) building block in its structure, which creates two rare-earth sites with a large difference in site volume. Thus, this phase can only be prepared when two rare-earth atoms of sufficiently different size are present.
Despite similar structures, the physical properties of the studied rare-earth pnictide suboxide phases can display quite different behavior. For the CaRE3SbO4, Ca2RE7Sb5O5, Ca2RE7Bi5O5, and tetragonal (REIREII)3SbO3 phases, the electrical resistivity remains fairly constant throughout the series, which can be traced to their highly ordered structures, as well as the physical and chemical similarities between rare-earths. Conversely, the more structurally disordered Ca2RE8Sb3O10 and Gd8Bi3O8 phases behave as semiconductors despite the fact they are not charge balanced. This anomalous behavior arises from the disorder of Sb and Bi atoms, which are responsible for electrical conduction in the phase. Interestingly, the level of disorder and thus, the magnitude of the electrical resistivity, can be greatly influenced by the rare-earth atom that is present, despite maintaining similar structures and charge carrier concentrations. Smaller rare earth atoms introduce a larger chemical pressure on the disordered antimony/bismuth atoms which lowers the range of Anderson localized states, pushing the system closer to metallic-type conduction. / Thesis / Doctor of Philosophy (PhD)
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Search for Unconventional Superconductors at the Itinerant-to-Local Moment CrossoverZhao, Liang 05 June 2013 (has links)
In searching for novel optimal superconductors, three strategic routes based on theoretical and experimental knowledge from the known high-Tc superconductors are followed.
CaFe4As3 is a newly discovered 3D compound, with Fe2+ in tetrahedral coordination, similar to that in the parent compounds of the known superconductors. The thermodynamic and transport properties reveal a spin density wave (SDW) transition at TN = 88 K, and an incommensurate-to-commensurate SDW transition at T2=26.4 K. A large electronic specific heat coefficient γ=0.02 J/molK^2 and an unusually high Kadowaki-Woods (KW) ratio A/γ^2=55×10E−5 μΩcm mol^2K^2/mJ^2 point to strong electron correlations. While the commensurate SDW state below T2 is suppressed in Co-doped CaFe4As3, neither doping with P, Yb, Co and Cu, nor application of hydrostatic pressures up to 5 GPa, is able to fully suppress the robust incommensurate SDW order in this system.
The new layered compound SrMnBi2 has been studied as a promising candidate for high Tc superconductivity as suggested by theoretical calculations. We found that SrMnBi2 is structurally similar to, but more two dimensional than the known Fe superconductors. Two phase transitions at T1=292 K and T2=252 K have been observed. A large electronic specific heat coefficient γ=36.5 mJ/molK^2 and a KW ratio of 9.38×10E−5 μΩcm mol^2K^2/mJ^2 indicate enhanced electron correlations. DFT calculations have revealed metallic Sr-Bi layers in SrMnBi2, as well as Dirac-cone like features in the band structure.
Doping experiments on the Mott insulator Sr2F2Fe2OS2 have been carried out to search for superconductivity at the localized-to-itinerant moment crossover. Increasing amounts of T=Mn in Sr2F2(Fe1−xTx)2OS2 suppress the long range magnetic ordering at x≈0.2, and the subsequent increase in x results in a spin glass behavior for 0.2≤x≤0.5, and possibly a new magnetic order for x≥0.5. By contrast, Co-doping increases the AFM transition from TN=106 K for x=0 up to 124 K for x=0.3. The excitation gap determined from the electrical resistivity is minimized but remains finite around x=0.5 for T=Mn.
In addition, a study has been done on a rare binary type I superconductor YbSb2. Besides the superconducting transition at Tc=1.30 K, a possible second superconducting phase is observed below Tc(2)=0.41 K. From thermodynamic and transport measurements, there is strong, unambiguous evidence for the type I nature of the superconductivity in YbSb2.
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Search for Unconventional Superconductors at the Itinerant-to-Local Moment CrossoverZhao, Liang 05 June 2013 (has links)
In searching for novel optimal superconductors, three strategic routes based on theoretical and experimental knowledge from the known high-Tc superconductors are followed.
CaFe4As3 is a newly discovered 3D compound, with Fe2+ in tetrahedral coordination, similar to that in the parent compounds of the known superconductors. The thermodynamic and transport properties reveal a spin density wave (SDW) transition at TN = 88 K, and an incommensurate-to-commensurate SDW transition at T2=26.4 K. A large electronic specific heat coefficient γ=0.02 J/molK^2 and an unusually high Kadowaki-Woods (KW) ratio A/γ^2=55×10E−5 μΩcm mol^2K^2/mJ^2 point to strong electron correlations. While the commensurate SDW state below T2 is suppressed in Co-doped CaFe4As3, neither doping with P, Yb, Co and Cu, nor application of hydrostatic pressures up to 5 GPa, is able to fully suppress the robust incommensurate SDW order in this system.
The new layered compound SrMnBi2 has been studied as a promising candidate for high Tc superconductivity as suggested by theoretical calculations. We found that SrMnBi2 is structurally similar to, but more two dimensional than the known Fe superconductors. Two phase transitions at T1=292 K and T2=252 K have been observed. A large electronic specific heat coefficient γ=36.5 mJ/molK^2 and a KW ratio of 9.38×10E−5 μΩcm mol^2K^2/mJ^2 indicate enhanced electron correlations. DFT calculations have revealed metallic Sr-Bi layers in SrMnBi2, as well as Dirac-cone like features in the band structure.
Doping experiments on the Mott insulator Sr2F2Fe2OS2 have been carried out to search for superconductivity at the localized-to-itinerant moment crossover. Increasing amounts of T=Mn in Sr2F2(Fe1−xTx)2OS2 suppress the long range magnetic ordering at x≈0.2, and the subsequent increase in x results in a spin glass behavior for 0.2≤x≤0.5, and possibly a new magnetic order for x≥0.5. By contrast, Co-doping increases the AFM transition from TN=106 K for x=0 up to 124 K for x=0.3. The excitation gap determined from the electrical resistivity is minimized but remains finite around x=0.5 for T=Mn.
In addition, a study has been done on a rare binary type I superconductor YbSb2. Besides the superconducting transition at Tc=1.30 K, a possible second superconducting phase is observed below Tc(2)=0.41 K. From thermodynamic and transport measurements, there is strong, unambiguous evidence for the type I nature of the superconductivity in YbSb2.
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Search for Unconventional Superconductors at the Itinerant-to-Local Moment CrossoverZhao, Liang 05 June 2013 (has links)
In searching for novel optimal superconductors, three strategic routes based on theoretical and experimental knowledge from the known high-Tc superconductors are followed.
CaFe4As3 is a newly discovered 3D compound, with Fe2+ in tetrahedral coordination, similar to that in the parent compounds of the known superconductors. The thermodynamic and transport properties reveal a spin density wave (SDW) transition at TN = 88 K, and an incommensurate-to-commensurate SDW transition at T2=26.4 K. A large electronic specific heat coefficient γ=0.02 J/molK^2 and an unusually high Kadowaki-Woods (KW) ratio A/γ^2=55×10E−5 μΩcm mol^2K^2/mJ^2 point to strong electron correlations. While the commensurate SDW state below T2 is suppressed in Co-doped CaFe4As3, neither doping with P, Yb, Co and Cu, nor application of hydrostatic pressures up to 5 GPa, is able to fully suppress the robust incommensurate SDW order in this system.
The new layered compound SrMnBi2 has been studied as a promising candidate for high Tc superconductivity as suggested by theoretical calculations. We found that SrMnBi2 is structurally similar to, but more two dimensional than the known Fe superconductors. Two phase transitions at T1=292 K and T2=252 K have been observed. A large electronic specific heat coefficient γ=36.5 mJ/molK^2 and a KW ratio of 9.38×10E−5 μΩcm mol^2K^2/mJ^2 indicate enhanced electron correlations. DFT calculations have revealed metallic Sr-Bi layers in SrMnBi2, as well as Dirac-cone like features in the band structure.
Doping experiments on the Mott insulator Sr2F2Fe2OS2 have been carried out to search for superconductivity at the localized-to-itinerant moment crossover. Increasing amounts of T=Mn in Sr2F2(Fe1−xTx)2OS2 suppress the long range magnetic ordering at x≈0.2, and the subsequent increase in x results in a spin glass behavior for 0.2≤x≤0.5, and possibly a new magnetic order for x≥0.5. By contrast, Co-doping increases the AFM transition from TN=106 K for x=0 up to 124 K for x=0.3. The excitation gap determined from the electrical resistivity is minimized but remains finite around x=0.5 for T=Mn.
In addition, a study has been done on a rare binary type I superconductor YbSb2. Besides the superconducting transition at Tc=1.30 K, a possible second superconducting phase is observed below Tc(2)=0.41 K. From thermodynamic and transport measurements, there is strong, unambiguous evidence for the type I nature of the superconductivity in YbSb2.
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Search for Unconventional Superconductors at the Itinerant-to-Local Moment CrossoverZhao, Liang 05 June 2013 (has links)
In searching for novel optimal superconductors, three strategic routes based on theoretical and experimental knowledge from the known high-Tc superconductors are followed.
CaFe4As3 is a newly discovered 3D compound, with Fe2+ in tetrahedral coordination, similar to that in the parent compounds of the known superconductors. The thermodynamic and transport properties reveal a spin density wave (SDW) transition at TN = 88 K, and an incommensurate-to-commensurate SDW transition at T2=26.4 K. A large electronic specific heat coefficient γ=0.02 J/molK^2 and an unusually high Kadowaki-Woods (KW) ratio A/γ^2=55×10E−5 μΩcm mol^2K^2/mJ^2 point to strong electron correlations. While the commensurate SDW state below T2 is suppressed in Co-doped CaFe4As3, neither doping with P, Yb, Co and Cu, nor application of hydrostatic pressures up to 5 GPa, is able to fully suppress the robust incommensurate SDW order in this system.
The new layered compound SrMnBi2 has been studied as a promising candidate for high Tc superconductivity as suggested by theoretical calculations. We found that SrMnBi2 is structurally similar to, but more two dimensional than the known Fe superconductors. Two phase transitions at T1=292 K and T2=252 K have been observed. A large electronic specific heat coefficient γ=36.5 mJ/molK^2 and a KW ratio of 9.38×10E−5 μΩcm mol^2K^2/mJ^2 indicate enhanced electron correlations. DFT calculations have revealed metallic Sr-Bi layers in SrMnBi2, as well as Dirac-cone like features in the band structure.
Doping experiments on the Mott insulator Sr2F2Fe2OS2 have been carried out to search for superconductivity at the localized-to-itinerant moment crossover. Increasing amounts of T=Mn in Sr2F2(Fe1−xTx)2OS2 suppress the long range magnetic ordering at x≈0.2, and the subsequent increase in x results in a spin glass behavior for 0.2≤x≤0.5, and possibly a new magnetic order for x≥0.5. By contrast, Co-doping increases the AFM transition from TN=106 K for x=0 up to 124 K for x=0.3. The excitation gap determined from the electrical resistivity is minimized but remains finite around x=0.5 for T=Mn.
In addition, a study has been done on a rare binary type I superconductor YbSb2. Besides the superconducting transition at Tc=1.30 K, a possible second superconducting phase is observed below Tc(2)=0.41 K. From thermodynamic and transport measurements, there is strong, unambiguous evidence for the type I nature of the superconductivity in YbSb2.
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