Thesis (D.P.H.)--University of Alabama at Birmingham, 2007. / Title from PDF title page (viewed on Feb. 19, 2010). Includes bibliographical references (p. 145-153).

Calcined clay and fly ash supplementary cementitious materials (SCMs) used in cement based materials were examined for their chemical and mechanical performance, as well as their pollutant interaction. This dissertation addresses three primary research questions, namely: (i) can zincite additions facilitate the use of calcined clay as SCMs by compensating for reductions in early-age mechanical performance or by compensating for their reduced pozzolanic reactivity, (ii) can cement renders, containing metakaolin calcined clays, be engineered for passive carbon dioxide and ozone removal, and (iii) how do the specific activity and emanation fractions of concrete constituents, including fly ash and metakaolin, as well as assembled concretes impact concrete radon emanation and indoor radon concentrations? The first question relates directly to the development of new, sustainable material options, which can replace a portion of cement in a concrete mixture. Results from the experiments with zincite showed that the treatment method removed the dilution effect that occurs when using less reactive materials to substitute a portion of portland cement, but did not considerably influence mechanical properties. Therefore, zincite additions are not a good means of enhancing the utilization of non-kaolinite clays in concrete. As an integrated system, the latter two questions of this dissertation investigate the interaction between airborne pollutants and the cement based materials containing SCMs. The use of SCMs in render and concrete systems resulted in different pollutant uptake and exhalation behavior, relative to non-SCM control systems. For pollutant uptake, render systems containing metakaolin increased the carbon dioxide ingress while decreasing the ozone uptake. For radon exhalation rates, modeling results demonstrated that concretes without fly ash have a higher probability of containing less total radium and lower radon exhalation rates, when compared to samples with fly ash, assuming an emanation fraction of 5%, as suggested in the literature. Experimental results demonstrated that metakaolin, fly ash and control concretes had emanation fractions of 7%, 9% and 13%, respectively, confirming that (i) an assumed fraction of 5% would underpredict indoor radon concentrations and potential health consequences, and (ii) SCMs can reduce the total concrete emanation fraction. This dissertation demonstrates how the use of sustainable material selections, such as calcined clays and fly ashes, not only influences the microstructure and mechanical performance of the cement based materials, but also alters the interaction of the material with its surrounding environment. / text

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published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy

The UPPER (Unified Physicochemical Property Estimation Relationships) model uses additive and non-additive parameters to estimate 21 biologically and environmentally important physicochemical properties of organic compounds. Thermodynamically sound relationships are used to predict boiling and melting points, aqueous and octanol solubilities, vapor pressure and the air-octanol, air-water and octanol-water partition coefficients. These properties determine the distribution and fate of organic compounds in biological and environmental systems. The model has been validated on a data set of 2000 hydrocarbons and polyhalogenated hydrocarbons, provides a simple and accurate method to predict the properties studied.

10 pp. / Introduction: Adult human beings may drink up to two liters/day (approx. two quarts/day) of fresh water to stay alive. However, we can consume up to two quarts/hour of water, depending on the level of activity, ambient temperature, and humidity conditions (Born 2013). We also need fresh water to cook with and to clean ourselves. About 40% of our food production depends on irrigation (UN Water 2013) using water with low salinity and other contaminants. Climate scientists project increasing temperatures and possibly less rainfall in the Southwest now and into the near future, see Extension Publication #AZ1458 (Artiola et al. 2008). Thus, climate change is likely to stress the limited water resources of Arizona and affect water quality by concentrating contaminants and stressing water-dependent environments. This publication presents brief summaries of the types of water sources, their water quality, and possible uses in Arizona. Since the types and amounts of constituents found in water, whether nutrients, pathogens, contaminants or pollutants, help determine its possible uses, it is necessary to measure water quality to determine treatment options for a given use. To assist in this task, we present a triangle-shaped diagram (Figure 8) which divides water quality into three major groups: Pathogens, Salinity, and Specific Contaminants, placing major water sources in relation to the three groups. Home and well owners can use this diagram as a general aid to evaluate various sources of water, determine their likely water quality, and identify appropriate uses for them.

Šio darbo pagrindinis tikslas − įvertinti radioaktyviųjų teršalų paplitimą atmosferoje ir nusėdimą, bei įvertinti teršalų žalą aplinkai ir žmonėms. Tam tikslui pasiekti, šiame darbe buvo: 1.išanalizuoti pagrindiniai radioaktyviųjų teršalų paplitimo būdai; 2.supažindinta su teisės aktais ribojančiais radionuklidų išmetimą į aplinką; 3.įvertinti labiausiai žmonių sveikatą įtakojančių radionuklidų ir sklidimą atmosferoje ir nusėdimą. / In Lithuania we have a very important object from the point of energetics. It’s atomic power − station of Ignalina. It is work safety aspects worry so the themes of the graduate work have been chosen for this clean reason. The base of the work is to evaluate the damage of the radiological nuclides and to the environment and people and their discharge amounts the atmosphere, if it doesn’t exceed allowable norms, witch are regulated by the laws of Lithuania Republic. Willing to introduce you to this theme the following objectives were defined: 1.The main ways of radiological pollutants discharge into the atmosphere have been analyzed; 2.Have been familiarized with the main norms of radiological safety and the limitation of the discharge of radio nuclides into the atmosphere from the objects of atomic energetics; 3.According to the push − button program of environment pollution “ Hysplit ” the distribution of the radiological nuclides in the atmosphere has been denoted; 4.According to the results having been done by the program “ Hysplit “, the diagram of the dependence of the nuclides and on time has been delineated. It is clear that the atmosphere doesn’t exceed allowable norms of the laws of Lithuania Republic. It’s even lower than allowable norms per day. In conclusion, having all the objectives of this work analyzed it becomes clear that the amounts of the nuclides and witch gets into the atmosphere doesn’t damage our organisms and environment.

No description available.

No description available.

Little is currently known regarding the nature and consequences of interactions between photoactive surfaces, including mineral dust and ‘urban film’, and gas-phase pollutants in urban environments. In order to address this knowledge gap, this thesis explores the photochemical reactivity of these environmental surfaces in controlled laboratory settings. The photoenhanced ozonation of pyrene, a toxic product of incomplete combustion, proceeds at different rates and via different mechanisms at three model ‘urban film’ surfaces. These results are important because they suggest that the reactivity of a molecule on simplified surfaces may not accurately reflect its reactivity in the real environment. The photooxidation of isopropanol at the surface of TiO2, here used as a proxy for the photoactive component of mineral dust, yields gas-phase acetone. This chemistry is amplified by nitrate, a major surficial component of atmospherically processed dust. These results suggest that dust has the potential to convert non-absorbing species to photochemically active species, and thereby serve as a source of reactive organic radicals for further gas- or surface-phase chemistry. Oxalic acid, the most atmospherically abundant dicarboxylic acid, is efficiently oxidized to gas-phase CO2 at the surface of Mauritanian sand and Icelandic volcanic ash. These experiments indicate that the lifetime of oxalic acid may be limited in arid regions by Fe and Ti-catalyzed aerosol-phase photochemistry. Fluorotelomer alcohols (FTOHs), a class of industrial chemicals used in the production of surface coatings, undergo photooxidation at the surface of sand and ash to yield toxic and persistent perfluorinated carboxylic acids (PFCAs). These results provide the first evidence that the metal-catalyzed heterogeneous oxidation of FTOHs may act as a local source of aerosol-phase PFCAs. Illumination of Nigerien sand in the presence of gas-phase SO2 leads to the formation of surface-sorbed sulfate. This chemistry proceeds more efficiently on fine sand than on coarse sand. In chamber experiments, the illumination of SO2 in the presence of realistically produced dust aerosol results in new particle formation. Together, these results suggest that SO2 photochemistry at the dust surface has the potential to change not only dust hygroscopicity but also the net scattering potential of dust-containing air masses.