A review of the main natural dyes (particularly yellow flavonoids and red anthraquinones) and proteinaceous substrates used in Historical Tapestries and North American porcupine quill work was undertaken, and is summarised in Chapter 1. The analysis of natural dyes which have been used on museum artefacts other than textiles has received little systematic study, particularly those of non-European origin. In this research, the use of Ultra Performance Liquid Chromatography (UPLC) for study of natural dyes found on historical textiles and ethnographical objects decorated with porcupine quill work is explored; this required a transfer of existing analytical protocols and methodology. The advantages of using Ultra Performance Liquid Chromatography (UPLC) was evaluated through a method development based on the separation and quantification of ten flavonoid and anthraquinone dyes as described in Chapter 2. These methods were then applied to the characterisation of the dye sources found on a group of sixteenth century historical tapestries which form an important part of the Burrell Collection in Glasgow and are believed to have been manufactured in an English workshop (Chapter 3) and also to the analysis of some late nineteenth century North American porcupine quill work from a collection owned by National Museums Scotland (Chapter 5); allowing exciting conclusions to be drawn in each case about the range of dyestuffs used in their manufacture. The second aim of this research was the development of methodology for the non-invasive quantification of metal ion residues on porcupine quill substrates. This was achieved through a comparative study of reference porcupine quills prepared in-house with dyebaths containing a range of metal ion concentrations (copper and tin). The concentration of metal ions sorbed by the porcupine quills was then quantified with Inductively Coupled Plasma (ICP) coupled to Optical Emission Spectrometry (OES) and non-invasive Particle Induced X-Ray Emission analysis (PIXE) coupled with Rutherford Backscattering Spectrometry (RBS) as described in Chapter 4. The responses provided by the different methods were compared and they were then applied to the study of micro-samples collected from mid-nineteenth century Northern Athapaskan porcupine quill work. Unexpectedly, the use of UPLC analysis and RBS-PIXE analysis allowed the characterisation of traded European natural dyes used with metallic mordants (copper and tin) on these samples, highlighting how European contact impacted on traditional Athapaskan porcupine quill work in the late nineteenth century (Chapter 5).

North American porcupine (Erethizon dorsatum) feeding scars on trees were used as an index of past porcupine abundance in the Bas St. Laurent region of eastern Quebec, Canada. The frequency distribution of scars revealed that porcupine populations have fluctuated regularly over the past 130 years in the Bas St. Laurent region, with superimposed periodicities of 11 and 22 years. This porcupine population cycle has closely followed the 11 and 22-year solar activity cycles. An analysis of local temperature and precipitation data revealed a close relationship between fluctuations in annual precipitation and both the solar cycle and the porcupine cycle. These results suggest that the solar cycle has sufficiently important effects on the climate along the southern shore of the St. Lawrence estuary to influence terrestrial ecosystem functioning to the point of setting the rhythm of porcupine population fluctuations. This is the strongest available evidence of a top-down cascading effect of solar variability on ecological systems at the decadal time scale and local spatial scale. These results confirm and extend those obtained by others at greater temporal and spatial scales and provide exciting opportunities for future research on the extensively debated topic of solar variability and its impact on our planet.

An exploratory analysis in low-dimensional objective space of the vector evaluated particle swarm optimization (VEPSO) algorithm is presented. A novel visualization technique is presented and applied to perform the exploratory analysis. The exploratory analysis together with a quantitative analysis revealed that the VEPSO algorithm continues to explore without exploiting the well-performing areas of the search space. A detailed investigation into the influence that the choice of archive implementation has on the performance of the VEPSO algorithm is presented. Both the Pareto-optimal front (POF) solution diversity and convergence towards the true POF is considered during the investigation. Attainment surfaces are investigated for their suitability in efficiently comparing two multi-objective optimization (MOO) algorithms. A new measure to objectively compare algorithms in multi-dimensional objective space, based on attainment surfaces, is presented. This measure, referred to as the porcupine measure, adapts the attainment surface measure by using a statistical test along with weighted intersection lines. Loosely based on the VEPSO algorithm, the multi-guided particle swarm optimization (MGPSO) algorithm is presented and evaluated. The results indicate that the MGPSO algorithm overcomes the weaknesses of the VEPSO algorithm and also outperforms a number of state of the art MOO algorithms on at least two benchmark test sets. / Thesis (PhD)--University of Pretoria, 2017. / Computer Science / PhD / Unrestricted

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