NDLTD Global ETD Search
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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.

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Spelling suggestions: "subject:"purpurlides"" "subject:"purpuralis""

1

TOTAL SYNTHESES OF BERGAMOTANE SESQUITERPENES AND LYCOPODIUM ALKALOIDS AND COMPUTATIONAL STUDY TOWARD DIAMINATION OF ALLENES AND [2+2] SELECTIVITY

Ye-Cheng Wang (14009903) 27 October 2022 (has links)
<p>Total synthesis of massarinolin A, purpurlides B, D, E, 2,3-deoxypurpurolide C, phleghenrines A and B were finished. A halogen bond promoted michael addiation was discovered during mechanism study toward diamination of allenes. Computational chemsitry study conducted toward the selectivity of 2+2 reaction supported the proposed key reaction during total synthesis of gibberellic acid 18.</p>
Organic chemical synthesis
total synthesis
flow chemistry
structural revision
diamination
2+2
massarinolin
purpurolide
phleghenrine
gibberellic acid 18

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