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A detailed geochronological and geochemical study has been undertaken on selected sediment cores from four lowland coastal marsh environments in Argyll, Western Scotland. This region of northern Britain has experienced differential crustal uplift and relative sea-level changes throughout the Holocene in response to glacio-isostatic adjustment. The complex interplay between land movements and relative sea-level continues to influence the morphological development of the Scottish coast. The study of lowland inter-tidal sedimentary environments from this region provides an opportunity to investigate the linkages between current estimated crustal movements, regional relative sea-level rise and the evolution of contemporary coastal saltmarshes derived from the record of historical sedimentation. The four sites are located across a ca. 70 km transect extending from the head of Loch Scridain (western Isle of Mull), across the Firth of Lorne to the head of Loch Etive, (mainland Argyll). Vertical activity distributions of the natural radionuclide 21OPb and anthropogenic isotopes (137Cs and 243Am) have been measured and are used to assess the depositional history of marsh sediment accumulation recorded in the four marsh cores. Down-core activity profiles of radionuclides are only reliable as a means of modelling recent marsh evolution provided no early-diagenetic (redox) reactions have compromised the historical depositional record within the marsh sediments. Solid-phase major and trace element down-core geochemical distributions provide a means of assessing the extent to which post-depositional (redox) reactions may have influenced the reliability of the radiometric dating methods. Marsh sediment geochemistry also serves as a useful proxy for identifying compositional variability over the period of marsh development investigated. Dating of the Argyll saltmarsh cores indicates that over the period corresponding to mature marsh conditions rates of sedimentation vary significantly across the study area. At Loch Scridain an average rate of 1.1 mm yr-1 corresponding to an historical period of ca. 130 years is recorded. Comparison with estimated rates of regional sea-level rise suggest an established asymptotic relationship between marsh accretion and coastal forcing, implying historical crustal stability at this site. At sites within the Firth of Lome (Loch Don and Loch Creran) average rates of 2.5 and 3.3 mm yr-1 are recorded for the ca. 70 year period to 1995 with a figure of 2.2 mm yr-1 recorded in the marsh core from the head of Loch Etive. These values are well in excess of estimated relative sea-level rise during the twentieth century suggesting that these marshes may not yet have reached full equilibrium with sea-level. Microfossil analysis of the Loch Etive core helps to identify a more complex depositional history with an underlying trend of marine transgression for the ca. 110 year period of marsh development recorded in these sediments. Over the most recent period of marsh development (ca. 5 years) a significant increase in the rate of marsh sedimentation at all sites is recorded. This signifies the response of these marshes to a very recent increase in the rate of relative sea-level rise across the region. Comparison with available storm frequency data indicates that the evolution of these marsh environments have not been subject to the influence of significant storm activity over the last in the late Twetieth century. The findings suggest that the more clastic sedimentary composition of the Argyll marshes results in these inter-tidal areas being extremely sensitive to changes in coastal forcing (sea-level rise). The implications of recent relative sea-level rise, current vertical crustal movements and future coastal management are discussed.

Ce travail retrace l’évolution varisque des Massifs d’Almǎj (Roumanie), de Deli Jovan (Serbie) et de la Stara Planina Occidentale (Bulgarie), à travers une étude pétrostructurale effectuée sur les différentes unités lithologiques de la Nappe alpine du Danubien supérieur. Cette nappe possède la particularité de contenir un marqueur de convergence de toute première importance sous la forme de 4 massifs ophiolitiques démembrés lors de l’orogenèse alpine :Tisoviţa Iuţi (TI, Roumanie), Deli Jovan (DJ, Serbie), Zaglavak (Z, Serbie) et Tcherni Vrah (TV, Bulgarie). Les études pétrologiques de terrain effectuées dans ces trois pays ont permis de confirmer la continuité entre ces 4 massifs, qui, séparément, comprennent chacun une portion de croûte océanique différente (TI :section mantélique et cumulats inférieurs, DJ :cumulats inférieurs et supérieurs, Z :cumulats supérieurs, TV :cumulats supérieurs et section effusive), mais considérés ensemble, forment une pile ophiolitique classique complète. De nouvelles datations par la méthode 147Sm-143Nd confirment un âge d’accrétion pour cette croûte océanique au Dévonien inférieur (~ 400 Ma). Cependant, l’essentiel de ce mémoire concerne les Monts Almǎj, notamment les roches encaissantes du massif de Tisoviţa Iuţi. La partie sud de ce massif ophiolitique représente la section inférieure d’une croûte océanique classique, alors que sa partie orientale est caractérisée par des roches de la croûte océanique supérieure, fortement déformées et transformées (métagabbros à zoïsite et fuchsite). Ces roches font partie de la Zone Mylonitique de Corbu (CMZ), qui comporte également des métasédiments à Gt ± St ± And et des serpentinites. Les conditions PT de formation de ces métagabbros, datés à 380-360 Ma par la méthode 40Ar-39Ar, ont été estimées à des températures comprises entre 450°C et 300°C. Leur contexte de formation peut être assimilé à une semelle ophiolitique ‘froide’, développée lors d’une obduction intra-océanique initiée probablement le long d’une faille transformante. Si le pic de métamorphisme des roches de Corbu a été estimé à 585°C/ 5.5 kbar, leur exhumation pourrait s’effectuer au sein d’un anticlinal en régime transpressif sénestre, en relation avec la formation de la CMZ, interprétée comme une ancienne zone plissée qui évolue en zone de cisaillement sénestre. Au Carbonifère, le granite syntectonique de Cherbelezu se met en place le long de la CMZ et enregistre les dernières phases de cette déformation lors de son refroidissement. Les études préliminaires sur les roches encaissantes des massifs ophiolitiques en Serbie et Bulgarie permettent de préciser une vergence d’obduction du lambeau ophiolitique vers le paléo-NW et d’établir un modèle de reconstitution paléogéodynamique au Varisque pour l’ensemble de la région étudiée./ This study provides new information on the Variscan evolution of the Almǎj Mountains (Romania), Deli Jovan Massif (Serbia) and Western Stara Planina (Bulgaria), throughout a petrostructural investigation conducted on the various lithological units of the Upper Danubian Alpine Nappe. This nappe displays an important convergence tectonic marker in the form of four ophiolitic massifs dismembered during the Alpine orogeny: Tisoviţa Iuţi (TI, Romania), Deli Jovan (DJ, Serbia), Zaglavak (Z, Serbia) and Tcherni Vrah (TV, Bulgaria). Our petrological studies in these three countries have confirmed the continuity between these four massifs, each of which showing, separately, a different portion of the oceanic crust (TI: mantle section and lower cumulates, DJ: lower and upper cumulates, Z: upper cumulates, TV: upper cumulates and effusive section), but taken together, forming a complete classical ophiolitic pile. New dating using the 147Sm-143Nd method has confirmed an accretion age for this oceanic crust at around 400 Ma (Early Devonian). However, the main part of this study has been focused in the Almǎj Mountains, particularly the Tisoviţa Iuţi ophiolitic massif and its enclosing rocks. The Southern part of this ophiolitic massif represents the lower section of a classical oceanic crust whereas its eastern part is characterized by upper crustal oceanic rocks that are highly deformed and transformed (zoïsite and fuchsite-bearing metagabbros). These rocks belong to the Corbu Mylonitic zone (CMZ), which also comprises Gt ± St ± And metasediments and serpentinites. Temperature estimates for the formation of the metagabbros are bracketed between 450°C and 300°C and these rocks have been dated at 380-360 Ma using the 40Ar-39Ar method on fuchiste. The geodynamic context for their formation can be viewed as a ‘cold’ ophiolitic sole, developed during an intra-oceanic obduction probably initiated along transform fault. If the metamorphic peak for the Corbu rocks has been estimated at 585°C/5.5kbar, their rapid exhumation could be realized via an anticline under a transpressive sinistral regime, connected with the formation of the CMZ that is interpreted as an ancient fold zone evolving in a sinistral shear zone. Finally, the Carboniferous syntectonic Cherbelezu granite intrudes along the CMZ and records the final stages of this deformation during its cooling. Preliminary investigations on the enclosing rocks of the ophiolitic massifs in Serbia and Bulgaria allow us to define a top to the NW obduction vergence for the ophiolite and to propose a paleogeodynamic reconstitution model for the Carpathian/Balkans terrains in the Variscan times. / Doctorat en Sciences / info:eu-repo/semantics/nonPublished