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Applications of nonlinear raman spectroscopyMelin, St��phanie 04 September 2002 (has links)
Two nonlinear optical experiments are presented in which the third-order
electronic susceptibility of molecules is used to generate Raman signals. The first
one uses a single 532 nm beam from a Nd:YAG laser to produce Stimulated Raman
Scattering in benzene and deuterated benzene. With a simple experimental set-up,
stimulated emission involving CC and CH (CD) stretching modes from both C���H���
and C���D��� can be visually witnessed. Collinear and conical stimulated Raman beams
are observed and explained. Measuring the wavelengths of the coherent beams with
a meter stick and a grating permits the calculation of CC and CH force constants in
benzene. This experiment has been developed as a lab in graduate and
undergraduate courses and has been submitted to J. Chem. Ed. for publication.
The second experiment uses a high resolution Coherent Anti-Stokes
spectrometer to investigate the v��� vibrational mode of the CD��� radical produced by
photolysis of CD���I. Calibrated spectra are obtained at much higher resolution than
in an earlier published study and efforts are described to improve the range of data
and to reconcile differences between the spectra. Modeling of the spectra leads to a
"best fit" set of vibration-rotation parameters for CD��� but a completely satisfactory
fit of both high and low resolution spectra was not achieved. / Graduation date: 2003
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High resolution ionization-detected simulated Raman spectroscopyCrew, Marshall D. 24 February 1997 (has links)
Graduation date 1997
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Raman spectroscopic studies of (A) the Co-C bond in vitamin B## and model compounds, (B) inorganic matrices-encapsulated metallocomplexes, and (C) molecular hydrogen compoundsChopra, Manu 05 1900 (has links)
No description available.
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Measurements of depolarization factors in Raman spectroscopyLyons, Philip Augustine, January 1948 (has links)
Thesis (Ph. D.)--University of Wisconsin--Madison, 1948. / Typescript. Vita. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves i-iii).
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Vibrational spectroscopies of bismuth molybdate catalystsKovats, William Daniel. January 1984 (has links)
Thesis (Ph. D.)--University of Wisconsin--Madison, 1984. / Typescript. Vita. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves 338-345).
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A computerized laser Raman spectroscopy systemWilson, James Harvey. January 1980 (has links)
Thesis (M.S.)--University of Wisconsin--Madison, 1980. / Typescript. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves 557-562).
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Raman studies of aldol condensation reactions on sodium hydroxide treated silica gelKlaassen, Alan Waldo. January 1979 (has links)
Thesis--University of Wisconsin--Madison. / Typescript. Vita. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves 350-368).
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New preprocessing methods of Raman spectra and their evaluationWu, Ying Wen January 2017 (has links)
University of Macau / Faculty of Science and Technology / Department of Computer and Information Science
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A study of stimulated Raman scattering in a CO₂ laser produced plasmaMcIntosh, Grant William John January 1987 (has links)
Stimulated Raman scattering (SRS) has been studied experimentally in a CO₂ laser plasma interaction. A N₂ gas jet target was irradiated with CO₂ laser light (wavelength, ⋋ = 10.6 µm and frequency, ѡ₀) at intensities up to 10¹⁴ Wcm⁻². SRS occurs at intensities greater than 3 x 10¹³ Wcm⁻², which is fair agreement with threshold predictions for a plasma with an electron temperature of 300eV and a density scale length of 300µm. After this intensity is reached, the plasma waves grow exponentially in time with a growth rate of 6 x 10⁻³ѡ₀. This was measured with ps resolution ruby laser Thomson scattering. Spatial growth was also observed. Scattered infrared light at 2⋋ was found. Weak IR light in a broad band near 15µm was also found. The saturated plasma wave level and the number of hot electrons at 150 keV are well correlated, which indicates that trapping is responsible for the electrons. However, trapping is not responsible for the saturation of the instability. Frequency resolved Thomson scattering revealed that ion acoustic waves start at the peak of the SRS fluctuations. Once the ion acoustic waves grow to a large amplitude, SRS is quenched and does not reappear. / Science, Faculty of / Physics and Astronomy, Department of / Graduate
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Tunable high order anti-Stokes radiation produced by stimulated Raman scatteringSinnott, Timothy Joseph January 1977 (has links)
Tunable high order anti-Stokes radiation produced by stimulated Raman scattering in liquid nitrogen is studied experimentally. The light beams of two lasers of different frequencies a ruby laser and tunable dye laser --.are simultaneously focussed in liquid nitrogen and two distinct series of anti-Stokes lines are observed. The dye laser anti-Stokes lines can be changed in frequency by tuning the dye laser. The intensities of the two series of lines are investigated as a function of both ruby and dye laser power, The dye laser anti-Stokes line intensities are found to have a distinct threshold for ruby laser power but no threshold for dye laser power. The experimental results support a two step model in which the ruby laser acts as a pump for molecular vibrations which in turn modulate the dye laser frequency. / Science, Faculty of / Physics and Astronomy, Department of / Graduate
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