Zugl.: Berlin, Techn. Universiẗat, Diss.

Zugl.: Berlin, Techn. Universiẗat, Diss.

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Thesis (Master of Engineering in Chemical Engineering)--Cape Peninsula University of Technology, 2018. / The rate of waste electrical and electronic equipment (WEEE) is growing at an alarming rate, especially in countries where markets are saturated with huge quantities of new electronic goods. Printed circuit boards (PCBs) are a substantial portion of the value contained in waste from WEEE although they are only 6% of the total weight. It is reported that WEEE is currently the fastest growing waste stream in South Africa as the general population’s access to electronic goods in the last decade has increased, especially access to mobile phones. PCBs are found in any piece of electrical or electronic equipment and consist of various metals including precious metals such as gold (Au), silver (Ag) and palladium (Pd). It is reported that gold has the highest economic incentive at 15,200 $ per ton of PCBs. The rapid introduction of new and advanced technology into mobile phones has caused mobile phones to have a relatively short life span, 1 to 2 years to be exact. Mobile phones printed circuit boards (MPPCBs) have more Au content compared to computer circuit boards. They contain 350 g/ton Au whereas computer (PC) PCBs contains 250 g/ton. This research project will recover gold from waste mobile phones PCBs pregnant ammonia thiosulphate leach solution using copper cementation. The cementation process is preferred to all the other technologies of metals extraction from solution due to ultrahigh purity metals that can be obtained and to the less consumption of materials and energy. Electronic parts on the PCBs were manually removed using pliers and screwdrivers. PCBs were then cut to smaller pieces of about 2 x 2 m. The pieces were crushed and milled respectively. Some of the particles were recycled back to the crusher to get finer particles. The particles were separated to particles of sizes between 0 and 1350 μm using a shaker. The comminuted fractions of the PCBs were then used in the leaching step. Batch cementation experiments were performed by bubbling N2 in glass reaction vessel with a working volume of 0.5 L. The reactor was connected to a circulating water bath for temperature control. The recovery percentage of gold at various temperatures, agitation speeds and different amounts of copper powder used, was determined while pH was monitored. The temperature was varied at 30 °C, 40 °C, and 50 °C and the agitation speeds at 300 RPM and 900 RPM. Copper powder was added at 0.5 g/L, 1 g/L, and 1.5 g/L. Gold concentrations were measured by atomic adsorption spectrophotometer (AAS). Scanning electron microscope (SEM) and Energy-dispersive x-ray spectrometry (EDS) analyses of the copper powder after cementation (precipitates) were used to determine the surface morphology and to evaluate the quantitative aspect of the precipitate. It was found that the recovery of gold from ammonia thiosulphate leach solution was greatly affected by agitation speed. At an agitation speed of 900 rpm, 40 °C and 0.5 g of Copper powder, 96% of the gold was recovered from the leach solution. The cementation rate increased as temperature was elevated from 30 to 40 °C, but slightly decreased as the temperature reached 50 °C. The change in experimental conditions affected the gold concentration on the precipitate recovered. This study will provide a possible solution to the WEEE problem and more specifically mobile cell phones, in South Africa.

Thesis (M. Sc.)--University of Hong Kong, 2002. / Includes bibliographical references.

Thesis (M.Hous.Man.)--University of Hong Kong, 2009. / Includes bibliographical references (p. 90-97).

Waste water from the mining industry is generally extremely complex and contains numerous species which influence the adsorption of the metals to any biomass. A variety of factors need to be addressed before treatment is considered viable. It is also beneficial to establish the binding characteristics of the metal of interest to maximise its interaction with the biomass to be utilised. Azalia filiculaides was investigated in the adsorption of gold(III), lead(II), iron(ID), copper(II) and platinum (IV). In batch studies, the optimum biomass and initial gold(III) concentrations were found to be 5 gIL and 8 mgIL respectively. The adsorption of gold(ID) is principally pH-dependent with optimal removal at pH 2. Lead(II), iron(III) and copper(II) did not compete with gold(III) adsorption under equimolar and simulated effluent conditions. Halides, with increasing affinity for gold (chloride < bromide < iodide), can affect gold uptake with the soft base, iodide, exhibiting the most inhibition (25%) and the hard base, chloride, O%. Mercaptoethanol (soft base) showed no interference in gold(III) adsorption while the presence of sulphate (hard base) and sulphite (borderline base) showed that concentrations in excess of 1 0 mM may adversely affect gold(ill) uptake, most likely due to competition for cationic sites on the biomass. Column studies, better suited to high volume treatment, indicated that a flow-rate of 5 mL/min and an initial gold(ill) concentration of 5 mgIL was optimal. Competitive effects between lead, iron, copper and gold again showed little or no interference. The halides, chloride, bromide and iodide, affect gold(ill) uptake similarly to the batch studies, while the bases mercaptoethanol and sulphate minimally affect gold(III) binding with sulphite severely hampering adsorption (70% inhibition). To optimise gold desorption, preliminary batch studies indicated that a ratio of 1:1 of adsorbentdesorbent was optimal, whilst gas purging of thiourea with oxygen, air and nitrogen decreased gold elution in proportion to decreased amounts of oxygen. A series of desorbents were utilised, in column studies, to optimise and determine the speciation of bound gold. The presence of an oxidant with thiourea enhanced desorption greater than 3 fold when compared with thiourea alone. Thiourea desorption studies, aided by the oxidant, suggest that gold is present in the + I and 0 oxidation states. Ultimately thiourea, perchloric acid and hydrochloric acid was found to be the most optimal elutant for gold (J 00% recovery). For selective metal recovery oflead and copper, pre-washing the plant material with water, utilising an acid (0.3 M nitric acid), pumping in an up-flow mode, and recycling the desorbent six times was found to be optimal elutant for gold (J 00% recovery). Cost analysis of utilising elutant versus incinerating the biomass for gold recovery indicated the latter as the most economical. Over a 5 cycle adsorption and desorption series, acid desorption before each adsorption cycle was found to result in greater than 92% desorption for lead and 96% for copper. Gold recovery was 97% with incineration. A preliminary study with gold effluent (Mine C) indicated that nickel and sulphate was removed in batch and column studies. Gold removal was found to be 100% and 4% in batch and column studies respectively. Adsorption of gold in the effluent study was accompanied by the release ofHt. Modifying the plant material with various reagents failed to identify the primary binding sites and the role of polysaccharides, proteins and lipids in gold(ill) uptake. The mode of gold binding is suggested as being initially ionic, this is very rapid, with the interaction of the anionic complex, [AuCI₄]". with the cationic biomass (PH 2). This eventually leads to the displacement of the chloride ligand(s) initiating covalent binding. Spectral studies of the chemical interaction between gold and the representative tannins indicated the protonated hydroxy groups to be responsible. All evidence suggests that the binding mechanisms of gold are not simple. Preliminary adsorption studies of platinum by Azalia filiculaides were conducted. Batch studies indicated that J gIL biomass concentration, initial platinum concentration of 20 mgIL and pH 2 are optimal, while the column studies indicated a flow-rate of! 0 rnL/min and initial platinum concentration of 20 mgIL as optimal. In the platinum effluent study, platinum showed a removal of 23 % and 2 J % for the batch and column studies respectively. Again adsorption was accompanied by //' release. Azalia filiculaides demonstrated its feasibility in the removal of gold and platinum from simulated as well as waste water solutions. Its potential viability as a biosorbent was demonstrated by the high recovery from synthetic solutions of greater than 99% for gold (2-10 mgIL), and greater than 89% for platinum (20 mgIL).

The desire to find more sustainable paving practices as well as the dramatically rising binder costs driven by the growing global demand for paved roads, has led to increased interest of the use of reclaimed asphalt pavement (RAP) in very high amounts. So far the major industry trend has been to develop procedures, invest in technologies and build confidence in mixtures with up to 40 % RAP content. However, a few innovators have refined 100 % recycling technologies over the past four decades to a level where routine production of 100 % recycled hot mix asphalt is in clear sight. Rejuvenators are an integral part of 100 % recycled asphalt production and they can also allow to significantly increase the RAP content for conventionally produced asphalt mixtures. An evaluation of the feasibility of production of 100 % recycled hot-mix asphalt was made and the use of rejuvenators is presented in this study. 100 % recycling is discussed by evaluating ten readily available production technologies along with proposing mix design procedures and identifying best RAP management strategies. A total of eleven different products were evaluated for restoring the RAP binder grade with a definite conclusion that achieving target grade (PG or empirical specification) is possible. In addition a rheological, micromechanical and chemical characterization was performed with select rejuvenators and binders from Strategic Highway Research Program (SHRP) library. To further assess the rejuvenators and feasibility of 100 % RAP recycling a series of 100 % mixture tests were performed that indicated significant improvement in low temperature and fatigue cracking resistance while providing a rut resistant mixture. With the use of some rejuvenators a performance equal to that of reference virgin mix was achieved. Based on these findings of rejuvenator effectiveness a methodology for choice of rejuvenator type and dose was proposed. Finally, a cradle-to-gate analysis of environmental effects was performed which indicated 35 % CO2eq savings per ton of produced 100 % RAP asphalt mixture compared to virgin mix while cost analysis showed at least 50 % savings in material related expenses. A short video summarizing the research is available at http://youtu.be/y-rYvdGiEbY.

This thesis investigated the technological economics of waste paper recovery and recycling in UK. The major problem in waste paper recycling is still the removal of contraries, although technological developments have so far been able to remove some of them. The costs incurred by the local authorities in recovering waste paper were investigated. Local authority costing was found to be inconsistent and many of them did not include all the relevant indirect costs and savings, so that many local authorities claimed to be making heavy losses in their operations. Full accounting incorporating all the relevant indirect costs and savings have shown that most local authorities incurred much smaller losses and in some cases profited from their waste paper recovery operations. A general computer model was developed to allow local authorities to check the viability of their on-going operations and another computer model was developed for an investment appraisal of a proposed waste paper recovery operation. Multiple regression models were developed to forecast the demand of waste paper in the short term and the long term. The cost to the mill in recycling waste paper was also examined. Waste paper recycling can only be increased by improving demand for waste paper based products. Various alternatives for diversifying the markets for waste paper were investigated, particularly those outside the paper and board industry. The government's role in helping to inc~ease waste paper recovery and recycling was examined and some government actions that could be taken were proposed.

Thesis (PhD)--University of Stellenbosch, 2006. / Bibliography. Also available via the Internet.