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Die Schiffsterminologie des Alten Testaments kulturgeschichtlich und etymologisch untersucht /Abraham, Aron. January 1900 (has links)
Diss. phil. hist. Bern, 1914.
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Investigations of highly conjugated macrocycles and polymers for aggregation and chemical sensingBoden, Britta Nicole 05 1900 (has links)
With the goal of developing Schiff base macrocycles with conjugation extended over multiple aromatic rings, new phenanthrene and triphenylene-containing bis(salicylates) were synthesized. A convenient route to 3,6,9,10-tetraalkoxy-2,7-diiodophenanthrene was developed. This compound has been found to be a useful precursor for Pd-catalyzed cross-coupling reactions.
Macrocycles were synthesized by Schiff base condensation of the phenanthrene and triphenylene precursors. Reaction of smaller phenanthrene and triphenylene bis(salicylates) with 1,2-dialkoxy-4,5-phenylenediamine afforded macrocycles in poor yield and purity, but formation of the macrocycle was confirmed by mass spectrometry. Condensation of larger phenanthrene ethynylene bis(salicylates) with phenylenediamines formed [3+3] Schiff base macrocycles in good yield and could be purified through recrystallization. These two large macrocycles were weakly luminescent, and showed decrease in intensity of emission in solution over time. Addition of nitroaromatic compounds to solutions of the macrocycles caused quenching of luminescence, but Stern-Volmer constants could not be determined. One of the macrocycles aggregates in solution and shows some order in the solid state. Association constants for self-assembly of this macrocycle in chloroform were determined, and aggregation was found to be enthalpically driven and entropically disfavoured. Both large macrocycles can complex metals, but low solubility prevents thorough characterization of the metal complexes.
Phenanthrene-containing poly(phenyleneethynylene)s (PPEs) and poly(phenylenevinylene)s (PPVs) were synthesized via the Sonogashira and Heckcouplings, respectively. The PPEs had high molecular weight and both polymers were extremely luminescent with OF = 70% for the PPE and OF = 59% for the PPV. These polymers show potential for use in solar cells and nitroaromatic sensors
.
Dithienylsalphen monomers were made using 4-(2-thienyl)salicylaldehyde and 5-(2-thienyl)salicylaldehyde. These monomers were coordinated to Ni(II), Cu(II) and vanadyl, and tested for electropolymerization. Conjugated dithienylsalphen monomers polymerize poorly, while non-conjugated dithienylsalphen monomers form good films through electropolymerization. Ultraviolet-visible spectroscopy confirmed extended conjugation in N,N '-phenylenebis(4-(2-thienyl)salicylideneimine).
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Investigations of highly conjugated macrocycles and polymers for aggregation and chemical sensingBoden, Britta Nicole 05 1900 (has links)
With the goal of developing Schiff base macrocycles with conjugation extended over multiple aromatic rings, new phenanthrene and triphenylene-containing bis(salicylates) were synthesized. A convenient route to 3,6,9,10-tetraalkoxy-2,7-diiodophenanthrene was developed. This compound has been found to be a useful precursor for Pd-catalyzed cross-coupling reactions.
Macrocycles were synthesized by Schiff base condensation of the phenanthrene and triphenylene precursors. Reaction of smaller phenanthrene and triphenylene bis(salicylates) with 1,2-dialkoxy-4,5-phenylenediamine afforded macrocycles in poor yield and purity, but formation of the macrocycle was confirmed by mass spectrometry. Condensation of larger phenanthrene ethynylene bis(salicylates) with phenylenediamines formed [3+3] Schiff base macrocycles in good yield and could be purified through recrystallization. These two large macrocycles were weakly luminescent, and showed decrease in intensity of emission in solution over time. Addition of nitroaromatic compounds to solutions of the macrocycles caused quenching of luminescence, but Stern-Volmer constants could not be determined. One of the macrocycles aggregates in solution and shows some order in the solid state. Association constants for self-assembly of this macrocycle in chloroform were determined, and aggregation was found to be enthalpically driven and entropically disfavoured. Both large macrocycles can complex metals, but low solubility prevents thorough characterization of the metal complexes.
Phenanthrene-containing poly(phenyleneethynylene)s (PPEs) and poly(phenylenevinylene)s (PPVs) were synthesized via the Sonogashira and Heckcouplings, respectively. The PPEs had high molecular weight and both polymers were extremely luminescent with OF = 70% for the PPE and OF = 59% for the PPV. These polymers show potential for use in solar cells and nitroaromatic sensors
.
Dithienylsalphen monomers were made using 4-(2-thienyl)salicylaldehyde and 5-(2-thienyl)salicylaldehyde. These monomers were coordinated to Ni(II), Cu(II) and vanadyl, and tested for electropolymerization. Conjugated dithienylsalphen monomers polymerize poorly, while non-conjugated dithienylsalphen monomers form good films through electropolymerization. Ultraviolet-visible spectroscopy confirmed extended conjugation in N,N '-phenylenebis(4-(2-thienyl)salicylideneimine).
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Investigations of highly conjugated macrocycles and polymers for aggregation and chemical sensingBoden, Britta Nicole 05 1900 (has links)
With the goal of developing Schiff base macrocycles with conjugation extended over multiple aromatic rings, new phenanthrene and triphenylene-containing bis(salicylates) were synthesized. A convenient route to 3,6,9,10-tetraalkoxy-2,7-diiodophenanthrene was developed. This compound has been found to be a useful precursor for Pd-catalyzed cross-coupling reactions.
Macrocycles were synthesized by Schiff base condensation of the phenanthrene and triphenylene precursors. Reaction of smaller phenanthrene and triphenylene bis(salicylates) with 1,2-dialkoxy-4,5-phenylenediamine afforded macrocycles in poor yield and purity, but formation of the macrocycle was confirmed by mass spectrometry. Condensation of larger phenanthrene ethynylene bis(salicylates) with phenylenediamines formed [3+3] Schiff base macrocycles in good yield and could be purified through recrystallization. These two large macrocycles were weakly luminescent, and showed decrease in intensity of emission in solution over time. Addition of nitroaromatic compounds to solutions of the macrocycles caused quenching of luminescence, but Stern-Volmer constants could not be determined. One of the macrocycles aggregates in solution and shows some order in the solid state. Association constants for self-assembly of this macrocycle in chloroform were determined, and aggregation was found to be enthalpically driven and entropically disfavoured. Both large macrocycles can complex metals, but low solubility prevents thorough characterization of the metal complexes.
Phenanthrene-containing poly(phenyleneethynylene)s (PPEs) and poly(phenylenevinylene)s (PPVs) were synthesized via the Sonogashira and Heckcouplings, respectively. The PPEs had high molecular weight and both polymers were extremely luminescent with OF = 70% for the PPE and OF = 59% for the PPV. These polymers show potential for use in solar cells and nitroaromatic sensors
.
Dithienylsalphen monomers were made using 4-(2-thienyl)salicylaldehyde and 5-(2-thienyl)salicylaldehyde. These monomers were coordinated to Ni(II), Cu(II) and vanadyl, and tested for electropolymerization. Conjugated dithienylsalphen monomers polymerize poorly, while non-conjugated dithienylsalphen monomers form good films through electropolymerization. Ultraviolet-visible spectroscopy confirmed extended conjugation in N,N '-phenylenebis(4-(2-thienyl)salicylideneimine). / Science, Faculty of / Chemistry, Department of / Graduate
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Macrocycles, macrobicycles : a studyMarrs, Deborah Jane January 1990 (has links)
No description available.
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Synthesis, characterization and luminescent properties of mono- and bi-metallic Schiff base complexesLo, Wing Kit 01 January 2004 (has links)
No description available.
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Synthesis, and characterization of 3d-4f heteronuclear Schiff base complexesWaheed, Abdul 28 August 2008 (has links)
Not available / text
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Some anomalies of the Schiff aldehyde testTolley, Willis Brown, 1926- January 1951 (has links)
No description available.
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Electrochemistry of oxorhenium(V) Schiff base complexesWojciechowski, Paul E. 12 1900 (has links)
No description available.
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Polynuclear Schiff base complexes of some first row transition metal ionsBreece, James Lowell 12 1900 (has links)
No description available.
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