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Novel zeotype frameworks with soft cyclodiphosphazane linkers and soft Cu₄X₄ clusters as nodesSiddiqui, Mujahuddin M., Mobin, Shaikh M., Senkovska, Irena, Kaskel, Stefan, Balakrishna, Maravanji S. 26 November 2019 (has links)
Two novel cyclodiphosphazane cluster frameworks with Cu₄X₄ clusters as tetrahedral nodes and ferrocenyl cyclodiphosphazanes [Fe(η5-C5H₄)₂(PNtBu)₂] as ditopic linkers have been synthesized. These frameworks having sodalite topology display a unique integration of porosity and redox activity and offer new opportunities for the synthesis of zeotype frameworks with soft phosphorus-based ligands.
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