Par rapport aux ressources énergétiques fossiles combustibles, l’énergie solaire présente des caractéristiques inhérentes à la nature même de la ressource. Ce constat met en évidence la nécessité de système de stockage d’énergie. Ce travail de thèse consiste à étudier un stockage thermique pour une centrale solaire à concentration, ainsi que ses deux composants essentiels : le fluide de transfert et les matériaux de garnissage solides. La compréhension du système de stockage thermocline sur lit de roche est réalisée grâce à une approche expérimentale et numérique. Une alternative innovante sur le choix du fluide de transfert consiste à utiliser des huiles végétales. Concernant le garnissage, un matériau à géométrie contrôlée est développé à partir d’un coproduit issu de la sidérurgie. L’originalité de cette association pour le stockage thermique permet d’allier performance, disponibilité des matériaux en quantité industrielle tout en réduisant l’impact environnemental et financier. / Compare to fossil fuel energy resources, solar energy presents the inherent characteristic given by the very nature of the resource (intermittent availability). This observation highlights the need for thermal energy storage system. This doctoral thesis studies thermal energy storage for concentrating solar power plant, as well as its two essential components: the heat transfer fluid and the thermal energy storage materials. The analysis of the thermocline storage system with filler materials is achieved through experimental and numerical approaches. An innovative alternative for the heat transfer fluid consists to use vegetable oils, which offers comparable thermal properties and operating behavior to conventional thermal fluid. Regarding thermal energy storage materials, many natural and recycled materials can be used. A storage material with controlled geometry is developed from steel industry co-product. The originality of this combination for thermal energy storage combines performance, materials availability at industrial scale while reducing environmental and financial impact.

Solar Tower Power Plants with thermal energy storage are a promising technology for dispatchable renewable energy in the near future. Storage integration makes possible to shift the electricity production to more profitable peak hours. Usually two tanks are used to store cold and hot fluids, but this means both higher related investment costs and difficulties during the operation of the variable volume tanks. Another solution can be a single tank thermocline storage in a multi-layered configuration. In such tank both latent and sensible fillers are employed to decrease the related cost by up to 30% and maintain high efficiencies.  The Master thesis hereby presented describes the modelling and implementation of a thermocline-like multi-layered single tank storage in a STPP. The research work presents a comprehensive methodology to determine under which market structures such devices can outperform the more conventional two tank storage systems. As a first step the single tank is modelled by means of differential energy conservation equations. Secondly the tank geometrical design parameters and materials are taken accordingly with the applications taken into consideration. Both the steady state and dynamic models have been implemented in an existing techno-economic tool developed in KTH, in the CSP division (DYESOPT). The results show that under current cost estimates and technical limitations the multi-layered solid PCM storage concept is a better solution when peaking operating strategies are desired, as it is the case for the two-tier South African tariff scheme. In this case the IRR of an optimal designed power plant can be decreased by 2.1%. However, if a continuous operation is considered, the technology is not always preferred over the two tank solution, yet is a cheaper alternative with optimized power plants. As a result the obtained LCOE can be decreased by 2.4%.

To study the impact of environmental changes in a coastal marine ecosystem, it is necessary to use indicator species. It is crucial to understand the foraging performances that proceed from environmental changes. The aim of my thesis was to examine the influence of intrinsic and extrinsic factors on the foraging activity of the little penguins (Eudyptula minor). The thermocline allowed birds to approach optimal behaviour. However, the thermocline is an unstable element. I did not find any effect of individual characteristics on their foraging behaviour and success. My work suggests that environmental conditions are major factors that will influence the behaviour of little penguins, allowing me to conclude that little penguins are good ecological indicators.

Le problème de la paramétrisation des mécanismes turbulents dans les couches marines superficielles est étudié par comparaison des résultats obtenus avec différents modèles de turbulence dans diverses situations types. On montre que la description fine des mécanismes turbulents est profondément affectée par les hypothèses de modélisation retenues mais que la structure thermique prévue reste globalement identique dans les situations considérées. Plusieurs simulations examinant l'influence de la variabilité temporelle des échanges air-mer ont mis en évidence qu'une représentation fidèle de cette variabilité est le facteur critique dans ce problème.

This thesis aims to increase our understanding of mechanisms that influence larval dispersal in marine benthic invertebrates, particularly in the absence of strong oceanographic features (e.g. estuarine plumes, upwelling events, or markedly different water masses). Laboratory experiments identified behavioural mechanisms that regulate the vertical distribution of larvae in response to thermal stratification, and field studies in St. George’s Bay, Nova Scotia (NS), Canada, examined the relationship between larval abundance and physical variables (temperature, salinity, fluorescence, etc) and identified mechanisms that regulate larval distributions in situ. In the laboratory, I demonstrated that thermal stratification affects the vertical distribution of larvae by acting as a barrier to migration, or through temperature-dependent vertical swimming velocities. I also developed a random walk based model which highlighted that the key to successfully simulating larval response to temperature was 1) determining the temperature-dependent distribution of vertical swimming velocities and 2) the temporal autocorrelation in these velocities. In the field, the most striking pattern was that the larval distributions for species with similar swimming abilities were significantly correlated to one another at all scales (0.5 to 40 km). This suggests a common mechanism, related to larval swimming ability, which greatly influences the horizontal larval distribution. I found that the spatial scale of variability in larval distributions (~ 3 km) matches that in both the environmental variables and of coherent structures in current velocities (i.e. the tidal excursion). Results from an aggregation-diffusion model suggest that horizontal larval swimming could not be responsible for the observed level of aggregation in the larval horizontal distributions. I suggest that these horizontal patterns are the result of 1) an aggregative process (i.e. larvae swimming against a vertical current and maintaining their vertical position) and 2) a diffusive process which scales the aggregations to the scale of the coherent structures in current velocity (i.e. tidal excursion). In conclusion, this thesis increases our understanding of larval behaviour and its effects on larval dispersal. The results will be particularly useful to those who are interested in mechanisms regulate population connectivity, particularly those using bio-physical models to model dispersal trajectories.

The shape of the thermocline and the depth of the lysoline in the western tropical Pacific are both influenced by the overlying atmosphere, and both the shape of thermocline and the depth of the lysocline can be reconstructed from foraminifera-based paleo-proxies. Paleoclimate proxy evidence suggests a southward shift of the Intertropical Convergence Zone (ITCZ) during times of Northern Hemisphere cooling, including the Last Glacial Maximum (LGM), 19-23 ka before present. However, evidence for movement over the Pacific has mainly been limited to precipitation reconstructions near the continents, and the position of the Pacific marine ITCZ is less well constrained. In this study, I address this problem by taking advantage of the fact that the upper ocean density structure reflects the overlying wind field. I reconstruct changes in the upper ocean density structure during the LGM using oxygen isotope measurements on the planktonic foraminifera G. ruber and G. tumida in a transect of sediment cores from the Western Tropical Pacific. The data suggest a ridge in the thermocline just north of the present-day ITCZ persists for at least part of the LGM, and a structure in the Southern Hemisphere that differs from today. The reconstructed structure is consistent with that produced in a General Circulation Model with both a Northern and Southern Hemisphere ITCZ. I also attempt to reconstruct the upper ocean density structure for Marine Isotope Stages 5e and 6, the interglacial and glacial periods, respectively, previous to the LGM. The data show a Northern Hemisphere thermocline ridge for both of these periods. There is insufficient data to draw any conclusions about the Southern Hemisphere thermocline. Using the same set of sediment cores, I also attempt to reconstruct lysocline depth over the last 23,000 years using benthic foraminiferal carbon isotope ratios, planktonic foraminiferal masses, and sediment coarse fraction percentage. Paleoclimate proxy evidence and modeling studies suggest that the deglaciation following the LGM is associated with a deepening of the lysocline and an increase in sedimentary calcite preservation. Although my data lack the resolution to constrain the depth of the lysocline, they do show an increase in calcite preservation during the last deglaciation, consistent with lysocline deepening as carbon moves from the deep ocean to the atmosphere.

Le niveau de la mer est une des variables climatiques essentielles dont la variabilité résulte de nombreuses interactions complexes entre toutes les composantes du système climatique sur une large gamme d'échelles spatiales et temporelles. Au cours du XXème siècle, les mesures marégraphiques ont permis d'estimer la hausse du niveau de la mer global entre 1,6 mm/an et 1,8 mm/an. Depuis 1993, les observations faites par les satellites altimétriques indiquent une hausse du niveau de la mer plus rapide de 3,3 mm/an. Grâce à leur couverture quasi-globale, elles révèlent aussi une forte variabilité du niveau de la mer à l'échelle régionale, parfois plusieurs fois supérieure à la moyenne globale du niveau de la mer. Compte tenu de l'impact très négatif de l'augmentation du niveau de la mer pour la société, sa surveillance, la compréhension de ses causes ainsi que sa prévision sont désormais considérées comme des priorités scientifiques et sociétales majeures. Dans cette thèse, nous validons d'abord les variations du niveau de la mer mesurées par la nouvelle mission d'altimétrie satellitaire, SARAL-AltiKa, en comparant les mesures avec celles de Jason- 2 et des marégraphes. Un autre volet de cette première partie de thèse a consisté à estimer les parts respectives des facteurs responsables des variations du niveau de la mer depuis 2003 en utilisant des observations issues de l'altimétrie satellitaire (missions altimétrique Jason-1, Jason-2 et Envisat), de la mission GRACE, et des profils de température et salinité de l'océan par les flotteurs Argo. Une attention particulière est portée à la contribution de l'océan profond non 'vue' par Argo. Nous montrons que les incertitudes dues aux approches du traitement des données et aux erreurs systématiques des différents systèmes d'observation nous empêchent encore d'obtenir des résultats précis sur cette contribution. Dans la deuxième partie de la thèse, en utilisant les données de reconstruction du niveau de la mer dans le passé, nous étudions la variabilité régionale du niveau de la mer et estimons sa hausse totale (composante régionale plus moyenne globale) de 1950 à 2009 dans trois régions vulnérables: l'océan Indien, la mer de Chine méridionale et la mer des Caraïbes. Pour les sites où l'on dispose de mesures du mouvement de la croûte terrestre par GPS, nous évaluons la hausse locale du niveau de la mer relatif (hausse du niveau de la mer totale plus mouvement de la croûte locale) depuis 1950. En comparant les résultats de ces trois régions avec une étude précédente sur le Pacifique tropical, nous constatons que le Pacifique tropical présente la plus forte amplitude des variations du niveau de la mer sur la période d'étude. Dans la dernière partie de la thèse, nous nous concentrons par conséquent sur le Pacifique tropical. Nous analysons les rôles respectifs de la dynamique océanique, des modes de variabilité interne du climat et du forçage anthropique sur les structures de la variabilité régionale du niveau de la mer du Pacifique tropical depuis 1993. Nous montrons qu'une partie importante de la variabilité régionale du niveau de la mer du Pacifique tropical peut être expliquée par le mouvement vertical de la thermocline en réponse à l'action du vent. En tentant de séparer le signal correspondant au mode de variabilité interne du climat de celui de la hausse régionale du niveau de la mer dans le Pacifique tropical, nous montrons également que le signal résiduel restant (c'est-à-dire le signal total moins le signal de variabilité interne) ne correspond probablement pas à l'empreinte externe du forçage anthropique. / Sea level is an integrated climate parameter that involves interactions of all components of the climate system (oceans, ice sheets, glaciers, atmosphere, and land water reservoirs) on a wide range of spatial and temporal scales. Over the 20th century, tide gauge records indicate a rise in global sea level between 1.6mm/yr and 1.8 mm/yr. Since 1993, sea level variations have been measured precisely by satellite altimetry. They indicate a faster sea level rise of 3.3 mm/yr over 1993-2015. Owing to their global coverage, they also reveal a strong regional sea level variability that sometimes is several times greater than the global mean sea level rise. Considering the highly negative impact of sea level rise for society, monitoring sea level change and understanding its causes are henceforth high priorities. In this thesis, we first validate the sea level variations measured by the new satellite altimetry mission, SARAL-AltiKa by comparing the measurements with Jason-2 and tide gauge records. We then attempt to close the global mean sea level budget since 2003 and estimate the deep ocean contribution by making use of observational data from satellite altimetry, Argo profiles and GRACE mission. We show that uncertainties due to data processing approaches and systematic errors of different observing systems still prevent us from obtaining accurate results. In the second part of the thesis, by making use of past sea level reconstruction, we study the patterns of the regional sea level variability and estimate climate related (global mean plus regional component) sea level change over 1950-2009 at three vulnerable regions: Indian Ocean, South China and Caribbean Sea. For the sites where vertical crustal motion monitoring is available, we compute the total relative sea level (i.e. total sea level rise plus the local vertical crustal motion) since 1950. On comparing the results from these three regions with already existing results in tropical Pacific, we find that tropical Pacific displays the highest magnitude of sea level variations. In the last part of the thesis, we therefore focus on the tropical Pacific and analyze the respective roles of ocean dynamic processes, internal climate modes and external anthropogenic forcing on tropical Pacific sea level spatial trend patterns since 1993. Building up on the relationship between thermocline and sea level in the tropical region, we show that most of the observed sea level spatial trend pattern in the tropical Pacific can be explained by the wind driven vertical thermocline movement. By performing detection and attribution study on sea level spatial trend patterns in the tropical Pacific and attempting to eliminate signal corresponding to the main internal climate mode, we further show that the remaining residual sea level trend pattern does not correspond to externally forced anthropogenic sea level signal. In addition, we also suggest that satellite altimetry measurement may not still be accurate enough to detect the anthropogenic signal in the 20 year tropical Pacific sea level trends.

L'énergie solaire est connue pour sa nature intermittente par rapport aux ressources d’énergie fossile. Cette observation souligne la nécessité d'utilisation d’un système de stockage d'énergie thermique. Le système de stockage thermocline est considéré comme un système de stockage rentable. La présente thèse vise à étudier le potentiel des roches basaltiques et siliceuses comme des candidates matériaux de stockage pour les centrales solaires concentrées. Les études expérimentales des propriétés thermo-physiques et thermomécaniques de ces roches à des températures allant jusqu'à 1000°C montrent que ces roches offrent de bonnes propriétés thermiques par rapport aux matériaux classiques de stockage. L'analyse du système de stockage thermocline sur un lit de roches à air direct est réalisée par une approche numérique. En outre, cette recherche vise également à évaluer l’impact environnementale de ce type de système de stockage en effectuant une analyse comparative de son cycle de vie. Enfin, une étude complémentaire réalisée dans le but de produire une carte d'indice de pertinence a permis d’identifier les zones les plus appropriées pour la construction des centrales solaires en Egypte. L'originalité de cette approche alternative pour le stockage d'énergie thermique est qu’elle combine la performance et la disponibilité des matériaux de stockage tout en réduisant leurs impacts environnementaux et financiers. / Compare to fossil fuel energy resources, solar energy is known for its intermittent nature. This observation highlights the need for the use of a thermal energy storage system. The thermocline storage system is considered as a cost-effective storage system. This thesis aims to study the potential of basalt and silex rocks as candidate storage materials for concentrated solar power plants. Experimental studies of the thermo-physical and thermo-mechanical properties of these rocks at temperatures up to 1000°C show that these rocks offer good thermal properties compared with conventional storage materials. The analysis of the thermocline storage system of air rock-packed bed is carried out using a numerical approach. This research also aims to assess the environmental impact of this type of storage system by conducting a comparative analysis of its life cycle. Finally, a complementary study carried out with the aim of producing a relevance index map made it possible to identify the most suitable areas for the construction of solar power plants in Egypt. The originality of this alternative approach for thermal energy storage is that it combines the performance and availability of storage materials while reducing their environmental and financial impacts.

Αντικείμενο της διατριβής είναι η προσομοίωση της ροής και της μεταφοράς θερμότητας σε ηλιακά και ενεργειακά συστήματα. Η έμφαση δόθηκε στις δεξαμενές αποθήκευσης της θερμότητας που παράγεται στα συγκεκριμένα συστήματα, με στόχο τον χαρακτηρισμό των ενεργειακών απωλειών και την βελτιστοποίηση του σχεδιασμού τους. Κύριες δραστηριότητες της διατριβής θα είναι η περαιτέρω ανάπτυξη διαθέσιμων εργαλείων προσομοίωσης ροών φυσικής και μικτής συναγωγής, με διερεύνηση των νεώτερων εξελίξεων στην μοντελοποίηση με τη μέθοδο Προσομοίωσης Μεγάλων Δινών (LES). Αρχικά γίνεται εκτεταμένη επικύρωση με πειραματικά αποτελέσματα σε απλές γεωμετρικές διατάξεις (π.χ. ορθογωνικά κανάλια ή κοιλώματα με βαθμίδα θερμοκρασίας) από την βιβλιογραφία. Στη συνέχεια η μεθοδολογία εφαρμόζεται στον υπολογισμό ροών σε πιο ρεαλιστικές γεωμετρίες, επιλεγμένες από πρακτικές εφαρμογές, όπως οι δεξαμενές αποθήκευσης νερού. Αναλύονται σε βάθος οι δυναμικές διεργασίες και τα ροϊκά φαινόμενα τόσο κατά την προσαγωγή της θερμότητας στη δεξαμενή (φόρτιση) όσο και κατά την απαγωγή της (εκφόρτιση) και η επίδραση που έχουν αυτά στην αποδοτικότητα της αποθήκευσης με βάση κατάλληλους ποσοτικούς δείκτες. Από τα αποτελέσματα αναδεικνύεται η σημασία της μοντελοποίησης σε τέτοιου είδους συστήματα ως ένα σημαντικό εργαλείο στη διερεύνηση της απόδοσης τους, του ενεργειακού χαρακτηρισμού τους και ακολούθως στην προσπάθεια επίτευξης του βέλτιστου σχεδιασμού τους. / The subject of the thesis is the Simulation of Turbulent Flow and Heat Transfer in Solar and Energy Systems. Emphasis is given in the thermal storage component of these systems, with the aim of characterizing their energy losses and improve their design. Main activities of the thesis will be the further development of available computational tools for the simulation of flows in natural and mixed convection, incorporating some of the most recent developments in modeling, particularly in the Large Eddy Simulation (LES) method. Initially, an extensive validation with experimental results in simple geometric configurations is carried out (e.g. channels or differentially heated cavities). Subsequently, the methodology is applied in the calculation of flows for more realistic geometries selected from practical applications, such as various hot water storage tanks. Analysis is conducted of the dynamic processes and relevant physical phenomena during the heat supply (charging) to and removal (discharging) from the tank and their influence on the storage effectiveness using appropriate thermodynamic indices. From the simulation results, the significance of the flow and heat transfer modeling in these systems as a practical tool for studying their performance is demonstrated, by characterizing their energy content and significantly contributing to the process of optimizing their design.

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