The objective of this research is to design, fabricate, and demonstrate a microfabricated monolithic ion trap for applications in quantum computation and quantum simulation. Most current microfabricated ion trap designs are based on planar-segmented surface electrodes. Although promising scalability to trap arrays containing ten to one hundred ions, these planar designs suffer from the challenges of shallow trap depths, radial asymmetry of the confining potential, and electrode charging resulting from laser interactions with dielectric surfaces. In this research, the design, fabrication, and testing of a monolithic and symmetric two-level ion trap is presented. This ion trap overcomes the challenges of surface-electrode ion traps. Numerical electrostatic simulations show that this symmetric trap produces a deep (1 eV for 171Yb+ ion), radially symmetric RF confinement potential. The trap has an angled through-chip slot that allows back-side ion loading and generous through laser access, while avoiding surface-light scattering and dielectric charging that can corrupt the design control electrode compensating potentials. The geometry of the trap and its dimensions are optimized for trapping long and linear ion chains with equal spacing for use with quantum simulation problems and quantum computation architectures.

Smallholder livestock keeping and agriculture systems in the sub-Saharan Africa (SSA) seem to be caught into poverty traps, in as much as they cannot any longer provide ecosystem services on which local communities depend for their survival. I used a regime shifts framework to carry out a thorough assessment of these two case studies in arid and semi-arid lands and smallholder by identifying relevant traps and alternate desirable regimes. Using systems analysis and modelling, I drew casual loop diagrams of the two case studies, which helped me to identify the feedback loops that maintain the systems in undesirable traps and the external driving forces of change. A set of interventions points or leverage points were identified to change the dynamics of the systems and shift them towards more desirable regimes. Essentially, a structural change of both systems is called for if sustainable livelihoods in the rural areas of the SSA are to be seriously envisaged. Human capital investments present the main opportunity for facilitating escape from poverty by transforming farmers to non-farmers and livestock keepers to non-livestock keepers.

Trapping centres and their distributions in as-grown TlGaSeS layered single crystals were studied using thermally stimulated current (TSC) measurements. The investigations were performed in the temperature range of 10&ndash / 160 K with various heating rates between 0.6&ndash / 1.2 K/s. Experimental evidence has been found for the presence of three electrons trapping centres with activation energies 12, 20, and 49 meV and one hole trapping centre located at 12 meV. Their capture cross-sections and concentrations were also determined. It is concluded that in these centres retrapping is negligible as confirmed by the good agreement between the experimental results and the theoretical predictions of the model that assumes slow retrapping. The optical properties of TlGaSeS layered single crystals have been investigated by measuring the transmission and the reflection in the wavelength region between 400 and 1100 nm. The optical indirect transitions with a band gap energy of 2.27 eV and direct transitions with a band gap energy of 2.58 eV were found by analyzing the absorption data at room temperature. The rate of change v of the indirect band gap with temperature was determined from the transmission measurements in the temperature range of 10&ndash / 300 K. The oscillator and the dispersion energies, the oscillator strength, and the zero-frequency refractive index were also reported. The parameters of monoclinic unit cell and the chemical composition of TlGaSes crystals were found by X-ray powder diffraction and energy dispersive spectroscopic analysis, respectively.

This thesis presents results of investigations that have been carried out to understand dynamics in nonlinear Paul trap mass spectrometers. Of the three problems that have been taken up for study in this thesis, the first concerns understanding early/delayed ejection of ions in mass selective boundary ejection experiments. The second looks at the differential resolution observed in forward and reverse scan resonance ejection experiments. The third study explores a coupled nonlinear resonance within the nominally stable region of trap operation. The method of multiple scales has been to elucidate dynamics associated with early and delayed ejection of ions in mass selective ejection experiments in Paul traps. We develop a slow flow equation to approximate the solution of a weakly nonlinear Mathieu equation to describe ion dynamics in the neighborhood of the stability boundary of ideal traps (where the Mathieu parameter qz = qz* = 0.908046). For positive even multipoles in the ion trapping field, in the stable region of trap operation, the phase portrait obtained from the slow flow consists of three fixed points, two of which are saddles and the third is a center. As the qz value of an ion approaches qz*, the saddles approach each other, and a point is reached where all nonzero solutions are unbounded, leading to an observation of early ejection. The phase portraits for negative even multipoles and odd multipoles of either sign are qualitatively similar to each other and display bounded solutions even for qz > qz*, resulting in the observation of delayed ejection associated with a more gentle increase in ion motion amplitudes, a mechanism different from the case of the positive even multipoles. The second study investigates constraints on pre-ejection dynamical states which cause differential resolution in resonance ejection experiments using Paul traps with stretched geometry. Both analytical and numerical computations are carried out to elucidate the role of damping and scan rate in influencing coherence in ion motion associated with the forward and reverse scan. It has been shown that in the forward scan experiments, for a given damping, low scan rates result in coherent motion of ions oof a given mass at the jump point. At this point, the amplitude and phase of ions of a given mass, starting at different initial conditions, become effectively identical. As the scan rate is increased, coherence is destroyed. For a given scan rate, increasing damping introduces coherence in ion motion, while decreasing damping destroys this coherence. In reverse scan experiments, for a given damping, very low scan rates will cause coherent ion motion. Increasing the scan rate destroys this coherence. The effect of damping in reverse scan experiments is qualitatively similar to that in the forward scan experiments, but settling times in the forward scan are shorter, leading to improved coherence and resolution. For mass spectrometrically relevant scan rates and damping values, significantly greater coherence is obtained in the forward scan. In the third study we investigate the weakly coupled and nonlinear Mathieu equations governing ion motion in axial and radial directions in a Paul trap in the neighborhood of a nonlinear resonance point at az* = -0.2313850427 and qz* = 0.9193009931$. Using harmonic balance based approximate averaging up to second order; we obtain a slow flow that, we numerically demonstrate, approximates the actual ion dynamics. We find that the slow flow is Hamiltonian. We study the slow flow numerically with the objective of exploring and displaying some of the possible types of interesting ion motions. In particular, we choose specific but arbitrary parameter values; study the stability of the individual radial and axial motion invariant manifolds; examine the rather large times associated with escape of ions; notice regions in the averaged phase space wherein trajectories do not, in fact, escape; observe apparently chaotic dynamics preceding escape for ions that do escape; and note that trajectories that do not escape appear to be confined to 4-tori. We conclude with some comments on the implications for practical operation of the Paul trap near this resonant point.

This thesis presents the results of studies on the problem of subharmonic oscillations in nonlinear Paul trap mass spectrometry. The objective of this thesis is to determine whether the subharmonic oscillations of ions in the trap could in any way affect the quality of mass spectrum in resonance ejection experiments. This is accomplished by studying the existence and stability criteria of these oscillations. This study is done for two casesone in which the auxiliary excitation frequency is close to thrice the ion axial secular frequency and other in which it is close to twice the ion axial secular frequency. Initially, the equations describing the ion motion in the presence of auxiliary excitation are derived. The equations describing the ion motion are then brought into a form easily amenable to analysis by techniques of perturbation theory. The necessary background and definitions to understand the basis for the thesis, along with a survey of results obtained in relevant areas in mass spectrometry and nonlinear dynamics is then developed. The first problem is the study of subharmonic oscillations when the auxiliary excitation frequency is in the vicinity of thrice the ion axial secular frequencies taken up. The application of the multiple time scales technique to the equations describing ion motion gives the slow flow equations, that describe the evolution of amplitudes of axial and radial oscillations. The expression for the steady state amplitudes of these oscillations are then derived. From these expressions the conditions for the existence of the oscillations are obtained in terms of the auxiliary amplitude and the frequency detuning. This is then followed by a detailed stability analysis for the subharmonic oscillation with a given amplitude and phase. The study ends with the discussion of the results obtained, the pertinent numerical studies and the relevance of this study to mass spectrometry. The second study is regarding the problem of subharmonic oscillations when the auxiliary excitation frequency is close to twice the ion axial secular frequency is analyzed. When PoincareLindstedt’s method is applied to the ion motion equations, the amplitude frequency relationship that describes the relation between the steady state subharmonic oscillation amplitude and the frequency detuning is obtained. The variation of the oscillation amplitude with the frequency detuning is then studied. Then follows the analysis of stability. The stability of subharmonic oscillation is analyzed using the results from the standard analysis of Hill’s equation of fourth order. This study ends with the discussion of the results obtained in the context of mass spectrometry. Finally, a summary of the results obtained is discussed.

The rapid progress of complementary-metal-oxide-semiconductor (CMOS) integrated circuit technology became feasible through continuous device scaling. The implementation of high-k/metal gates had a significantcontribution to this progress during the last decade. However, there are still challenges regarding the reliability of these devices. One of the main issues is the escalating 1/fnoise level, which leads to degradation of signal-to-noise ratio (SNR) in electronic circuits. The focus of this thesis is on low-frequency noise characterization and modeling of various novel CMOS devices. The devices include PtSi Schottky-barriers  for source/drain contactsand different high-kgatestacksusingHfO2, LaLuO3 and Tm2O3 with different interlayers. These devices vary in the high-k material, high-k thickness, high-k deposition method and interlayermaterial. Comprehensive electrical characterization and low-frequency noise characterization were performed on various devices at different operating conditions. The noise results were analyzed and models were suggested in order to investigate the origin of 1/f noise in these devices. Moreover, the results were compared to state-of-the-art devices. High constant dielectrics limit the leakage current by offering a higher physical dielectric thickness while keeping the Equivalent Oxide Thickness (EOT) low. Yet, the 1/f noise increases due to higher number of traps in the dielectric and also deterioration of the interface with silicon compared to SiO2. Therefore, in order to improve the interface quality, applying an interfacial layer (IL) between the high-k layer and silicon is inevitable. Very thin, uniform insitu fabricated SiO2 interlayers with HfO2 high-k dielectric have been characterized. The required thickness of SiO2 as IL for further scaling has now reached below 0.5 nm. Thus, one of the main challenges at the current technology node is engineering the interfacial layer in order to achieve both high quality interface and low EOT. High-k ILs are therefore proposed to substitute SiOx dielectrics to fulfill this need. In this work, we have made the first experiments on low-frequency noise studies on TmSiO as a high-k interlayer with Tm2O3 or HfO2 on top as high-k dielectric. The TmSiO/Tm2O3 shows a lower level of noise which is suggested to be related to smoother interface between the TmSiO and Tm2O3. We have achieved excellentnoise performancefor TmSiO/Tm2O3 and TmSiO/HfO2 gate stacks which are comparableto state-of-the-art SiO2/HfO2 gate stacks. / <p>QC 20151130</p>

Το πρόβλημα της αυξημένης σύλληψης υπομεγεθών ατόμων τσιπούρας (Sparus aurata, Linnaeus 1758) στις ιχθυοσυλληπτικές εγκαταστάσεις της λιμνοθάλασσας Μεσολογγίου-Αιτωλικού τις τελευταίες δεκαετίες έχει αποκτήσει σοβαρές διαστάσεις. Το φαινόμενο αυτό εκτός του ότι συνιστά περιβαλλοντική απειλή έχει επιφέρει σημαντική μείωση της εμπορικής αξίας του αλιεύματος με αποτέλεσμα τη συρρίκνωση του εισοδήματος των αλιέων. Η παρούσα εργασία μελετά την επιλεκτικότητα νέων τροποποιημένων ιχθυοπαγίδων που έχουν εγκατασταθεί στη λιμνοθάλασσα στο πλαίσιο μιας πρωτοβουλίας για την αντιμετώπιση του συγκεκριμένου προβλήματος. Η παρακολούθηση αυτής της πρωτοβουλίας έδειξε ότι οι νέες ιχθυοπαγίδες συμβάλλουν στη διαφυγή των υπομεγεθών ψαριών, οπότε και στη μείωση των ποσοτήτων των απορριπτόμενων ψαριών διασφαλίζοντας έτσι τη βιωσιμότητα του ιχθυοπληθυσμού. Επίσης, αυξάνονται τα έσοδα της αλιευτικής εκμετάλλευσης και βελτιώνεται η καθημερινότητα των αλιέων δεδομένου ότι δε μεσολαβεί το στάδιο του διαχωρισμού των μη εμπορεύσιμων από τα εμπορεύσιμα ψάρια. Οι διαφυγές των ψαριών από τις ιχθυοπαγίδες φάνηκε να επηρεάζονται από την αφθονία του αλιεύματος και πιο συγκεκριμένα σε περιπτώσεις μεγάλης αφθονίας παρατηρήθηκε να δυσχεραίνεται η διαφυγή των υπομεγεθών ψαριών από τις ιχθυοπαγίδες. Ενδεχομένως, αυτό να δημιουργεί την ανάγκη επέκτασης της τροποποιημένης επιφάνειας των ιχθυοπαγίδων. Η παρούσα εργασία αποτελεί πηγή σημαντικών πληροφοριών στη λήψη μέτρων με στόχο τη βελτίωση του προτύπου της αλιευτικής εκμετάλλευσης της λιμνοθάλασσας. / The problem of increased capture of undersized individuals of gilthead seabream (Sparus aurata, Linnaeus, 1758) at the Messolonghi - Etoliko lagoon fish traps, the last decades has become serious. This phenomenon apart from the ecological threat has decreased the commercial value of the catch thus leading to a reduction of the fishermen income. The present study investigates the selectivity of new fish traps installed in the lagoon in order to deal with this problem. It was found that modified traps contribute to the escapement of undersized individuals thus decreasing the discards as well as ensuring the sustainability of fish population. Furthermore, new traps exploitation leads to an increase of the income. Also, there is no need to sort undersized fish from the catch thus improving the daily lives of the fishermen. Fish escapement was found to be affected by the abundance of fish catch. In more details, high abundance was observed to make fish escapement difficult. Perhaps, this highlights the need of modified area extension. The present study reflects a source of useful information to take into consideration for the improvement of the lagoon fishery exploitation.

Ion traps are an incredibly versatile tool which have many applications throughout the physical sciences, including such diverse topics as mass spectrometry, precision frequency metrology, tests of fundamental physics, and quantum computing. In this thesis, experiments are presented which involve trapping and measuring properties of Th³⁺. Th³⁺ ions are of unique interest in part because they are a promising platform for studying an unusually low-lying nuclear transition in the 229Th nucleus which could eventually be used as an exceptional optical clock. Here, experiments to measure electronic lifetimes of Th³⁺ are described. A second experimental topic explores the production of sympathetically cooled molecular ions. The study of cold molecular ions has a number of applications, some of which include spectroscopy to aid the study of astrophysical objects, precision tests of quantum electrodynamics predictions, and the study of chemical reactions in the quantum regime. The experiments presented here involve the production of barium monohalide ions, BaX⁺ (X = F, Cl, Br). This type of molecular ion proves to be particularly promising for cooling to the rovibrational ground state. The method used for producing BaX⁺ ions involves reactions between cold, trapped Ba⁺ ions and neutral gas phase reactants at room temperature. The Ba⁺ ion reaction experiments presented in this thesis characterize these reactions for producing Coulomb crystals composed of laser cooled Ba⁺ ions and sympathetically cooled BaX⁺ ions.

The adaptive cycle metaphor provides insight into how and why social-ecological systems change. Literature on 'resilience thinking' has built upon this foundation and further developed the concepts of resilience, adaptation, and transformation to describe social-ecological system behavior. The resilience-thinking literature also describes systems that do not change, even when such change is desirable, as being in a trapped state. However, relatively little research has explored why such systems are trapped and how to free them. This thesis is the product of doctoral research which resolves how to identify, evaluate, and free a system caught in a maladaptive system trap. The study setting is water management in Grenada, a small island developing state in the southeastern Caribbean. Four research questions guide this study: (1) To what extent is Grenadian water management in a trap?, (2) To what extent is Grenadian water management transformable?, (3) Do current and recent interventions effectively foster or utilize transformability?, and (4) Which interventions should be pursued to facilitate transformation of water management in Grenada?. The study is informed by literature on social-ecological systems and integrated water resources management. Methodologically, the study is an explanatory single-case study of water management in Grenada, conducted from 2012 to 2013. The study utilizes data from semi-structured interviews (n=19), a questionnaire (n=180), a document review (n>200), and observation. The general strategy was to evaluate attempts to transform Grenadian water management within the 3-phase transformation framework described in the resilience-thinking literature. 'Points of failure' in transformation are defined as the cause(s) of a trap, and interventions to relieve the points of failure are proposed. Results indicate Grenadian water management is in a rigidity trap, although it exhibits some capacity to transform. A key point of failure of attempts to transform the Grenadian water sector into an integrated and holistic management system has been an inability to seize windows of opportunity to pass key legislation. I conclude the primary cause for this failure is poor fit among the problem, as perceived by various stakeholders, the proposed solution prescribed by water sector reform proponents, and political reality. In addition, reform proponents focus on advocating for reform to water sector professionals and do little to broker passage of legislation politically. Finally, reform proponents also assume legislation will be effectively implemented, which is not certain. Contributions specific to the Grenadian setting include a post-mortem on why efforts to reform the water sector have failed, described above. Five recommendations are made for future interventions to foster transformation of Grenadian water management: (1) engage residents as part of a vision to create political pressure for proposed solutions, (2) frame the problem with substantial resident input and focus, (3) craft solutions which take advantage of political realities such as funding restrictions, (4) anticipate and prepare for crises, and (5) enlist one or more people or organizations to serve as brokers. Empirical contributions include support for the three-streams framework of seizing windows of opportunity as fundamental to explain transformation of social-ecological systems. The primary conceptual contribution is the development of resilience thinking to illuminate ways to free trapped systems. I begin by providing a nomenclature to quantify and describe traps, which includes the type of trap, the degree of persistence and undesirability of the trap, and recent changes in these properties. Then, I develop a framework to assess transformability of a given system based on the existing 3-phase framework of transformation. When applied empirically, this framework illuminates points of failure of transformation, which I define as the cause of a given trap. Once identified, specific strategies can be devised to foster transformation and to break free of a trap.

Study object. The research was made in two forest stands: one was affected by fire and another without fire damage. A sample plot was in a pine stand damaged by fire a year ago, which is is in Kaunas forest enterprise, in Kulautuva forest department. The stand is in square No. 169 and the plots numbers are 14 and 15. The damaged area takes 0,4 hectare. It is 100% pine stand with a site index Nbl. Study aim. To investigate the low fire influence on pine stand litter entomocomplex fluctuation: on their number and seasonal dynamic, on their distrubution by trophical groups, on species abundance and variety in a fire damaged stands. Methods. The research was made in 2004 since april till october. The Barberis ground trap was used in a research. The trap is made from a 150 ml volume and 6,5 cm diameter plastic cruet. The traps were digged into ground to the top of the trap. 1/3 of the trap was filled with a 10% formalin soak. In that case the insects were saved of decomposing and birds. The traps were placed in three zones: in burned area, chequerwise in the place between damaged and undamaged area, and in undamaged area. There were 6 satelites in each area holding 4 traps in each. All together it was 72 traps placed. The distance between the areas was 20 m and the distance between satelites – 10 m. The collected insects were dried and recognized in the labs of Lithuanian University of Agriculture and Forest Research Institute. Results. The total amount of collected insects in 6... [to full text]