The Valle del Bove is a horse-shoe shaped depression, 8km long and 5km wide, cut into the eastern flanks of Mount Etna, Sicily. In the southern cliff walls there are exposed the lavas and pyroclastics erupted by six ancient centres of activity which existed in the vicinity of the site now occupied by the Valle del Bove. The majority of these volcanics originated at a centre, Trifoglietto II, which occupied a position on the site of the southern Valle del Bove, and which was still erupting lavas at 25,000 ys BP. A reconstruction of the topography which previously existed within the Valle del Bove, is accomplished by extrapolating preserved contours on the northern and southern walls of the depression. Reconstruction of the Trifoglietto II centre shows that its summit was probably between 2500m and 2600m above present sea-level, and that it consisted of a cone constructed predominantly from pyroclastic materials, overlain on its southern and eastern flanks by lavas. A stratigraphy is constructed for the southern wall. The Trifoglietto II lavas rest unconformably upon the eroded remnants of an older centre, and are themselves overlain by the products of younger centres. All the lavas exposed in the southern wall are of alkalic affinity, and comprise a trachybasaltic suite ranging from hawaiite to benmoreite. Variation in the chemistry of most of the lavas can be explained by their differentiation at high levels in the crust, from a more basic magma of alkalibasalt/hawaiite composition. Chemical variation in the Trifoglietto II lavas, however, can best be explained as a result of generation by the partial melting of garnet-peridotite material at upper mantle depths and pressures. A study has been made of the numerous dykes exposed in the walls of the Valle del Bove., the alignments of which parallel trends which are important on Etna at the present time. It is proposed that the Valle del Bove was formed by phreatic or phreato-magmatic eruptions which destroyed the Trifoglietto II centre, some 15-17,000 ys BP, following magmatic extinction at the centre. The eruptions produced lahars which are evident to the east of the depression, and extensive air-fall ashes. Subsequent enlargement of the Valle del Bove was accomplished by fluvial erosion.

Primary succession on the basaltic lava flows of Mt. Etna was studied usmg chronosequence theory to investigate the first 500 years of ecosystem development. Separate experiments were conducted to look at how plant species, nutrient availability and lichen activity on the lava changed over time under different conditions based on the site location (age, aspect and altitude on the volcano). By comparing the results of these different areas of study, close links were observed between soil development and nutrient availability. Lichens were found to be an important stage in primary succession introducing biomass to form a developing soil as well as weathering the lava surface. The plant species present on the lava were found to change as plants first colonised the lava and were then replaced as further species appeared over time. Nutrient availability was investigated in living plant material by measurement of the enzyme nitrate reductase and also in the developing soil. Two large inputs of nitrogen were observed in the chronosequences. An early input believed to be lichen derived and another steadily increasing input associated with the soil. The biomass of the nitrogen fixing lichen Stereocaulofl vesuvianum on the lava flows was found to change over time with a rapid increase over the first 100 years of the chronosequence followed by a slower decline as competition and shading from vascular plants covered available habitat. S. vesuvianum was also found to be an efficient weathering agent on the lava altering the surface morphology. This weathering was observed qualitatively by detailed visual examination of the lava surface by scanning electron microscopy. Weathering was also measured quantitatively using an intelligent machine vision computer system, to collate the surface changes of many images simultaneously and compare surface change to a baseline chronosequence, allowing discrimination of fine differences in the extent of weathering. Two of the experiments conducted on Mt. Etna (nitrate reductase activity and lichen weathering) were repeated on a second volcano, Mauna Loa (Hawaii). This tested if the trends observed on Etna were typical of primary succession on lava and the impact of a different climate regime (tropical) compared to Etna (temperate). Nitrate reductase activity was found to be very low in the primary colonising species studied on Hawaii indicating that nitrogen is limited on the early lava flows. Lichen weathering by Stereocaulon vulcani on Hawaii was found to occur in a comparable manner to S. vesuvianum on Etna, and was similarly controlled by the lichen biomass and associated climatic conditions.

The south-west portion of the main caldera was mapped and a stratigraphy for the caldera-fill was constructed. The exact timing of formation of the main caldera is unclear; However, caldera collapse either predates or was synchronous with the eruption of the Campagnola Tuff. The proximal facies of the Campagnola Tuff exists as a complex relation of ignimbrite, lithic breccia and pyroclastic surge deposits. Overlying this the Galluccio Tuff a compound ignimbrite, ~6 km3 D.R.E, forms the base of the exposed caldera fill. Caldera lakes then became well established and following activity was predominantly phreatomagmatic. Pyroclastic surge deposits possess sand wave structures of several types and their migration direction was apparently controlled by the velocity/flow regime of the surge rather than the moisutre content. The morphology of juvenile clasts from phreatomagmatic deposits indicates that the eruptions were driven by a combination of vesiculation and magma/water interaction. The uppermost pyroclastic deposits are thought to represent the early phase of dome building where water still had access to the vent. The construction of the lava domes brought activity to a close within the main caldera. The Galluccio Tuff on the flanks of the volcano may be divided into three compositionally distinct eruptive units. The Lower Galluccio Tuff, correlated with the bulk of the Galluccio Tuff filling the main caldera. The Middle Galluccio Tuff commenced with the eruption of pumice-rich pyroclastic flows followed by flows enriched in both the size and amount of lithic fragments forming lithic-rich ignimbrite and co-ignimbrite lithic breccias of which several types exist. The Upper Galluccio Tuff is composed of lithic-rich ignimbrite which possess dense pumice fragments and are thought to be the product of a combination of both vesiculation and magma water interaction. Field relations indicate that pyroclastic flows were sometimes generated in quick succession and may have overrun earlier slower moving flows. Occasionally internal shear may have caused the overriding of portions of the same flow, these often coincide with lithic breccias and represent the climax of the eruptive phases. The grading of lithic fragments indicates that the expansion and fluidization decreased and yield strength increased with time in a pyroclastic flow.