No description available.

Thesis (Ph. D.)--University of Wisconsin--Madison, 1940. / Typescript. Vita. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves 423-435).

Thesis (M.A.)--University of Wisconsin--Madison, 1937. / Typescript. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves 80-82).

Thesis (Ph. D.)--University of Wisconsin--Madison, 1940. / Typescript. Vita. Title from title screen (viewed May 9, 2006). Includes bibliographical references (leaves 423-435). Online version of the print original.

The goal of this project was improve the fundamental understanding of the wood-resin interaction, by looking at the relationship between the resin wetting onto wood and the resulting penetration into wood lumens. Wetting was analyzed with the sessile drop method, which observed the initial contact angle and change in contact angle over 35s. Penetration was measured within each individual tracheid. The Lucas-Washburn equation analyzed the wetting and penetration by calculating the penetration and comparing it to the measured penetration. Wetting of four resins was compared on 3 species, to improve the understanding of adhesive wetting behavior. This study agreed with previous research, that the non-aqueous resin exhibited favorable wetting and presumably better penetration than aqueous resins, with exception of urea-formaldehyde. Wetting and penetration of pMDI was studied on 5 wood species using the Lucas-Washburn equation. The wetting behaviors exhibited grain and species effects, which had implications on the resin availability for flake/strand-based composite products. The greater surface energy of loblolly pine most likely accounted for the significantly greater penetration of loblolly pine compared to Douglas-fir. The calculated penetration, via the Lucas-Washburn equation, exceeded the measured penetration, but it was concluded that the Lucas-Washburn equation predicted penetration reasonably well. Wetting and penetration of phenol-formaldehyde and subsequent adhesives was compared on 3 wood species using the Lucas-Washburn equation. All contact angles were unfavorable due to a skin formation. The Lucas-Washburn equation did not predict any penetration; however, penetration was observed with all systems. The findings suggest that the system was too complex for the Lucas-Washburn equation to be able to predict accurately. / Master of Science / Although the wood-based composites industry has been in operation for over a century, fundamental aspects of the wood/resin interaction- what happens when the liquid resin touches wood- remain poorly understood. An important aspect of this wood/resin interaction is penetration, which is critical to the strength and durability of wood-based composites. The two types of resins used, oil-based and water-based, were observed on a variety of wood species, Douglas-fir, loblolly pine, spotted gum, European beech and yellow-poplar. When using the oil-based resin, penetration measurements were in reasonable agreement with theoretical predictions. However, when using the water-based resins, the theory predicted no penetration which contradicted measurements- a shallow penetration was clearly observed. This means that parameters modeled by theory were in error, and this is sensible because we expect water to transfer from resin into the dry wood. Consequently, controlling parameters such as resin viscosity, resin surface tension, and wood surface energy were changing. This contributes fundamental knowledge, providing a better understanding of a critical step in the manufacture of wood-based composites, the materials most North Americans use to build their homes.

Honors project (B.A.) -- Carson-Newman College, 2009. / Project advisor: Dr. Beth Vanlandingham. Includes bibliographical references (p. 40-41).

No description available.

One part experimental composer, one part choral craftsman, Stephen Chatman reveals the unique harmony of his musical double-life.

Quantification and prediction of capillary fluid flow in planar nanochannels is essential to the development of many emerging nanofluidic technologies. Planar nanochannels are typically produced using the standard nanofabrication processes of thermal bonding or sacrificial etching. Both approaches may yield nanochannels that are bowed and/or exhibit non-uniform (i.e. non-planar) wall spacing. These variations in wall spacing affect the transient dynamics of a liquid plug filling the nanochannel, causing deviations from the classical behavior in a parallel-plate channel as described by the Washburn model. Non uniform wall spacing impacts the overall frictional resistance and influences the meniscus curvature. In this thesis, a new analytical model that predicts the meniscus location over time in micro- and nanochannels as a function of channel height was compared to experimental filling data of well-characterized channels with different heights. The wall-to-wall spacing of the utilized nanochannels exhibited height variations between 60 and 300 nm. The model was also validated with microscale channels that were fabricated with a linear variation in the wall-to-wall spacing from 100 µm to 400 µm. The filling speed and meniscus shape during the filling process were determined by dynamic imaging of the meniscus front for several different liquids. A modified Washburn equation that utilizes an effective channel height to predict the filling speed corresponding to the location of the tallest height within a channel was derived. A model was also developed to predict the meniscus distortion encountered in a non-constant height channel, provided the cross-sectional channel heights and the distance from the channel entrance are known. The models developed herein account for induced transverse pressure gradients created by non-constant channel heights. The models are compared to experimental data derived from both nanoscale and microscale channels with good qualitative agreement. These results demonstrate that the capillary flow in nanochannels with non-parallel-plate, linear tapered, or parabolic cross sections can be predicted.

No description available.