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The movement of salts in soils following application of feedlot wastes was studied experimentally and theoretically. The objectives of the study were (1) to evaluate the movement of salts in the soil following heavy application of animal wastes as related to the aggregate sizes of manure and water management practices and (2) to develop a mathematical model to predict the movement of salts within the soil and manure mixture. In the experimental study, air dried manure was formed into three distinct sizes, small (to pass 40 mesh sieve), medium (0.9 am in diameter, 1.2 cm in length), and large (1.8 cm in diameter, 1.8 cm in length). Soil columns of 15 cm inside diameter were packed with 30 cm of a soil-manure mixture over a 10 cm depth of soil. The manure application rate was equivalent to 100 metric tons/ha calculated on the basis of the cross-sectional area of the column. A total of five pore volumes of water was passed through the soil under continuous and intermittent water applications. The leachates were collected in 1/2 pore volume increments and the volume, EC, and pH determined immediately. Within 48 hours of the sampling, the leachates were analyzed for Na, K, Ca, Mg, Cl, and five trace elements (Fe, Mn, Zn, Cu, and Ni). The EC of the leachate for the first 1/2 pore volume was significantly (1% level) highest for the small-sized aggregates and the lowest for the large aggregate treatments under both moisture regimes. During the second increment, the order was reversed. In the later water applications, the EC for small aggregates was higher than the other sizes. There were no significant differences between the EC of the leachate from medium and large aggregate treatments during the later periods under either water treatments. Under both moisture regimes, the amount of Na removed from small aggregates decreased more rapidly than the other sizes. More than 90% of the total Na added to the system by manure was removed from the small aggregate treatment. In contrast, the highest amount of K removed (895 mg from small-sized aggregates under continuous leaching' represents about 35% of the total amount present In the manure applied. More Ca was removed from the small-sized aggregate treatments under both moisture regimes than was added by manure application. As for Mg the pattern of the removal was similar to that of Ca. No Cl was detected in the leachate after the fifth 1/2 pore volume was displaced. A mathematical model was developed to predict the movement of readily soluble ions such as Na, K, and Cl from different aggregate sizes of manure. The theoretical curves were compared with earlier experimental data and the parameters appearing in the mathematical equation were estimated. The results for Cl, Na, and K are presented graphically, and the estimated parameters as well as the values of the square roots of the sum of the squares between the theoretical and experimental values as percentage of the sum of the experimental values (SSR) are reported. From the low value of SSR's, it is evident that the model can predict the movement of the readily soluble ions from different aggregate sizes of manure quite accurately. A discussion on the suitability of the model for different sizes of manure aggregates and also a comparison between two different procedures to fit the model to the experimental data are given. In addition, a three phase theoretical model was developed to describe the movement of readily soluble ions from a soil-manure-water system. Experimental data were used in testing the model. The results for Na, K, and Cl are presented graphically. Estimated parameters for the experimental system and the values of SSR are presented. This model also can predict the movement of readily soluble ions from a soil-manure-water system.

The objective of this study is to identify and examine potential mechanisms of radionuclide transport as vapor at a high-level radioactive waste repository located in unsaturated fractured rock. Transport mechanisms and processes have been investigated near the repository and at larger distances. Transport mechanisms potentially important at larger distances include ordinary diffusion, viscous flow and free convection. Ordinary diffusion includes self and binary diffusion, Knudsen flow and surface diffusion. Pressure flow and slip flow comprise viscous flow. Free convective flow results from a gas density contrast. Transport mechanisms or processes dominant near the repository include ordinary diffusion, viscous flow plus several mechanisms whose driving forces arise from the non-isothermal, radioactive nature of high-level waste. The additional mechanisms include forced diffusion, aerosol transport, thermal diffusion and thermophoresis. Near a repository vapor transport mechanisms and processes can provide a significant means of transport from a failed canister to the geologic medium from which other processes can transport radionuclides to the accessible environment. These issues are believed to be important factors that must be addressed in the assessment of specfic engineering designs and site selection of any proposed HLW repository.

Samples of ordinary copper, hot-isotactically-pressed (HIP) copper, and simulated borosilicate high-level waste glass were leached at 25°C, 51°C, and 80°C in solutions simulating brine and silicate groundwaters. It was found that the amount of glass leached increased at higher temperatures, and more leaching occurred in brine than in silicate groundwater. This behavior is predicted by Le Chatelier's Principle. Similarly, more copper was dissolved at higher temperatures, and more was dissolved in brine than in silicate groundwaters.

An analysis was performed of a Texas gulf coast hazardous waste injection well disposal system. The system was complicated by the presence of a fault which transected the injection interval. The existence of the fault presented the potential for enhanced vertical migration of the injected solutes via a tortuous path of interconnected, highly permeable sand units. Evaluation of this potential necessitated a fully three dimensional model which incorporated the arrangement of the alternating shales and sands and their associated discontinuities. Computer run time and memory limitations compelled a dissection of the problem into components, as well as the utilization of a specific mixture of conservative and realistic assumptions. The analysis indicated that within 10,000 years, the waste would advance vertically no further than one hundred feet into the overlying stratigraphy, and laterally no further than 24,000 feet from the point of injection.

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