The range of thermally stable, predominantly a-bonded metal carbonyl derivatives has
been expanded to include Pd(I), Pd(II), Ir(III), Os(II), and Ru(II). The new compounds,
[Pd(CO)₄][Sb₂F₁₁]₂, cis-Pd(CO)₂(SO₃F)₂, [Pd₂(µ-CO)₂](SO₃F)₂, [Pd₂(µ -CO) ₂][Sb₂₁₁]₂, mer-
Ir(CO)₃(SO₃F)₃, [Ir(CO)₅Cl][Sb₂ F₁₁]₂, [Ru(CO)₆][Sb₂F₁₁]₂, [Os(CO)₆][Sb₂F₁₁]₂, and cis-
Pt(CO)₂(Sb₂Fn)₂ have been synthesized. The compounds have been characterized using a
variety of physico-chemical techniques: elemental analysis, FT-IR and Raman spectroscopy,
and ¹³C NMR spectroscopy. For cis-Pd(CO)₂(SO₃F)₂, [Pd₂(µ-CO)₂](SO₃F)₂, mer-
Ir(CO)₃(SO₃F)₃, and [Ir(CO)₅Cl][Sb₂F₁₁]₂, the molecular structures have been determined by
single crystal X-ray diffraction.
[More abstract follows; please see pp.3+ of the accompanying pdf file] / Science, Faculty of / Chemistry, Department of / Graduate
| Identifer | oai:union.ndltd.org:UBC/oai:circle.library.ubc.ca:2429/6178 |
| Date | 11 1900 |
| Creators | Wang, Changqing |
| Source Sets | University of British Columbia |
| Language | English |
| Detected Language | English |
| Type | Text, Thesis/Dissertation |
| Format | 9140332 bytes, application/pdf |
| Rights | For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use. |
Page generated in 0.0017 seconds