Thesis advisor: Marc L. Snapper / Intramolecular [2+2] photocycloadditions have been studied: (i) Previous studies in our group have demonstrated that there is a regiochemical dependence of intramolecular [2+2] photocycloadditions on the solvent employed. In order to understand the generality of hydrogen bonding effects of photochemical reactions of β-hydroxyl enones, we examined the photochemical outcome of enones with both acyclic and cyclic olefin tethers. (ii) An application of an intramolecular [2+2] photocycloaddition/ fragmentation strategy to form 5-8-5 ring systems has been demonstrated toward the synthesis of the natural product cycloaraneosene. / Thesis (PhD) — Boston College, 2008. / Submitted to: Boston College. Graduate School of Arts and Sciences. / Discipline: Chemistry.
| Identifer | oai:union.ndltd.org:BOSTON/oai:dlib.bc.edu:bc-ir_101694 |
| Date | January 2008 |
| Creators | Ng, Stephanie M. |
| Publisher | Boston College |
| Source Sets | Boston College |
| Language | English |
| Detected Language | English |
| Type | Text, thesis |
| Format | electronic, application/pdf |
| Rights | Copyright is held by the author, with all rights reserved, unless otherwise noted. |
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