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Diffusion coefficients of cerate solutions

The apparent integral diffusion coefficients of ceric sulphate solutions, 4 normal in sulphuric acid, were measured for concentrations ranging from 0.05 normal to 0.415 normal at 25°C with the use of a pyrex sintered glass diaphragm diffusion cell. A graph obtained by plotting the calculated integral diffusion coefficients versus the square root of the initial concentration is similar to the graphs obtained for uni-univalent salts. The rate of diffusion, however, is less by a factor of ten. The sintered glass diaphragm cell was calibrated with 0.1 normal potassium chloride at 25°C and the value of the cell constant was determined to be 0.1111 ± 0.0002 cm⁻². / Science, Faculty of / Chemistry, Department of / Graduate

Identiferoai:union.ndltd.org:UBC/oai:circle.library.ubc.ca:2429/41327
Date January 1951
CreatorsMcFadden, Mary Louise
PublisherUniversity of British Columbia
Source SetsUniversity of British Columbia
LanguageEnglish
Detected LanguageEnglish
TypeText, Thesis/Dissertation
RightsFor non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.

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