Two novel cyclodiphosphazane cluster frameworks with Cu₄X₄ clusters as tetrahedral nodes and ferrocenyl cyclodiphosphazanes [Fe(η5-C5H₄)₂(PNtBu)₂] as ditopic linkers have been synthesized. These frameworks having sodalite topology display a unique integration of porosity and redox activity and offer new opportunities for the synthesis of zeotype frameworks with soft phosphorus-based ligands.
Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:36036 |
Date | 26 November 2019 |
Creators | Siddiqui, Mujahuddin M., Mobin, Shaikh M., Senkovska, Irena, Kaskel, Stefan, Balakrishna, Maravanji S. |
Publisher | Royal Society of Chemistry |
Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
Language | English |
Detected Language | English |
Type | info:eu-repo/semantics/publishedVersion, doc-type:article, info:eu-repo/semantics/article, doc-type:Text |
Rights | info:eu-repo/semantics/openAccess |
Relation | 1364-548X, 10.1039/c4cc03810j |
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