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Novel zeotype frameworks with soft cyclodiphosphazane linkers and soft Cu₄X₄ clusters as nodes

Two novel cyclodiphosphazane cluster frameworks with Cu₄X₄ clusters as tetrahedral nodes and ferrocenyl cyclodiphosphazanes [Fe(η5-C5H₄)₂(PNtBu)₂] as ditopic linkers have been synthesized. These frameworks having sodalite topology display a unique integration of porosity and redox activity and offer new opportunities for the synthesis of zeotype frameworks with soft phosphorus-based ligands.

Identiferoai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:36036
Date26 November 2019
CreatorsSiddiqui, Mujahuddin M., Mobin, Shaikh M., Senkovska, Irena, Kaskel, Stefan, Balakrishna, Maravanji S.
PublisherRoyal Society of Chemistry
Source SetsHochschulschriftenserver (HSSS) der SLUB Dresden
LanguageEnglish
Detected LanguageEnglish
Typeinfo:eu-repo/semantics/publishedVersion, doc-type:article, info:eu-repo/semantics/article, doc-type:Text
Rightsinfo:eu-repo/semantics/openAccess
Relation1364-548X, 10.1039/c4cc03810j

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