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Previous issue date: 2012-10-19 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / This work aims to study the influence of two additives, the monomer, acrylamide and its polymer, polyacrylamide, solubilized in microemulsion systems and applied on enhanced oil recovery. By the microemulsion system obtained, it was chosen points into the phase diagram, presenting these compositions: 25%, 30%, 35% C/T; 2% Fo (fixed for all points) e 73%, 68% e 63% Fa, respectively. However, the monomer and the polymer were solubilized in these microemulsion points with 0.1%; 0.5%; 1% e 2% of concentration, ordering to check the concentration influence at the physicochemical properties (surface tension and rheology) of the microemulsion. Through the salinity study, was possible to observe that the concentrations of 1% and 2% of polymer made the solution became blurred, accordingly, the study of surface tension and rheology only was made for the concentrations of 0.1% e 0.5% of monomer and polymer, respectively. By the surface tension study it was observed that how the concentration of active matter (C/T) was increasing the surface tension was amending for each system, with or without additives. In the rheology study, as it increases the concentration of active matter increases both the viscosity of the microemulsion system (SME) with no additive, as the SME with polymer (AD2). After the entire study, it was chosen the lower point of active matter (25% C/T; 2% Fo e 73% Fa), plus additives in concentrations of 0.1% and 0.5% to be used on enhanced oil recovery. Assays were made on sandstone from Botucatu Formation, where after the tests, it was concluded that among the studied points, the point who showed the best efficiency of advanced shift was the microemulsion system + 0.5% AD2, with a recovery of 28% of oil in place and a total of 96,49%, while the other solution with 0.5% of polymer presented the worst result, with 14.1% of oil in place and 67,39% of efficiency of total displacement / Este trabalho tem como objetivo estudar a influ?ncia de dois aditivos, a acrilamida e seu pol?mero, poliacrilamida, solubilizados em sistemas microemulsionados e aplicados na recupera??o avan?ada de petr?leo. Atrav?s da obten??o do sistema microemulsionado, foram escolhidos pontos do diagrama de fases apresentando as seguintes composi??es: 25%, 30%, 35% C/T; 2% Fo (fixa para todos os pontos) e 73%, 68% e 63% Fa, respectivamente. O mon?mero e o pol?mero foram solubilizados nestes pontos de microemuls?o nas concentra??es de 0,1%; 0,5%; 1% e 2%, visando verificar a influ?ncia da concentra??o nas propriedades f?sico-qu?micas (tens?o superficial e reologia) da microemuls?o. Atrav?s do estudo de salinidade, foi poss?vel observar que as concentra??es 1% e 2% de pol?mero turvaram a microemuls?o, portanto, o estudo de tens?o e reologia foi realizado para as concentra??es 0,1% e 0,5% de mon?mero e pol?mero, respectivamente. Atrav?s do estudo de tens?o superficial observou-se que ? medida que aumenta a concentra??o de mat?ria ativa (C/T) altera a tens?o superficial para ambos sistemas com e sem aditivos. No estudo de reologia, ? medida que aumenta a concentra??o de mat?ria ativa, aumenta tanto a viscosidade do sistema microemulsionado (SME) sem aditivo, quanto o SME com pol?mero (AD2). Ap?s esse estudo, foi selecionado o ponto de menor concentra??o de mat?ria ativa (25% C/T; 2% Fo e 73% Fa) acrescido dos aditivos nas concentra??es 0,1% e 0,5% para serem utilizados na recupera??o avan?ada de petr?leo. Os ensaios foram realizados em arenitos da forma??o Botucatu, onde, ap?s terem sido realizados os testes, concluiu-se que dentre os pontos estudados, o que apresentou a melhor efici?ncia de deslocamento avan?ada foi o sistema microemulsionado + 0,5% de poliacrilamida (AD2), com uma recupera??o de 28% de ?leo in place e total de 96,49%, que ao ser comparada a solu??o de 0,5% do mesmo pol?mero apresentou recupera??o avan?ada de 14,1% de ?leo in place e 67,39% de efici?ncia de deslocamento total. A realiza??o deste trabalho mostrou que a utiliza??o de pol?meros em sistemas microemulsionado aparece como uma alternativa vi?vel na recupera??o avan?ada de petr?leo
| Identifer | oai:union.ndltd.org:IBICT/oai:repositorio.ufrn.br:123456789/17687 |
| Date | 19 October 2012 |
| Creators | Teixeira, Ewerton Richard Fernandes |
| Contributors | CPF:07286937391, http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4783139Z0&dataRevisao=null, Barros Neto, Eduardo Lins de, CPF:59545844434, http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4798645D3, Vale, T?lio Yt?rbio Fernandes, CPF:85050822491, http://lattes.cnpq.br/4911813695252136, Santanna, Vanessa Cristina, CPF:77938780430, http://lattes.cnpq.br/9445575768909084, Dantas, Tereza Neuma de Castro |
| Publisher | Universidade Federal do Rio Grande do Norte, Programa de P?s-Gradua??o em Qu?mica, UFRN, BR, F?sico-Qu?mica; Qu?mica |
| Source Sets | IBICT Brazilian ETDs |
| Language | Portuguese |
| Detected Language | English |
| Type | info:eu-repo/semantics/publishedVersion, info:eu-repo/semantics/masterThesis |
| Format | application/pdf |
| Source | reponame:Repositório Institucional da UFRN, instname:Universidade Federal do Rio Grande do Norte, instacron:UFRN |
| Rights | info:eu-repo/semantics/embargoedAccess |
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