The growth of energy demand in the world requires addressing the increasing
power requirements of industrial and residential consumers. Optimizing the design of
new and existing large power producing systems can efficiently increase energy supply to
meet the growing demand. Hydrogen as an energy carrier is a promising sustainable way
to meet the growing energy demand, while protecting the environment. This thesis
investigates the efficient production of hydrogen from the electrolysis of copper chloride,
by predicting entropy production as a result of diffusive mass transfer.
Also, this thesis investigates the possibility of producing electrical energy from
waste heat produced by industrial or other sources. The thermocapillary motion of fluid
droplet in a closed rectangular microchannel is used to generate electrical energy from
waste heat in a piezoelectric membrane by inducing mechanical deformation as a result
of the droplet motion. Modeling, fabrication, and experimental measurement of a micro
heat engine (MHE) are investigated in this study. Analytical and experimental results are
reported for both circular and rectangular microchannels. A novel fabrication technique
using lead zirconate titanate (PZT) as substrate in microfluidic application is presented in
this study. This thesis develops a predictive model of the entropy production due to
thermal and fluid irreversibilities in the microchannel. Thermocapillary pressure and
friction forces are modelled within the droplet, as well as surface tension hysteresis
during start-up of the droplet motion. A new analytical model is presented to predict the
effect of transient velocity on the voltage production in the MHE. In order to predict the
effect of the applied stress on voltage, the different layers of deposition are considered for
thin film laminates. The highest efficiency of the system from simulated taking into
iv
account the electromechanical coupling factor is about 1.6% with a maximum voltage of
1.25mV for the range of displacement considered in this study. In addition, new
experimental and analytical results are presented for evaporation and de-pinning of
deionised water and toluene droplets in rectangular microchannels fabricated from Su-8
2025 and 2075. / UOIT
| Identifer | oai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:OOSHDU.10155/236 |
| Date | 01 April 2012 |
| Creators | Odukoya, Adedoyin |
| Contributors | Naterer, Greg F. |
| Source Sets | Library and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada |
| Language | English |
| Detected Language | English |
| Type | Dissertation |
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