In addition, two unknown vibronic bands have been observed in the 12150 cm-1 region and 12450 cm-1 region. From the observed linewidths, isotopic shift of the transition frequency and appearance of intricate spectral pattern, it is plausible that these bands may be due to C2 under the perturbation of a state inaccessible by dipole transition. Further analysis of these bands are underway. / The unprecedented sensitivity and resolution achieved by our spectrometer allows the measurement of the very weak Phillips band system (A 1piu - X1Sigmag +) of C2 in the plasma of methane and helium at a ratio of 1:170 generated under very mild ac hollow cathode discharge conditions. A total of eleven vibronic bands of the Phillips system have been observed in the region from 10300 cm-1 to 14250 cm-1 and analyzed based on the previous work. Combining the observed transition frequencies with those from Douay et al. [J. Mol. Spectrosc. 131, 250 (1988)], a set of spectroscopic constants for both the X1Sigma g+ and A1piu states have been obtained using least-squares fitting. Excellent agreement has been found between determined molecular constants and those found in the literature. The observation of the high upsilon levels in the 1piu state allows the determination of high order anharmonic constants oeze and oeae for the first time. / This thesis reports the construction of a custom-designed experimental setup for the high resolution near infrared spectroscopic studies of molecular ions and radicals generated in gaseous plasma. The home-built near infrared spectrometer system has a frequency resolution of 500 kHz and a frequency accuracy of ∼0.0010 cm-1 with a detection sensitivity of DeltaI/I of 10-6 using zero background concentration modulated phase sensitive detection scheme. An in-house program has been designed for data acquisition, frequency calibration and data processing and storage. / Yeung, Shun Hin. / Source: Dissertation Abstracts International, Volume: 72-04, Section: B, page: . / Thesis (Ph.D.)--Chinese University of Hong Kong, 2010. / Includes bibliographical references (leaves 129-134). / Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Electronic reproduction. Ann Arbor, MI : ProQuest Information and Learning Company, [200-] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Abstract also in Chinese.
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_344542 |
| Date | January 2010 |
| Contributors | Yeung, Shun Hin., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, theses |
| Format | electronic resource, microform, microfiche, 1 online resource (xix, 134 leaves : ill.) |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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