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Fabrication of photo-patterned ferrocene polymer electrodes by [2+2] cycloaddition

In this thesis, photocrosslinked ferrocene-based methacrylate polymers for thin-film cathodes in lithium batteries have been synthesized. Patterned
thin-film electrodes of the ferrocene-based methacrylate polymers are
fabricated by photocrosslinking. The structure and composition of the
photocrosslinkable polymers are characterized by infrared spectra, nuclear
magnetic resonances, and gel permeation chromatography. The result of quartz crystal microbalance shows that the crosslinked polymers prevent the polymers from dissolving into organic electrolytes. The cyclic voltammogram shows the photocrosslinked ferrocene-based methacrylate polymers have a redox couple. The energy capacity of the polymer for lithium batteries is about 40-50 mAh g-1 at a discharge rate of 10 C. The results show that the photocrosslinked ferrocene-based methacrylate polymers also improve the batteries.

Identiferoai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0825111-171803
Date25 August 2011
CreatorsTseng, Hsueh-Fen
ContributorsShu-chen Hsieh, Jyh-Tsung Lee, Mao-Sung Wu
PublisherNSYSU
Source SetsNSYSU Electronic Thesis and Dissertation Archive
LanguageCholon
Detected LanguageEnglish
Typetext
Formatapplication/pdf
Sourcehttp://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0825111-171803
Rightsuser_define, Copyright information available at source archive

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