The crystal structure of the bromo derivative of a cyclic diterpene has been determined. The crystals are of orthorhombic symmetry with a = 9.00Å, b = 31.46Å, c = 7.31Å. The structure was solved by the normal heavy atom procedure, and refined by least-squares to a residual of R = 0.064. The molecule is shown to be phyllocladan-15-yl bromoacetate, rather than to be a neo-atisirane derivative, as had been expected.
| Identifer | oai:union.ndltd.org:ADTP/247430 |
| Date | January 1972 |
| Creators | Brown, Kevin L. (Kevin Laurie) |
| Publisher | ResearchSpace@Auckland |
| Source Sets | Australiasian Digital Theses Program |
| Language | English |
| Detected Language | English |
| Rights | Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated., http://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm, Copyright: The author |
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