The anion constituent transference numbers in aqueous 0.005-0.02 M picric acid and 0.02- 0.10 M tartaric acid solutions at 25°C were determined by the moving boundary method. Various types of closed electrode were investigated for their suitability. The transference numbers were found to deviate from the Debye-Hiickel-Onsager theory and this was explained by postulating triple ion formation in these solutions in the concentration range studied. Recently published conductance data on picric acid and literature transference data on iodic, nitric and perchloric acids were also analysed for the presence of complex ions.
| Identifer | oai:union.ndltd.org:bl.uk/oai:ethos.bl.uk:622959 |
| Date | January 1967 |
| Creators | Shamim, Mohammad |
| Publisher | Imperial College London |
| Source Sets | Ethos UK |
| Detected Language | English |
| Type | Electronic Thesis or Dissertation |
| Source | http://hdl.handle.net/10044/1/17558 |
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