The coordination behaviour of the pseudohalide ions (NCO ̄ NCS ̄ NCSe ̄ NCTe ̄) has been studied. A number of N- and S-bonded thiocyanate complexes of rhodium(I), of the type Rh(PPh3)2(L)CNS (L = ligand), have been prepared. The mode of linkage of the thiocyanate group has been established by means of infrared spectral measurements. The preparation of Rh(PPh3)2(piperidine)NCS clearly demonstrates that a strongly π-accepting ligand such as CO is not a prerequisite for a N-thiocyanato complex of the type Rh(PPh3)2(L)NCS.
| Identifer | oai:union.ndltd.org:bl.uk/oai:ethos.bl.uk:447881 |
| Date | January 1974 |
| Creators | Anderson, S. J. |
| Publisher | Loughborough University |
| Source Sets | Ethos UK |
| Detected Language | English |
| Type | Electronic Thesis or Dissertation |
| Source | https://dspace.lboro.ac.uk/2134/33955 |
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