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Novel Au(I) and Re(I) luminescent complexes towards sensing, imaging and therapeutics

Two novel quinolinyl/pyridinyl bis-urea ligands were coordinated to Au(I) and Re(I). Emission was ligand-centred (Au(I)) or <super>3</super>MLCT (Re(I)).&nbsp; Two <italic>fac</italic>{[Re(CO)<sub>3</sub>(di-imine)]<sub>2</sub>L}<super> 2+</super> complexes demonstrated luminescent responses to anions in two organic solvents.&nbsp; Emission quenching and modulated <super>3</super>MLCT lifetimes, characteristic of each anion, were observed.

Identiferoai:union.ndltd.org:bl.uk/oai:ethos.bl.uk:584833
Date January 2010
CreatorsMullice, Lucy Anne
PublisherCardiff University
Source SetsEthos UK
Detected LanguageEnglish
TypeElectronic Thesis or Dissertation
Sourcehttp://orca.cf.ac.uk/54190/

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