Selective alpha-olefin trimerisation catalysts are of substantial and increasing commercial significance. Novel chromium based catalyst systems, based on derivatives and analogues of the previously developed chromium III complexes of 1,3,5-triazacyclohexanes, have been investigated, with particular emphasis on the synthesis and reactivity of the potential ligand type RB(R’NCH2)2, and on the incorporation of weakly coordinating anionic functionalities into the active complexes.
Identifer | oai:union.ndltd.org:bl.uk/oai:ethos.bl.uk:535373 |
Date | January 2009 |
Creators | I'Anson, Ian A. |
Contributors | Kohn, Randolf |
Publisher | University of Bath |
Source Sets | Ethos UK |
Detected Language | English |
Type | Electronic Thesis or Dissertation |
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