A linear AH....A model, representing hydrogen bonding, which incorporates a symmetrical double minimum in the potential energy, and interaction between the symmetric and antisymmetric motion, is examined in detail. The asymmetric system A-H....B is also briefly examined. Using harmonic oscillator functions as a basis for expansion, solutions of the two dimensional wave equation are obtained. Three tests for the convergence of the matrix expansion are satisfied. A set of potential parameters describing a typical hydrogen bonded system is chosen. A method for obtaining the interaction constant is described.
| Identifer | oai:union.ndltd.org:bl.uk/oai:ethos.bl.uk:622962 |
| Date | January 1967 |
| Creators | Singh, Thakur Ranjit |
| Publisher | Imperial College London |
| Source Sets | Ethos UK |
| Detected Language | English |
| Type | Electronic Thesis or Dissertation |
| Source | http://hdl.handle.net/10044/1/17567 |
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