This thesis is concerned with the characterisation and modification of a group of pyrrole based conducting polymers. The monomers were fabricated, and upon electrochemical growth, the electronically conducting polymers were characterised using a number of techniques in order to study the chemical and physical structure of the polymer films. Subsequently, a method of surface modification (derivatisation) was developed, optimised and characterised. To optimise the characteristion and derivatisation methods before application to this group of polymers, a study of UV photo-induced grafting was undertaken upon a well-defined system. The photografting of acetic acid and a maleic anhydride/styrene co-polymer to a poly(ethylene) surface and the subsequent derivatisation of the surface polymer chains was successfully optimised and characterised for each system.
| Identifer | oai:union.ndltd.org:bl.uk/oai:ethos.bl.uk:500378 |
| Date | January 2007 |
| Creators | Pearson, Philip E. |
| Publisher | Loughborough University |
| Source Sets | Ethos UK |
| Detected Language | English |
| Type | Electronic Thesis or Dissertation |
| Source | https://dspace.lboro.ac.uk/2134/34504 |
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