The complex between Al(III) and 2-methyloxine has been prepared from various aqueous and aqueous-acetone solutions, both in the presence and the absence of acetate ion as an auxilliary complexing agent. The effect of pH on precipitation of the complex from 20% v/v acetone-water medium has been determined. Solid-phase hydrous aluminum oxide has been converted to the tris complex by the addition of a dioxane solution of 2-methyloxine. Infrared spectral evidence has been found for some degree of complexation from reactions in the melt between Al(III) and 2-n-propyl-, 2-n-butyl-, and 2-phenyloxine. / Thesis / Master of Science (MSc)
| Identifer | oai:union.ndltd.org:mcmaster.ca/oai:macsphere.mcmaster.ca:11375/17779 |
| Date | 08 1900 |
| Creators | Fowler, David J. |
| Contributors | Corsini, A., Chemistry |
| Source Sets | McMaster University |
| Language | English |
| Detected Language | English |
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