Density functional theory was employed to investigate the energetics of ABA, ABC, and intermediary stacked phases for both pristine and s-triazine functionalized graphene trilayers. The energy of the ABC-stacked phase relative to the pristine ABA-stacked ground state showed a 94% increase when s-triazine was adsorbed to the graphene surface, confirming previous studies of the ability of s-triazine to facilitate the ABC to ABA phase-transition. This work is outlined in an enclosed publication titled “Trilayer Graphene as a Candidate Material for Phase Change Memory Applications.” Subsequently, low-pressure CVD was used to synthesize single-crystal graphene trilayers of up to 200 µm, the largest reported thus far. The defect density, stacking density, and morphology of the CVD-grown graphene trilayers are evaluated using Raman spectroscopy. The layers are also shown to be directly discernable as-grown on copper substrates using dark-field optical microscopy even without contrast oxidation of the copper film, representing a quick and reliable method for their identification. Slow-etching of the graphene yielded well-aligned, hexagonal domains further indicating the high-quality, single-crystalline of the graphene.
Identifer | oai:union.ndltd.org:UPSALLA1/oai:DiVA.org:kth-206117 |
Date | January 2016 |
Creators | Atwa, Mohamed |
Publisher | KTH, Skolan för informations- och kommunikationsteknik (ICT) |
Source Sets | DiVA Archive at Upsalla University |
Language | English |
Detected Language | English |
Type | Student thesis, info:eu-repo/semantics/bachelorThesis, text |
Format | application/pdf |
Rights | info:eu-repo/semantics/openAccess |
Relation | TRITA-ICT-EX ; 2016:193 |
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