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Rearrangement of Alkylhaloketene-Cyclopentadiene Adducts in Basic Solution--A New Synthesis of 2-Alkyltropones

This research is concerned with determining whether the previously reported synthesis of tropolone by the solvolysis of the dichloroketene-cyclopentadiene adduct in sodium acetate and acetic acid could be used to prepare 2-alkyltropones from the adducts of alkylhaloketenes and cyclopentadiene. The information obtained from these rearrangements could be useful in determining the mechanism of the ring expansion of halogenated ketene-cyclopentadiene adducts to tropone derivatives.

Identiferoai:union.ndltd.org:unt.edu/info:ark/67531/metadc164519
Date12 1900
CreatorsHieble, Jacob Paul, 1948-
ContributorsBrady, William Thomas, Marshall, James L., 1940-, Escue, Richard Byrd, Glaze, William
PublisherNorth Texas State University
Source SetsUniversity of North Texas
LanguageEnglish
Detected LanguageEnglish
TypeThesis or Dissertation
Formativ, 84 leaves: ill., Text
RightsPublic, Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved., Hieble, Jacob Paul, 1948-

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