In recent years, the celebration activities of various types of folk-custom festivals in Taiwan have already been getting more and more attention from civilians. Festivities throughout the whole island are traditionally accompanied by loud and brightly colored firework displays. Among these activities, the firework display during the Chinese Lantern Festival in Kaohsiung City is one of the largest festivals in Taiwan every year. Therefore, it is important to investigate the influences of firework displays on ambient air quality during the Chinese Lantern Festival in Kaohsiung City.
Field measurement of ambient gaseous pollutants and particulate matter (PM) was conducted on February 9-12, 2009, the Chinese Lantern Festival, in Kaohsiung City. Moreover, three kinds of firework powders obtained from the same factory producing Kaohsiung Lantern Festival fireworks were burned in a combustion chamber to determine the physicochemical properties of firework aerosols. Metallic elements were analyzed with an inductively coupled plasma-atomic emission spectrometer (ICP-AES). Ionic species and carbonaceous contents in the PM samples were analyzed with an ion chromatography (IC) and an elemental analyzer (EA), respectively. Finally, the source identification and apportionment of PM were analyzed by principal component analysis (PCA), enrichment factor (EF), and receptor modeling (CMB).
For inorganic gaseous pollutants, the concentration peaks of NO, NO2, O3, CO were observed during the firework periods, and the concentration peak of NO was approximately 8.8 times higher than those during the non-firework periods. This study further revealed that, even at nighttime, ambient O3 could be reduced dramatically during the firework periods, whenas NO2 concentration increased concurrently, due to titration effects resulting from the prompt reaction of NO with O3 to form NO2 and O2. For organic gaseous pollutants, the concentration peak of toluene during the firework periods was approximately 2.2-4.1 times higher than those during the non-firework periods.
Several metallic elements of PM during the firework display periods were obviously higher than those during the non-firework periods. On February 10, the concentrations of Mg, K, Pb, and Sr in PM2.5 were 10 times higher than those during the non-firework periods. Besides, the Cl-/Na+ ratio was slightly smaller than 1 in Kaohsiung Harbor, but it was approximately 3 during the firework display periods since Cl- came form chlorine content in firework aerosols at this time. Moreover, OC/EC ratio increased up to 2.8.
In addition to the analysis of gaseous pollutants and PM during the Chinese Lantern Festival in Kaohsiung City, this study burned firework powders in a self-designed combustion chamber to measure the physicochemical properties of firework aerosols. In the results, K, Mg, Cl-, OC were major contents (<10%) in the aerosols produced from the burning firework powders. Moreover, Cl-/Na+ and OC/EC ratio were 15.0~23.4 and 2.9~3.2, respectively. Consequently, Cl-/Na+ and OC/EC ratio can be used as two important indicators of firework displays.
Results obtained from PCA and CMB receptor modeling showed that the major sources of aerosols during the firework display periods were firework displays, motor/diesel vehicle exhanst, soil dusts, and marine aerosols. Besides, the firework displays on February 10 contributed approximately 25.2% and 16.6% of PM10 at two sampling sites, respectively.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0810110-014346 |
| Date | 10 August 2010 |
| Creators | Chien, Li-hsing |
| Contributors | Yuan-chung Lin, Shui-jen Chen, Chung-shin Yuan, Chang-gai Lee |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0810110-014346 |
| Rights | withheld, Copyright information available at source archive |
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