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The effect of stannous chloride on the solvent extraction of tetrachloroplatinate(II) ion by triphenylphosphine

Bibliography: leaves 91-95. / The effect of SnCl₂ on the solvent extraction of K₂PtCl₄ in HCl into CH2Cl2 using triphenylphosphine (PPh₃) has been studied in detail. It has been found that SnCl₂ dramatically increases the rate and efficiency of extraction. Our studies show that the percentage Pt extraction depends upon the time allowed for extraction, the Pt(II)/PPh₃ ratio, the Pt(II)/Sn(II) ratio and the HCl concentration in a complicated way.

Identiferoai:union.ndltd.org:netd.ac.za/oai:union.ndltd.org:uct/oai:localhost:11427/14067
Date January 1981
CreatorsYates, Janet Elizabeth
ContributorsKoch, Klaus
PublisherUniversity of Cape Town, Faculty of Science, Department of Chemistry
Source SetsSouth African National ETD Portal
LanguageEnglish
Detected LanguageEnglish
TypeMaster Thesis, Masters, MSc
Formatapplication/pdf

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