<p> </p>
<p>The development of a novel technique employing the use of a linear quadrupole ion trap mass spectrometer coupled to a Nd:YAG laser and a home-built fast reagent-mixing apparatus is detailed and used to detect the short-lived tetrahedral reaction intermediate of the reaction of acetyl chloride with ethanol in microdroplets. Additionally, tandem and high-resolution mass spectrometry is used to characterize potential precursors for solution-processed metal selenide semiconductors in order to determine a synthetic route to sulfur-free thin films. Lastly, Raman MCR (multivariate curve resolution) spectroscopy is used to study the binding-induced conformational change of 1-bromopropane upon binding to α-cyclodextrin as a model system to examine guest conformational changes upon binding to a host molecule.</p>
| Identifer | oai:union.ndltd.org:purdue.edu/oai:figshare.com:article/21685142 |
| Date | 07 December 2022 |
| Creators | Victoria Boulos (14228024) |
| Source Sets | Purdue University |
| Detected Language | English |
| Type | Text, Thesis |
| Rights | CC BY 4.0 |
| Relation | https://figshare.com/articles/thesis/THE_DETECTION_OF_SHORT-LIVED_REACTION_INTERMEDIATES_IN_SOLUTION_CHARACTERIZATION_OF_METAL_COMPLEXES_AND_THE_CONFORMATIONAL_CHANGE_OF_1-BROMOPROPANE_UPON_BINDING_TO_LPHA-CYCLODEXTRIN/21685142 |
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