Nitroxide radical groups grafted on silica have been synthesized. The catalytic oxidation of alcohols to aldehydes and ketones using the nitroxide radical groups as a catalyst was also investigated. The results of scanning electron microscopy, infrared spectroscopy, and X-ray photoelectron spectroscopy confirmed that the nitroxide radical groups are successfully grafted onto silica. The yield of the catalytic oxidation using the catalysts is higher than 99%. The catalysts are easily recovered. Furthermore, the reused catalysts still keep high performance in the catalytic oxidation.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0824112-135626 |
| Date | 24 August 2012 |
| Creators | Yang, Jian-jhe |
| Contributors | Hsiu-wei Chen, Jyh-tsung Lee, Mao-sung Wu |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0824112-135626 |
| Rights | user_define, Copyright information available at source archive |
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