(¤@) Photolytic Study of 2-Azido-1-(2-pyridinyl)ethan- one and Its Derivatives (¤G) Pyrolytic Study of 2-(Azidomethyl)pyridine and Its Derivatives (¤T) Pyrolytic Study of 2-Cyclohexeno[b]furylmethyl Benzoate

Description

¤@. Photolysis of 2-azido-1-(2- pyridyl)ethanone (68),2-azido-1-(3-pyridyl)ethanone)
(69),2-azido-1-(1-methyl-2-pyrryl)ethanone (53) and 2-azido-1-(1-methyl-3-indo yl)ethanone gave Norrish products (71, 7 3-76), (84-86, 89), (92-94) and (93, 95-98).
¤G. Pyrolysis of 2-(azidomethyl)pyridine (9) and 4-(azidomethyl)pyr idine (10) gave the expected products 1,3,5-tri-2-pyridyl-2,4-diaza-1,4-pentadiene (13) and 1,3,5-tri-4-pyridyl-2,4-diaza-1,4-pentadiene (21).
¤T. Pyrolysis of 2-cyclohexeno[b]furylmethyl benzoate (31) gave 2-methylbenzo[b]-
furan (40) and benzene products.

Links & Downloads

1. http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0809111-225407

Tags

photolysis

flash vacuum pyrolysis

Cyclohexeno[b]furylmethyl

Azidomethyl

Azidoethanone

Additional Fields

Identifer	oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0809111-225407
Date	09 August 2011
Creators	Song, Yu-Huei
Contributors	Cherng-Chyi Tzeng, Chin-Hsing CHOU, none, Yeh-Long Chen
Publisher	NSYSU
Source Sets	NSYSU Electronic Thesis and Dissertation Archive
Language	Cholon
Detected Language	English
Type	text
Format	application/pdf
Source	http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0809111-225407
Rights	user_define, Copyright information available at source archive