Iridium complexes with a chiral metal center and chiral carbons, Λ/Δ-(dfppy)₂Ir(chty-R) and Λ/Δ-(dfppy)2Ir(chty-S), were synthesized and characterized. These isomers have the same steadystate photophysical properties, and obvious offsets in ECD spectra highlight both the chiral sources. Each enantiomeric couple shows mirror-image CPL bands with a dissymmetry factor in the order of 10ˉ³.
| Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:36123 |
| Date | 19 December 2019 |
| Creators | Li, Tian-Yi, Zheng, You-Xuan, Zhou, Yong-Hui |
| Publisher | Royal Society of Chemistry |
| Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
| Language | English |
| Detected Language | English |
| Type | info:eu-repo/semantics/publishedVersion, doc-type:article, info:eu-repo/semantics/article, doc-type:Text |
| Rights | info:eu-repo/semantics/openAccess |
| Relation | 1477-9234, 10.1039/c6dt04030f, info:eu-repo/grantAgreement/National Natural Science Foundation of China/Major State Basic Research Development Program/2013CB922101/ |
Page generated in 0.0017 seconds