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Fabrication of three dimensional nanostructured cadmium selenide and its potential applications in sensing of deoxyribonucleic acid. / 硒化鎘三維納米結構之製作及其感應脫氧核糖核酸之應用潛能 / Fabrication of three dimensional nanostructured cadmium selenide and its potential applications in sensing of deoxyribonucleic acid. / Xi hua ge san wei na mi jie gou zhi zhi zuo ji qi gan ying tuo yang he tang he suan zhi ying yong qian neng

Ho, Yee Man Martina = 硒化鎘三維納米結構之製作及其感應脫氧核糖核酸之應用潛能 / 何綺雯. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2009. / Includes bibliographical references. / Abstract also in Chinese. / Ho, Yee Man Martina = Xi hua ge san wei na mi jie gou zhi zhi zuo ji qi gan ying tuo yang he tang he suan zhi ying yong qian neng / He Qiwen. / Chapter Chapter 1 --- Introduction / Chapter 1 --- Photovoltaic properties of CdSe --- p.1 / Chapter 1.1 --- Quantum size effect --- p.1 / Chapter 1.2 --- Synthesis of CdSe nanostructures --- p.3 / Chapter 1.3 --- Electrochemical sensing of CdSe nanostructures --- p.4 / Chapter 1.3.1 --- Surface passivation and functionalization of CdSe nanostructures --- p.5 / Chapter 1.4 --- Electronic properties of nanocrystalline semiconductor electrode --- p.6 / Chapter 1.4.1 --- Band alignment --- p.6 / Chapter 1.4.2 --- Interfacial charge transfer process --- p.9 / Chapter 1.4.3 --- Surface traps and adsorbed molecules --- p.10 / Chapter 1.4.4 --- DNA molecules as a capping group --- p.11 / Chapter 1.5 --- Literatures review in DNA sensing --- p.12 / Chapter 1.6 --- Present study --- p.14 / Chapter 1.6.1 --- Objective --- p.14 / Chapter 1.6.2 --- General methodology --- p.15 / Chapter Chapter 2 --- Experimental / Chapter 2.1 --- Introduction into the instrumentation of this project --- p.21 / Chapter 2.2 --- CHI Electrochemical workstation --- p.22 / Chapter 2.2.1 --- Linear sweep voltammetry --- p.24 / Chapter 2.2.2 --- Cyclic voltammetry --- p.24 / Chapter 2.2.3 --- Multiple potential step --- p.25 / Chapter 2.3 --- CEM Microwave-assisted chemical synthesizer --- p.27 / Chapter 3.1 --- Morphological examination by scanning electron microscopy --- p.28 / Chapter 3.2 --- Elemental analysis by energy dispersive x-ray spectroscopy --- p.30 / Chapter 3.3 --- Crystal structure analysis by x-ray diffraction --- p.31 / Chapter 3.4 --- Surface compositional analysis by x-ray photoelectron spectroscopy --- p.32 / Chapter 3.5 --- Transmission electron microscopy --- p.34 / Chapter Chapter 3 --- Synthesis of 3D nanostructured CdSe multipod electrodes / Chapter 3.1 --- Introduction into the synthesis of CdSe MP electrode --- p.35 / Chapter 3.2 --- Recipe for the synthesis of CdSe NPs --- p.36 / Chapter 3.3 --- The synthesis of CdSe MPs --- p.37 / Chapter 3.3.1 --- Tuning the experimental parameters: Reaction temperature --- p.37 / Chapter 3.3.2 --- Tuning the experimental parameters: Reaction hold time --- p.46 / Chapter 3.3.3 --- Tuning in experimental parameters: Precursor molar ratio --- p.50 / Chapter 3.4 --- The fabrication of MP CdSe on a conductive substrate --- p.54 / Chapter 3.4.1 --- The electrodeposition of CdSe thin films on ITO/glass substrates --- p.55 / Chapter 3.4.2 --- The growth of CdSe MPs on CdSe/ ITO/glass --- p.57 / Chapter 3.5 --- The characterization of MP CdSe electrode --- p.57 / Chapter Chapter 4 --- Electrical and opto-electric characteristics of CdSe MP electrodes and their applications as platforms for the DNA recognition / Chapter 4.1 --- Introduction to the property characterization of CdSe MP electrodes --- p.62 / Chapter 4.2 --- DNA surface attachment --- p.64 / Chapter 4.2.1 --- Mechanism of DNA surface anchoring --- p.65 / Chapter 4.3 --- I-V characterization in PBS --- p.69 / Chapter 4.3.1 --- Experimental procedures of the I-V tests in PBS --- p.70 / Chapter 4.3.2 --- Results and discussions of I-V tests in PBS --- p.72 / Chapter 4.3.2.1 --- Exercising as-prepared CdSe MP electrode --- p.74 / Chapter 4.3.2.2 --- I-V characteristics of CdSe MP electrodes before and after ssDNA attachment --- p.75 / Chapter 4.3.2.3 --- I-V characteristics of CdSe MP electrodes before and after the dsDNA attachment --- p.76 / Chapter 4.3.2.4 --- "Photo-response of bare CdSe MP, ssDNA/CdSe MP and dsDNA/CdSe electrodes" --- p.77 / Chapter 4.4 --- "Photovoltaic I-V measurement in I3""/I"" redox electrolyte" --- p.79 / Chapter 4.4.1 --- Experimental procedures --- p.79 / Chapter 4.4.2 --- Results and discussions --- p.80 / Chapter 4.5 --- Possible application implied by the results --- p.88 / Chapter 4.5.1 --- DNA base pair mismatch identification --- p.91 / Chapter 4.5.2 --- Field-assisted DNA hybridization acceleration process --- p.92 / Chapter Chapter 5 --- Conclusions / Chapter 5.1 --- Conclusions --- p.95

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_326880
Date January 2009
ContributorsHo, Yee Man Martina., Chinese University of Hong Kong Graduate School. Division of Materials Science and Engineering.
Source SetsThe Chinese University of Hong Kong
LanguageEnglish, Chinese
Detected LanguageEnglish
TypeText, bibliography
Formatprint, xi, 96 leaves : ill. ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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